Natural gas, which is mostly methane, CH 4 , is a resource that the United States has in abundance. In principle, ethane can be obtained from methane by the reaction 2 CH 4 ( g ) → C 2 H 6 ( g ) + H 2 ( g ) (a) Calculate ΔG ° at 25°C for the reaction. Comment on the feasibility of this reaction at 25°C. (b) Couple the reaction above with the formation of steam from the elements: H 2 ( g ) + 1 2 O 2 ( g ) → H 2 O ( g ) Δ G ° = − 228.6 kJ What is the equation for the overall reaction? Comment on the feasibility of the overall reaction.
Natural gas, which is mostly methane, CH 4 , is a resource that the United States has in abundance. In principle, ethane can be obtained from methane by the reaction 2 CH 4 ( g ) → C 2 H 6 ( g ) + H 2 ( g ) (a) Calculate ΔG ° at 25°C for the reaction. Comment on the feasibility of this reaction at 25°C. (b) Couple the reaction above with the formation of steam from the elements: H 2 ( g ) + 1 2 O 2 ( g ) → H 2 O ( g ) Δ G ° = − 228.6 kJ What is the equation for the overall reaction? Comment on the feasibility of the overall reaction.
Solution Summary: The author explains the Gibbs free energy, G, which governs the spontaneity of a chemical reaction.
Natural gas, which is mostly methane, CH4, is a resource that the United States has in abundance. In principle, ethane can be obtained from methane by the reaction
2
CH
4
(
g
)
→
C
2
H
6
(
g
)
+
H
2
(
g
)
(a) Calculate ΔG° at 25°C for the reaction. Comment on the feasibility of this reaction at 25°C. (b) Couple the reaction above with the formation of steam from the elements:
H
2
(
g
)
+
1
2
O
2
(
g
)
→
H
2
O
(
g
)
Δ
G
°
=
−
228.6
kJ
What is the equation for the overall reaction? Comment on the feasibility of the overall reaction.
A complete tensile test was performed on a magnesium
specimen of 12 mm diameter and 30 mm length, until breaking.
The specimen is assumed to maintain a constant volume.
Calculate the approximate value of the actual stress at breaking.
TABLE. The tensile force F and the length of the specimen are
represented for each L until breaking.
F/N
L/mm
0
30,0000
30,0296
5000
10000 30,0592
15000 30,0888
20000
30,15
25000 30,51
26500
30,90
27000
31,50
26500
32,10
25000 32,79
None
Differentiate between plastic deformation, elastic deformation, viscoelastic deformation and viscoplastic deformation.
Chapter 16 Solutions
Student Solutions Manual For Masterton/hurley's Chemistry: Principles And Reactions, 8th
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