The sign of Δ S ∘ is to be predicted in each case. Concept introduction: Entropy ( Δ S ∘ ) is the measure of degree of disorder or randomness. Increase in the randomness of the system leads to increase in the entropy (entropy is positive). The sign of entropy depends on the number of moles. If number of moles decreases, then sign of the entropy will be negative whereas, if the number of moles increases, the sign of entropy will be positive.
The sign of Δ S ∘ is to be predicted in each case. Concept introduction: Entropy ( Δ S ∘ ) is the measure of degree of disorder or randomness. Increase in the randomness of the system leads to increase in the entropy (entropy is positive). The sign of entropy depends on the number of moles. If number of moles decreases, then sign of the entropy will be negative whereas, if the number of moles increases, the sign of entropy will be positive.
Solution Summary: The author explains that the sign of DeltaScirc is to be predicted in each case.
Interpretation: The sign of
ΔS∘ is to be predicted in each case.
Concept introduction: Entropy
(ΔS∘) is the measure of degree of disorder or randomness. Increase in the randomness of the system leads to increase in the entropy (entropy is positive).
The sign of entropy depends on the number of moles. If number of moles decreases, then sign of the entropy will be negative whereas, if the number of moles increases, the sign of entropy will be positive.
(b)
Interpretation Introduction
Interpretation: The sign of
ΔS∘ is to be predicted in each case.
Concept introduction: Entropy
(ΔS∘) is the measure of degree of disorder or randomness. Increase in the randomness of the system leads to increase in the entropy (entropy is positive).
The sign of entropy depends on the number of moles. If number of moles decreases, then sign of the entropy will be negative whereas, if the number of moles increases, the sign of entropy will be positive.
(c)
Interpretation Introduction
Interpretation: The sign of
ΔS∘ is to be predicted in each case.
Concept introduction: Entropy
(ΔS∘) is the measure of degree of disorder or randomness. Increase in the randomness of the system leads to increase in the entropy (entropy is positive).
The sign of entropy depends on the number of moles. If number of moles decreases, then sign of the entropy will be negative whereas, if the number of moles increases, the sign of entropy will be positive.
(d)
Interpretation Introduction
Interpretation: The sign of
ΔS∘ is to be predicted in each case.
Concept introduction: Entropy
(ΔS∘) is the measure of degree of disorder or randomness. Increase in the randomness of the system leads to increase in the entropy (entropy is positive).
The sign of entropy depends on the number of moles. If number of moles decreases, then sign of the entropy will be negative whereas, if the number of moles increases, the sign of entropy will be positive.
Predict the major organic product(s) of the following reactions. Indicate which of the following mechanisms is in operation: SN1, SN2, E1, or E2.
(c)
(4pts)
Mechanism:
heat
(E1)
CH3OH
+
1.5pts each
_E1 _ (1pt)
Br
CH3OH
(d)
(4pts)
Mechanism:
SN1
(1pt)
(e)
(3pts)
1111 I
H
10
Ill!!
H
LDA
THF (solvent)
Mechanism: E2
(1pt)
NC
(f)
Bri!!!!!
CH3
NaCN
(3pts)
acetone
Mechanism: SN2
(1pt)
(SN1)
-OCH3
OCH3
1.5pts each
2pts for either product
1pt if incorrect
stereochemistry
H
Br
(g)
“,、
(3pts)
H
CH3OH
+21
Mechanism:
SN2
(1pt)
H
CH3
2pts
1pt if incorrect
stereochemistry
H
2pts
1pt if incorrect
stereochemistry
A mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixture
Chapter 16 Solutions
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The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY