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Nanotechnology has become an important field, with applications ranging from high-density data storage to the design of “nano machines.” One common building block of nanostructured architectures is manganese oxide nanoparticles. The particles can be formed from manganese oxalate nanorods, the formation of which can be described as follows:
Calculate the value for the overall formation constant for Mn(C2O4)22−:
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Chapter 16 Solutions
Chemistry
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- Silicon is produced for the chemical and electronics industries by the following reactions. Give the balanced equation for each reaction. a. SiO2(s)+C(s)arefurnaceElectricSi(s)+CO(g) b. Liquid silicon tetrachloride is reacted with very pure solid magnesium, producing solid silicon and solid magnesium chloride. c. Na2SiF6(s) + Na(s) Si(s) + NaF(s)arrow_forwardChlorine exists mainly as two isotopes, 37Cl and 33Cl. Which is more abundant? How do you know?arrow_forwardColorful fireworks often involve the decomposition of barium nitrate and potassium chlorate and the reaction of the metals magnesium, aluminum, and iron with oxygen. (a) Write the formulas of barium nitrate and potassium chlorate. (b) The decomposition of solid potassium chlorate leads to the formation of solid potassium chloride and diatomic oxygen gas. Write an equation for the reaction. (c) The decomposition of solid barium nitrate leads to the formation of solid barium oxide, diatomic nitrogen gas, and diatomic oxygen gas. Write an equation for the reaction. (d) Write separate equations for the reactions of the solid metals magnesium, aluminum, and iron with diatomic oxygen gas to yield the corresponding metal oxides. (Assume the iron oxide contains Fe3+ ions.)arrow_forward
- Consider the chemical reaction 2 S + 3 O2 → 2 SO3. If the reaction is run by adding S indefinitely to a fixed amount of O2, which of these graphs best represents the formation of SO3? Explain your choice.arrow_forwardEthanol, C2H5OH, is a gasoline additive that can be produced by fermentation of glucose. C6H12O62C2H5OH+2CO2 (a) Calculate the mass (g) of ethanol produced by the fermentation of 1.000 lb glucose. (b) Gasohol is a mixture of 10.00 mL ethanol per 90.00 mL gasoline. Calculate the mass (in g) of glucose required to produce the ethanol in 1.00 gal gasohol. Density of ethanol = 0.785 g/mL. (c) By 2022, the U. S. Energy Independence and Security Act calls for annual production of 3.6 1010 gal of ethanol, no more than 40% of it produced by fermentation of corn. Fermentation of 1 ton (2.2 103 lb) of corn yields approximately 106 gal of ethanol. The average corn yield in the United States is about 2.1 105 lb per 1.0 105 m2. Calculate the acreage (in m2) required to raise corn solely for ethanol production in 2022 in the United States.arrow_forwardPhosphorus occurs naturally in the form of fluorapatite, CaF2 3Ca3(PO4)2. The dot indicates 1 part CaF2 to 3 parts Ca3(PO4)2. This mineral is reacted with an aqueous solution of H2SO4 in the preparation of a fertilizer. The products are phosphoric acid, hydrogen fluoride, and gypsum, CaSO4 2H2O. Write the balanced equation describing this process.arrow_forward
- The carbon dioxide exhaled in the breath of astronauts is often removed from the spacecraft by reaction with lithium hydroxide 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) Estimate the grams of lithium hydroxide required per astronaut per day. Assume that each astronaut requires 2.50 103 kcal of energy per day. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 2.50 103 kcal of heat, calculate the amount of CO2 produced and hence the amount of LiOH required. The H for glucose(s) is 1273 kJ/mol.arrow_forwardWrite balanced chemical equations for the following reactions: (a) zinc metal heated in a stream of oxygen gas (b) zinc carbonate heated until loss of mass stops (c) zinc carbonate added to a solution 0f acetic acid, CH3CO2H (d) zinc added to a solution of hydro-bromic acidarrow_forward3.99 Iron—platinum alloys may be useful as high-density recording materials because of their magnetic properties. These alloys have been made with a wide range of composition, from 34.0 at% Pt to 81.8 at% Pt. Express this range in mol%.arrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningChemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax
- Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
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