Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Textbook Question
Chapter 16, Problem 11Q
Ag2S(s) has a larger molar solubility than CuS even though Ag2S has the smaller Ksp value. Explain how this is possible.
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When a small amount of AgCl(s) is added to a saturated solution of AgCl at constant temperature, then
a.) the value of Ksp for AgCl(s) decreases
b.)additional AgCl(s) dissolves into the solution
c.)the value of Ksp for AgCl increases
d.)the value of Ksp for AgCl(s) remains the same
e.)less AgCl(s) precipitates from the solution
Compare the solubility of silver sulfide in each of the following aqueous solutions
Compare the solubility of silver sulfate in each of the following aqueous solutions:
Clear All
0.10 M AGNO3
More soluble than in pure
water.
0.10 M (NH4)2SO4
Similar solubility as in pure
water.
0.10 M NH,CH,COO
Less soluble than in pure
water.
0.10 M KNO3
Chapter 16 Solutions
Chemistry
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Ch. 16 - Which of the following will affect the total...Ch. 16 - Prob. 2ALQCh. 16 - You are browsing through the Handbook of...Ch. 16 - A friend tells you: The constant Ksp of a salt is...Ch. 16 - Explain the following phenomenon: You have a test...Ch. 16 - What happens to the Ksp value of a solid as the...Ch. 16 - Which is more likely to dissolve in an acidic...Ch. 16 - Two different compounds have about the same molar...Ch. 16 - Sodium chloride is listed in the solubility rules...Ch. 16 - For which of the following is the Ksp value of the...Ch. 16 - Ag2S(s) has a larger molar solubility than CuS...Ch. 16 - Solubility is an equilibrium position, whereas Ksp...Ch. 16 - Prob. 13QCh. 16 - Prob. 14QCh. 16 - The common ion effect for ionic solids (salts) is...Ch. 16 - Sulfide precipitates are generally grouped as...Ch. 16 - List some ways one can increase the solubility of...Ch. 16 - The solubility of PbCl2 increases with an increase...Ch. 16 - You have two salts, AgX and AgY, both with very...Ch. 16 - The stepwise formation constants for a complex ion...Ch. 16 - Silver chloride dissolves readily in 2 M NH3 but...Ch. 16 - If a solution contains either Pb2+(aq) or Ag+(aq),...Ch. 16 - Write balanced equations for the dissolution...Ch. 16 - Write balanced equations for the dissolution...Ch. 16 - Prob. 25ECh. 16 - Use the following data to calculate the Ksp value...Ch. 16 - Approximately 0.14 g nickel(II) hydroxide,...Ch. 16 - The solubility of the ionic compound M2X3, having...Ch. 16 - The concentration of Pb2+ in a solution saturated...Ch. 16 - The concentration of Ag+ in a solution saturated...Ch. 16 - Calculate the solubility of each of the following...Ch. 16 - Calculate the solubility of each of the following...Ch. 16 - Cream of tartar, a common ingredient in cooking,...Ch. 16 - Barium sulfate is a contrast agent for X-ray scans...Ch. 16 - Calculate the molar solubility of Cd(OH)2, Ksp =...Ch. 16 - The solubility rules outlined in Chapter 4 say...Ch. 16 - Calculate the molar solubility of Al(OH)3, Ksp = 2...Ch. 16 - Calculate the molar solubility of Co(OH)3, Ksp =...Ch. 16 - For each of the following pairs of solids,...Ch. 16 - For each of the following pairs of solids,...Ch. 16 - Calculate the solubility (in moles per liter) of...Ch. 16 - Calculate the solubility of Co(OH)2(s) (Ksp = 2.5 ...Ch. 16 - The Ksp for silver sulfate (Ag2SO4) is 1.2 105....Ch. 16 - The Ksp for lead iodide (PbI2) is 1.4 108....Ch. 16 - Calculate the solubility of solid Ca3(PO4)2 (Ksp =...Ch. 16 - Calculate the solubility of solid Pb3(P04)2 (Ksp =...Ch. 16 - Prob. 47ECh. 16 - The solubility of Pb(IO3)(s) in a 0.10-M KIO3...Ch. 16 - Which of the substances in Exercises 27 and 28...Ch. 16 - For which salt in each of the following groups...Ch. 16 - What mass of ZnS (Ksp = 2.5 1022) will dissolve...Ch. 16 - The concentration of Mg2+ in seawater is 0.052 M....Ch. 16 - Will a precipitate form when 100.0 mL of 4.0 104...Ch. 16 - A solution contains 1.0 105 M Ag+ and 2.0 106 M...Ch. 16 - A solution is prepared by mixing 100.0 mL of 1.0 ...Ch. 16 - If 10.0 mL of 2.0 103 M Cr(NO3)3 is added to 10.0...Ch. 16 - Calculate the final concentrations of K+(aq),...Ch. 16 - A solution is prepared by mixing 75.0 mL of 0.020...Ch. 16 - A 50.0-mL sample of 0.00200 M AgNO3 is added to...Ch. 16 - Prob. 60ECh. 16 - A solution contains 1.0 105 M Na3PO4. What is the...Ch. 16 - A solution is 1 104 M in NaF, Na2S, and Na3PO4....Ch. 16 - A solution contains 0.25 M Ni(NO3)2 and 0.25 M...Ch. 16 - Write equations for the stepwise formation of each...Ch. 16 - Write equations for the stepwise formation of each...Ch. 16 - In the presence of CN, Fe3+ forms the complex ion...Ch. 16 - In the presence of NH3, Cu2+ forms the complex ion...Ch. 16 - Prob. 69ECh. 16 - Prob. 70ECh. 16 - The overall formation constant for HgI42 is 1.0 ...Ch. 16 - A solution is prepared by adding 0.10 mole of...Ch. 16 - A solution is formed by mixing 50.0 mL of 10.0 M...Ch. 16 - A solution is prepared by mixing 100.0 mL of 1.0 ...Ch. 16 - a. Calculate the molar solubility of AgI in pure...Ch. 16 - Solutions of sodium thiosulfate are used to...Ch. 16 - Kf for the complex ion Ag(NH3)2+ is 1.7 107. Ksp...Ch. 16 - Prob. 78ECh. 16 - Prob. 79ECh. 16 - The solubility of copper(II) hydroxide in water...Ch. 16 - A solution contains 0.018 mole each of I, Br, and...Ch. 16 - Magnesium hydroxide, Mg(OH)2, is the active...Ch. 16 - Tooth enamel is composed of the mineral...Ch. 16 - The U.S. Public Health Service recommends the...Ch. 16 - What mass of Ca(NO3)2 must be added to 1.0 L of a...Ch. 16 - Calculate the mass of manganese hydroxide present...Ch. 16 - Prob. 87AECh. 16 - The active ingredient of Pepto-Bismol is the...Ch. 16 - Consider saturated solutions of die following...Ch. 16 - Silver cyanide (AgCN) is an insoluble sail with...Ch. 16 - Nanotechnology has become an important field, with...Ch. 16 - The equilibrium constant for the following...Ch. 16 - Calculate the concentration of Pb2+ in each of the...Ch. 16 - Will a precipitate of Cd(OH)2 form if 1.0 mL of...Ch. 16 - a. Using the Ksp value for Cu(OH)2 (1.6 1019) and...Ch. 16 - Describe how you could separate the ions in each...Ch. 16 - Nitrate salts are generally considered to be...Ch. 16 - In the chapter discussion of precipitate...Ch. 16 - Assuming that the solubility of Ca3(PO4)2(s) is...Ch. 16 - Order the following solids (ad) from least soluble...Ch. 16 - The Ksp for PbI2(s) 1.4 108. Calculate the...Ch. 16 - The solubility of Pb(IO3)2(s) in a 7.2 102-M KIO3...Ch. 16 - A 50.0-mL sample of 0.0413 M AgNO3(aq) is added to...Ch. 16 - Prob. 105CPCh. 16 - Prob. 106CPCh. 16 - a. Calculate the molar solubility of AgBr in pure...Ch. 16 - Calculate the equilibrium concentrations of NH3,...Ch. 16 - Calculate the solubility of AgCN(s) (Ksp = 2.2 ...Ch. 16 - Calcium oxalate (CaC2O4) is relatively insoluble...Ch. 16 - The salt MX has a solubility of 3.17 108 mol/L in...Ch. 16 - Consider 1.0 L of an aqueous solution that...Ch. 16 - A solution saturated with a salt of the type M3X2...Ch. 16 - What mass of Ca(NO3O)2 must be added to 1.0 L of a...Ch. 16 - The Ksp for Q, a slightly soluble ionic compound...Ch. 16 - Aluminium ions react with the hydroxide ion to...
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