Consider the equation ∆G = ∆G ° + RT ln( Q ). What is the value of ∆ G for a reaction at equilibrium? What does Q equal at equilibrium? At equilibrium, the previous equation reduces to ∆G° = − RT ln( K ). When ∆ G ° > 0, what does it indicate about K ? When ∆G ° < 0, what does it indicate about K? When t ∆ G ° = 0, what does it indicate about K ? ∆G predicts spontaneity for a reaction, whereas ∆G ° predicts the equilibrium position. Explain what this statement means. Under what conditions can you use ∆ G ° to determine the spontaneity of a reaction?
Consider the equation ∆G = ∆G ° + RT ln( Q ). What is the value of ∆ G for a reaction at equilibrium? What does Q equal at equilibrium? At equilibrium, the previous equation reduces to ∆G° = − RT ln( K ). When ∆ G ° > 0, what does it indicate about K ? When ∆G ° < 0, what does it indicate about K? When t ∆ G ° = 0, what does it indicate about K ? ∆G predicts spontaneity for a reaction, whereas ∆G ° predicts the equilibrium position. Explain what this statement means. Under what conditions can you use ∆ G ° to determine the spontaneity of a reaction?
Consider the equation ∆G = ∆G° + RT ln(Q). What is the value of ∆G for a reaction at equilibrium? What does Q equal at equilibrium? At equilibrium, the previous equation reduces to ∆G° = −RT ln(K). When ∆G° > 0, what does it indicate about K? When ∆G° < 0, what does it indicate about K? When t ∆G° = 0, what does it indicate about K? ∆G predicts spontaneity for a reaction, whereas ∆G° predicts the equilibrium position. Explain what this statement means. Under what conditions can you use ∆G° to determine the spontaneity of a reaction?
Predict the major organic product(s) of the following reactions. Indicate which of the following mechanisms is in operation: SN1, SN2, E1, or E2.
(c)
(4pts)
Mechanism:
heat
(E1)
CH3OH
+
1.5pts each
_E1 _ (1pt)
Br
CH3OH
(d)
(4pts)
Mechanism:
SN1
(1pt)
(e)
(3pts)
1111 I
H
10
Ill!!
H
LDA
THF (solvent)
Mechanism: E2
(1pt)
NC
(f)
Bri!!!!!
CH3
NaCN
(3pts)
acetone
Mechanism: SN2
(1pt)
(SN1)
-OCH3
OCH3
1.5pts each
2pts for either product
1pt if incorrect
stereochemistry
H
Br
(g)
“,、
(3pts)
H
CH3OH
+21
Mechanism:
SN2
(1pt)
H
CH3
2pts
1pt if incorrect
stereochemistry
H
2pts
1pt if incorrect
stereochemistry
A mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixture
Chapter 16 Solutions
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