
(a)
Interpretation:
To explain the reason for not obtaining the ester by dissolving by dissolving
Concept introduction:
Esterificationis the process in which
(b)
Interpretation:
To explain the reason methyl ester can form by dissolving
Concept introduction:
Esterificationis the process in which carboxylic acid reacts with alcohol in the presence of an acid to produce an ester. Carboxylic acid undergoes nucleophilicsubstitution reaction. The acid protonates the oxygen of carboxylic acid which results in increased electrophilicity of the carbonyl carbon. The alcohol acts as a nucleophile and gets attached to the carbonyl carbon of the carboxylic acid. Proton transfer takes place between alkoxy group and a hydroxy group. Water molecule gets eliminated from the tetrahedral intermediate. The proton releases from the carbonyl oxygen to form ester.

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Chapter 16 Solutions
Organic Chemistry
- Where are the chiral centers in this molecule? Also is this compound meso yes or no?arrow_forwardA mixture of C7H12O2, C9H9OCl, biphenyl and acetone was put together in a gas chromatography tube. Please decide from the GC resutls which correspond to the peak for C7,C9 and biphenyl and explain the reasoning based on GC results. Eliminate unnecessary peaks from Gas Chromatography results.arrow_forwardIs the molecule chiral, meso, or achiral? CI .CH3 H₂C CIarrow_forward
- A mixture of three compounds Phen-A, Acet-B and Rin-C was analyzed using TLC with 1:9 ethanol: hexane as the mobile phase. The TLC plate showed three spots of R, 0.1 and 0.2 and 0.3. Which of the three compounds (Phen-A; Acet-B or Rin-C) would have the highest (Blank 1), middle (Blank 2) and lowest (Blank 3) spot respectively? 0 CH: 0 CH, 0 H.C OH H.CN OH Acet-B Rin-C phen-A A A <arrow_forwardHow many chiral carbons are in the molecule? Farrow_forwardcan someone give the curly arrow mechanism for this reaction written with every intermediate and all the side products pleasearrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
