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OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)
5th Edition
ISBN: 9781285460420
Author: John W. Moore; Conrad L. Stanitski
Publisher: Cengage Learning US
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Chapter 17, Problem 103QRT
Interpretation Introduction
Interpretation:
The
Concept Introduction:
Cell potential can be used to tell the possibility of the reaction to occur. The reactions having a positive value of
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+0
Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone
required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one
molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01
number of moles= 0.400/277.15 = 0.00144 moles
2 x 0.00 144=0.00288 moves
arams of acetophenone = 0.00144 X 120.16 = 0.1739
0.1739x2=0.3469
grams of benzaldehyde = 0.00144X106.12=0.1539
0.1539x2 = 0.3069
Starting materials:
0.3469 Ox acetophenone,
0.3069 of benzaldehyde
3
1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants
or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure
and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in
the reactant before being able to draw the arrows corresponding to product formation.
A.
B.
Rearrangement
ΘΗ
Chapter 17 Solutions
OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)
Ch. 17.1 - Prob. 17.1ECh. 17.1 - Prob. 17.1PSPCh. 17.2 - Write oxidation and reduction half-reactions for...Ch. 17.2 - Prob. 17.2CECh. 17.3 - Prob. 17.3PSPCh. 17.3 - Prob. 17.3CECh. 17.3 - Prob. 17.4CECh. 17.4 - Which has the larger charge, 1.0 C or Avogadro's...Ch. 17.4 - Is it reasonable to conclude that a potential...Ch. 17.4 - Devise an experiment that would show that Zn is...
Ch. 17.4 - Given this reaction, its standard potential, and...Ch. 17.5 - Prob. 17.5PSPCh. 17.5 - Prob. 17.8CECh. 17.5 - Prob. 17.9CECh. 17.5 - Prob. 17.10CECh. 17.6 - Prob. 17.6PSPCh. 17.6 - Prob. 17.11ECh. 17.6 - Prob. 17.7PSPCh. 17.7 - Calculate the cell potential for the Zn(s) +...Ch. 17.7 - Prob. 17.9PSPCh. 17.8 - Prob. 17.12ECh. 17.8 - Prob. 17.13ECh. 17.8 - Prob. 17.14ECh. 17.10 - Predict the results of passing a direct electrical...Ch. 17.10 - In 1886. Henri Moissan was the first to prepare...Ch. 17.11 - In the commercial production of sodium metal by...Ch. 17.11 - Prob. 17.16CECh. 17.11 - Prob. 17.17ECh. 17.11 - Prob. 17.18CECh. 17.11 - Prob. 17.19ECh. 17.12 - Prob. 17.20CECh. 17.12 - Prob. 17.21CECh. 17 - Prob. 2SPCh. 17 - Prob. 1QRTCh. 17 - Prob. 2QRTCh. 17 - Prob. 3QRTCh. 17 - Prob. 4QRTCh. 17 - Identify each statement as true or false. Rewrite...Ch. 17 - Prob. 6QRTCh. 17 - Prob. 7QRTCh. 17 - Prob. 8QRTCh. 17 - Answer Question 8 again, but this time find a...Ch. 17 - Prob. 10QRTCh. 17 - Prob. 11QRTCh. 17 - For the reaction in Question 6, write balanced...Ch. 17 - Prob. 13QRTCh. 17 - Prob. 14QRTCh. 17 - Prob. 15QRTCh. 17 - Prob. 16QRTCh. 17 - Prob. 17QRTCh. 17 - For the reaction Cu2+(aq) + Zn(s) → Cu(s) + Zn2+...Ch. 17 - Prob. 19QRTCh. 17 - Prob. 20QRTCh. 17 - Prob. 21QRTCh. 17 - Prob. 22QRTCh. 17 - Draw a diagram of each cell. Label the anode, the...Ch. 17 - Prob. 24QRTCh. 17 - Prob. 25QRTCh. 17 - Prob. 26QRTCh. 17 - Prob. 27QRTCh. 17 - Prob. 28QRTCh. 17 - Prob. 29QRTCh. 17 - Prob. 30QRTCh. 17 - Prob. 31QRTCh. 17 - Consider these half-reactions: (a) Which is the...Ch. 17 - Consider these half-reactions: (a) Which is the...Ch. 17 - In principle, a battery could be made from...Ch. 17 - Prob. 35QRTCh. 17 - Hydrazine, N2H4, can be used as the reducing agent...Ch. 17 - Prob. 37QRTCh. 17 - Prob. 38QRTCh. 17 - Prob. 39QRTCh. 17 - Prob. 40QRTCh. 17 - Prob. 41QRTCh. 17 - Prob. 42QRTCh. 17 - Prob. 43QRTCh. 17 - Prob. 44QRTCh. 17 - Prob. 45QRTCh. 17 - Prob. 46QRTCh. 17 - Consider the voltaic cell 2 Ag+(aq) + Cd(s) 2...Ch. 17 - Consider a voltaic cell with the reaction H2(g) +...Ch. 17 - Calculate the cell potential of a concentration...Ch. 17 - Prob. 50QRTCh. 17 - Prob. 51QRTCh. 17 - Prob. 52QRTCh. 17 - Prob. 53QRTCh. 17 - NiCad batteries are rechargeable and are commonly...Ch. 17 - Prob. 55QRTCh. 17 - Prob. 56QRTCh. 17 - Prob. 57QRTCh. 17 - Hydrazine, N2H4, has been proposed as the fuel in...Ch. 17 - Consider the electrolysis of water in the presence...Ch. 17 - Prob. 60QRTCh. 17 - Prob. 61QRTCh. 17 - Prob. 62QRTCh. 17 - Identify the products of the electrolysis of a 1-M...Ch. 17 - Prob. 64QRTCh. 17 - Prob. 65QRTCh. 17 - Prob. 66QRTCh. 17 - Prob. 67QRTCh. 17 - Prob. 68QRTCh. 17 - Prob. 69QRTCh. 17 - Prob. 70QRTCh. 17 - Prob. 71QRTCh. 17 - Prob. 72QRTCh. 17 - Prob. 73QRTCh. 17 - Prob. 74QRTCh. 17 - Calculate how long it would take to electroplate a...Ch. 17 - Prob. 76QRTCh. 17 - Prob. 77QRTCh. 17 - Prob. 78QRTCh. 17 - Prob. 79QRTCh. 17 - Prob. 80QRTCh. 17 - Prob. 81QRTCh. 17 - Prob. 82QRTCh. 17 - Prob. 83QRTCh. 17 - Prob. 84QRTCh. 17 - Prob. 85QRTCh. 17 - Prob. 86QRTCh. 17 - Prob. 87QRTCh. 17 - Prob. 88QRTCh. 17 - You wish to electroplate a copper surface having...Ch. 17 - Prob. 90QRTCh. 17 - Prob. 91QRTCh. 17 - Prob. 92QRTCh. 17 - Prob. 93QRTCh. 17 - An electrolytic cell is set up with Cd(s) in...Ch. 17 - Prob. 95QRTCh. 17 - Prob. 96QRTCh. 17 - Prob. 97QRTCh. 17 - Prob. 98QRTCh. 17 - Prob. 99QRTCh. 17 - Prob. 100QRTCh. 17 - Prob. 101QRTCh. 17 - Prob. 102QRTCh. 17 - Prob. 103QRTCh. 17 - Prob. 104QRTCh. 17 - Prob. 105QRTCh. 17 - Prob. 106QRTCh. 17 - Prob. 107QRTCh. 17 - Prob. 108QRTCh. 17 - Prob. 109QRTCh. 17 - Prob. 110QRTCh. 17 - Prob. 111QRTCh. 17 - Prob. 17.ACPCh. 17 - Prob. 17.BCP
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