Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
13th Edition
ISBN: 9780134421353
Author: Karen C. Timberlake
Publisher: PEARSON
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Chapter 16.5, Problem 16.44PP

pepsin, a peptidase that hydrolyzes proteins, functions in the stomach at an optimum pH of 1.5 to 2.0. How is the rate of a pepsin −catalyzed reaction affected by each of the following conditions?

  1. Changing the pH to 5.0
  2. Running the reaction at 0 C

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Free Energy (kcal/mol) 25 20 15 10 5 0 A \ B A D Reaction progress Use the reaction energy diagram above to answer the following questions. Calculate the activation energy, AG ‡, for the step A to B. kcal/mol Calculate the overall energy change, AGº, for the process B to C. Which step is faster, (a) A to B or (b) C to D? kcal/mol
Free Energy (kcal/mol) 25 20 15 10 B 5 сле C A D 0 Reaction progress Use the reaction energy diagram above to answer the following questions. Calculate the activation energy, AG *, for the step B to A. kcal/mol Calculate the overall energy change, AG°, for the process A to D. Which step is faster, (a) B to C or (b) D to C? @ kcal/mol
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Chapter 16 Solutions

Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)

Ch. 16.2 - Prob. 16.11PPCh. 16.2 - Prob. 16.12PPCh. 16.2 - Prob. 16.13PPCh. 16.2 - Prob. 16.14PPCh. 16.2 - Prob. 16.15PPCh. 16.2 - Prob. 16.16PPCh. 16.3 - Prob. 16.17PPCh. 16.3 - Prob. 16.18PPCh. 16.3 - Prob. 16.19PPCh. 16.3 - Prob. 16.20PPCh. 16.3 - What type of interaction would you expect between...Ch. 16.3 - What type of interaction would you expect between...Ch. 16.3 - Prob. 16.23PPCh. 16.3 - Prob. 16.24PPCh. 16.3 - Prob. 16.25PPCh. 16.3 - Prob. 16.26PPCh. 16.3 - Prob. 16.27PPCh. 16.3 - Indicate the changes in secondary and tertiary...Ch. 16.4 - Why do chemical reactions in the body require...Ch. 16.4 - Prob. 16.30PPCh. 16.4 - Prob. 16.31PPCh. 16.4 - Prob. 16.32PPCh. 16.4 - Prob. 16.33PPCh. 16.4 - Prob. 16.34PPCh. 16.4 - Prob. 16.35PPCh. 16.4 - 16.36 Match the terms (1) active site, (2)...Ch. 16.4 - Prob. 16.37PPCh. 16.4 - Prob. 16.38PPCh. 16.4 - Prob. 16.39PPCh. 16.4 - Prob. 16.40PPCh. 16.4 - For problems 16.39 to 16.42, see Chemistry Link to...Ch. 16.4 - Prob. 16.42PPCh. 16.5 - Trypsin, a peptidase that hydrolyzes polypeptides,...Ch. 16.5 - pepsin, a peptidase that hydrolyzes proteins,...Ch. 16.5 - The following graph shows the activity versus pH...Ch. 16.5 - The following graph shows the activity versus pH...Ch. 16.5 - Prob. 16.47PPCh. 16.5 - Prob. 16.48PPCh. 16.5 - Prob. 16.49PPCh. 16.5 - Prob. 16.50PPCh. 16.5 - What is the chemical formula for hydroxyurea?Ch. 16.5 - What is the molar mass of hydroxyurea?Ch. 16.5 - Prob. 16.53PPCh. 16.5 - Prob. 16.54PPCh. 16 - Prob. 16.55UTCCh. 16 - Prob. 16.56UTCCh. 16 - Prob. 16.57UTCCh. 16 - Prob. 16.58UTCCh. 16 - 16.59 Identify the amino acids and type of...Ch. 16 - What type of interaction would you expect between...Ch. 16 - Draw the condensed structural formula for...Ch. 16 - Draw the condensed structural formula for...Ch. 16 - Seed and vegetables are often deficient in one or...Ch. 16 - 16.64 Seeds and vegetables are often deficient in...Ch. 16 - Prob. 16.65APPCh. 16 - Prob. 16.66APPCh. 16 - Prob. 16.67APPCh. 16 - Prob. 16.68APPCh. 16 - Prob. 16.69APPCh. 16 - Why do enzymes function only under mild...Ch. 16 - Prob. 16.71APPCh. 16 - Prob. 16.72APPCh. 16 - Prob. 16.73APPCh. 16 - Prob. 16.74APPCh. 16 - Prob. 16.75APPCh. 16 - Prob. 16.76APPCh. 16 - Prob. 16.77APPCh. 16 - Prob. 16.78APPCh. 16 - If a blood test indicates a high level of LDH and...Ch. 16 - Prob. 16.80APPCh. 16 - Prob. 16.81CPCh. 16 - Prob. 16.82CP
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