If you calculate a value for ∆ G ° for a reaction using the values of Δ G f ∘ in Appendix 4 and get a negative number, is it correct to say that the reaction is always spontaneous? Why or why not? Free energy changes also depend on concentration. For gases, how is G related to the pressure of the gas? What are standard pressures for gases and standard concentrations for solutes? How do you calculate ∆ G for a reaction at nonstandard conditions? The equation to determine ∆G at nonstandard conditions has Q in it: What is Q ? A reaction is spontaneous as long as ∆ G is negative; that is, reactions always proceed as long as the products have a lower free energy than the reactants. What is so special about equilibrium? Why don’t reactions move away from equilibrium?
If you calculate a value for ∆ G ° for a reaction using the values of Δ G f ∘ in Appendix 4 and get a negative number, is it correct to say that the reaction is always spontaneous? Why or why not? Free energy changes also depend on concentration. For gases, how is G related to the pressure of the gas? What are standard pressures for gases and standard concentrations for solutes? How do you calculate ∆ G for a reaction at nonstandard conditions? The equation to determine ∆G at nonstandard conditions has Q in it: What is Q ? A reaction is spontaneous as long as ∆ G is negative; that is, reactions always proceed as long as the products have a lower free energy than the reactants. What is so special about equilibrium? Why don’t reactions move away from equilibrium?
If you calculate a value for ∆G° for a reaction using the values of
Δ
G
f
∘
in Appendix 4 and get a negative number, is it correct to say that the reaction is always spontaneous? Why or why not? Free energy changes also depend on concentration. For gases, how is G related to the pressure of the gas? What are standard pressures for gases and standard concentrations for solutes? How do you calculate ∆G for a reaction at nonstandard conditions? The equation to determine ∆G at nonstandard conditions has Q in it: What is Q? A reaction is spontaneous as long as ∆G is negative; that is, reactions always proceed as long as the products have a lower free energy than the reactants. What is so special about equilibrium? Why don’t reactions move away from equilibrium?
A.
B.
b. Now consider the two bicyclic molecules A. and B. Note that A. is a dianion
and B. is a neutral molecule. One of these molecules is a highly reactive
compound first characterized in frozen noble gas matrices, that self-reacts
rapidly at temperatures above liquid nitrogen temperature. The other
compound was isolated at room temperature in the early 1960s, and is a
stable ligand used in organometallic chemistry. Which molecule is the more
stable molecule, and why?
Where are the chiral centers in this molecule? Also is this compound meso yes or no?
PLEASE HELP! URGENT!
Chapter 16 Solutions
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