Chemistry
9th Edition
ISBN: 9781133611097
Author: Steven S. Zumdahl
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 16, Problem 61E
Write equations for the stepwise formation of each of the following complex ions.
a. Ni(CN)42−
b. V(C2O4)33−
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
68. In the presence of NH 3, Cu+2 forms the complex ion
Cu(NH3) 4+2. If the equilibrium concentrations of Cu+2 and
Cu(NH3) 4+ are 1.8 x 10-17 M and 1.0 x 10-3 M, respectively, in
a 1.5 M NH3 solution, calculate the value for the overall
formation constant of Cu(NH3)+2.
Cu+2 + 4 NH3 -> Cu(NH3) 4+2
25. Consider a system that includes both the Al(OH)3(s) (Ksp = 3 x 10-34) and the complex ion [Al(OH)4]- (Kf = 3 x 1033). What would be the effect of decreasing the pH of the solution?
A. The mass of Al(OH)3 would increase.
B. The concentration of [Al(OH)4]-would increase.
C. The concentration of [OH-] (aq) would increase.
D. Adjusting the pH would not impact the concentration of any of the species in solution.
The answer is A, but can youp lease help explain why this is true? Thanks!
Please explain steps.
Chapter 16 Solutions
Chemistry
Ch. 16 - To what reaction does the solubility product...Ch. 16 - Under what circumstances can you compare the...Ch. 16 - What is a common ion and how does its presence...Ch. 16 - List some salts whose solubility increases as the...Ch. 16 - What is the difference between the ion product, Q,...Ch. 16 - Mixtures of metal ions in aqueous solution can...Ch. 16 - Prob. 7RQCh. 16 - What is a complex ion? The stepwise formation...Ch. 16 - When 5 M ammonia is added to a solution containing...Ch. 16 - Figure 15-3 outlines the classic scheme for...
Ch. 16 - Which of the following will affect the total...Ch. 16 - Prob. 2ALQCh. 16 - You are browsing through the Handbook of...Ch. 16 - A friend tells you: The constant Ksp of a salt is...Ch. 16 - Explain the following phenomenon: You have a test...Ch. 16 - What happens to the Ksp value of a solid as the...Ch. 16 - Which is more likely to dissolve in an acidic...Ch. 16 - For which of the following is the Ksp value of the...Ch. 16 - Ag2S(s) has a larger molar solubility than CuS...Ch. 16 - Solubility is an equilibrium position, whereas Ksp...Ch. 16 - Prob. 11QCh. 16 - Prob. 12QCh. 16 - The common ion effect for ionic solids (salts) is...Ch. 16 - Sulfide precipitates are generally grouped as...Ch. 16 - List some ways one can increase the solubility of...Ch. 16 - The stepwise formation constants for a complex ion...Ch. 16 - Silver chloride dissolves readily in 2 M NH3 but...Ch. 16 - If a solution contains either Pb2+(aq) or Ag+(aq),...Ch. 16 - Write balanced equations for the dissolution...Ch. 16 - Write balanced equations for the dissolution...Ch. 16 - Prob. 21ECh. 16 - Use the following data to calculate the Ksp value...Ch. 16 - Approximately 0.14 g nickel(II) hydroxide,...Ch. 16 - The solubility of the ionic compound M2X3, having...Ch. 16 - The concentration of Pb2+ in a solution saturated...Ch. 16 - The concentration of Ag+ in a solution saturated...Ch. 16 - Calculate the solubility of each of the following...Ch. 16 - Calculate the solubility of each of the following...Ch. 16 - Cream of tartar, a common ingredient in cooking,...Ch. 16 - Barium sulfate is a contrast agent for X-ray scans...Ch. 16 - Calculate the molar solubility of Mg (OH)2, Ksp =...Ch. 16 - Prob. 32ECh. 16 - Calculate the molar solubility of Al(OH)3, Ksp = 2...Ch. 16 - Calculate the molar solubility of Co(OH)3, Ksp =...Ch. 16 - For each of the following pairs of solids,...Ch. 16 - For each of the following pairs of solids,...Ch. 16 - Calculate the solubility (in moles per liter) of...Ch. 16 - Calculate the solubility of Co(OH)2(s) (Ksp = 2.5 ...Ch. 16 - The Ksp for silver sulfate (Ag2SO4) is 1.2 105....Ch. 16 - The Ksp for lead iodide (PbI2) is 1.4 108....Ch. 16 - Calculate the solubility of solid Ca3(PO4)2 (Ksp =...Ch. 16 - Calculate the solubility of solid Pb3(P04)2 (Ksp =...Ch. 16 - Prob. 43ECh. 16 - The solubility of Pb(IO3)(s) in a 0.10-M KIO3...Ch. 16 - Which of the substances in Exercises 27 and 28...Ch. 16 - For which salt in each of the following groups...Ch. 16 - What mass of ZnS (Ksp = 2.5 1022) will dissolve...Ch. 16 - The concentration of Mg2+ in seawater is 0.052 M....Ch. 16 - Will a precipitate form when 100.0 mL of 4.0 104...Ch. 16 - A solution contains 1.0 105 M Ag+ and 2.0 106 M...Ch. 16 - A solution is prepared by mixing 100.0 mL of 1.0 ...Ch. 16 - Prob. 52ECh. 16 - Calculate the final concentrations of K+(aq),...Ch. 16 - A solution is prepared by mixing 75.0 mL of 0.020...Ch. 16 - A 50.0-mL sample of 0.00200 M AgNO3 is added to...Ch. 16 - Prob. 56ECh. 16 - A solution contains 1.0 105 M Na3PO4. What is the...Ch. 16 - The Ksp of Al(OH)3 is 2 1032. At what pH will a...Ch. 16 - A solution is 1 104 M in NaF, Na2S, and Na3PO4....Ch. 16 - A solution contains 0.25 M Ni(NO3)2 and 0.25 M...Ch. 16 - Write equations for the stepwise formation of each...Ch. 16 - Write equations for the stepwise formation of each...Ch. 16 - In the presence of CN, Fe3+ forms the complex ion...Ch. 16 - In the presence of NH3, Cu2+ forms the complex ion...Ch. 16 - Prob. 65ECh. 16 - Prob. 66ECh. 16 - The overall formation constant for HgI42 is 1.0 ...Ch. 16 - A solution is prepared by adding 0.10 mole of...Ch. 16 - A solution is formed by mixing 50.0 mL of 10.0 M...Ch. 16 - A solution is prepared by mixing 100.0 mL of 1.0 ...Ch. 16 - a. Calculate the molar solubility of AgI in pure...Ch. 16 - Solutions of sodium thiosulfate are used to...Ch. 16 - Kf for the complex ion Ag(NH3)2+ is 1.7 107. Ksp...Ch. 16 - Prob. 74ECh. 16 - Prob. 75ECh. 16 - The solubility of copper(II) hydroxide in water...Ch. 16 - A solution contains 0.018 mole each of I, Br, and...Ch. 16 - You have two salts, AgX and AgY, with very similar...Ch. 16 - Tooth enamel is composed of the mineral...Ch. 16 - The U.S. Public Health Service recommends the...Ch. 16 - Prob. 81AECh. 16 - Calculate the mass of manganese hydroxide present...Ch. 16 - Prob. 83AECh. 16 - The active ingredient of Pepto-Bismol is the...Ch. 16 - Nanotechnology has become an important field, with...Ch. 16 - The equilibrium constant for the following...Ch. 16 - Calculate the concentration of Pb2+ in each of the...Ch. 16 - Will a precipitate of Cd(OH)2 form if 1.0 mL of...Ch. 16 - a. Using the Ksp value for Cu(OH)2 (1.6 1019) and...Ch. 16 - Describe how you could separate the ions in each...Ch. 16 - The solubility rules outlined in Chapter 4 say...Ch. 16 - In the chapter discussion of precipitate...Ch. 16 - Assuming that the solubility of Ca3(PO4)2(s) is...Ch. 16 - Order the following solids (ad) from least soluble...Ch. 16 - The Ksp for PbI2(s) 1.4 108. Calculate the...Ch. 16 - The solubility of Pb(IO3)2(s) in a 7.2 102-M KIO3...Ch. 16 - A 50.0-mL sample of 0.0413 M AgNO3(aq) is added to...Ch. 16 - Prob. 99CPCh. 16 - Prob. 100CPCh. 16 - a. Calculate the molar solubility of AgBr in pure...Ch. 16 - Calculate the equilibrium concentrations of NH3,...Ch. 16 - Calculate the solubility of AgCN(s) (Ksp = 2.2 ...Ch. 16 - Calcium oxalate (CaC2O4) is relatively insoluble...Ch. 16 - A solution saturated with a salt of the type M3X2...Ch. 16 - Consider 1.0 L of an aqueous solution that...Ch. 16 - The Ksp for Q, a slightly soluble ionic compound...Ch. 16 - Aluminium ions react with the hydroxide ion to...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Write equations for the stepwise formation of each of the following complex ions. a. Ni(CN)42 b. V(C2O4)33arrow_forwardThe solubility of cadmium oxalate. CdC2O4, in 0.150 M ammonia is 6.1 103 mol/L. What is the oxalate-ion concentration in the saturated solution? If the solubility product constant for cadmium oxalate is 1.5 108, what must be the cadmium-ion concentration in the solution? Now calculate the formation constant for the complex ion Cd(NH3)42+.arrow_forwardWhat is a complex ion? The stepwise formation constants for the complex ion Cu(NH3)42+ are K1 1 103, K2 1 104, K3 = 1 103, and K4 1 103. Write the reactions that refer to each of these formation constants. Given that the values of the formation constants are large, what can you deduce about the equilibrium concentration of Cu(NH3)42+ versus the equilibrium concentration of Cu2+?arrow_forward
- Refer to Appendix J for solubility products for calcium salts. Determine which of the calcium salts listed is most soluble in moles per liter and which is most soluble in grams per liter.arrow_forwardPredict whether nickel(II) hydroxide, Ni(OH)2, will precipitate from a solution that is 0.0020 M NiSO4, 0.010 M NaOH, and 0.10 M NH3. Note that nickel(II) ion forms the Ni(NH3)62+ complex ion.arrow_forwardCalculate the solubility of copper(II) iodate, Cu(IO3)2 (Ksp = 7.4 108), in (a) water. (b) a 0.10 M copper(II) nitrate solution.arrow_forward
- A Boric acid and glycerin form a complex B(OH)3(aq) + glycerin(aq) B(OH)3 glycerin(aq) with an equilibrium constant of 0.90. If the concentration of boric acid is 0.10 M, how much glycerin should be added, per liter, so that 60.% of the boric acid is in the form of the complex?arrow_forwardA solution contains 1.0 105 M Na3PO4. What is the minimum concentration of AgNO3 that would cause precipitation of solid Ag3PO4 (Ksp = 1.8 1018)arrow_forwardSometimes equilibria fur complex ions are described in terms of dissociation constants. Kd . For the complex ion AlF63- the dissociation reaction is: AlF63Al3++6F and Kd=[Al3+][F]6[AlF63]=21024 Calculate the value of the formation constant, Kf, for AlF63-.arrow_forward
- . Chromiurn(III) hydroxide dissolves in water only to the extent of 8.21105M at 25 °C. Calculate Kspfor Cr(OH)3at this temperature.arrow_forwardUnder what circumstances, if any, does a sample of solid AgCl completely dissolve in pure water?arrow_forwardWhich of the following compounds precipitates from a solution that has the concentrations indicated? (See Appendix J for Ksp values.) (a) CaCO3:[Ca2+]=0.003M,[CO32]=0.003M (b) CO(OH)2:[CO2+]=0.01M,[OH]=1107M (c) CaHPO4:[Ca2+]=0.01M,[HPO42]=2106M (d) Pb3(PO4)2:[Pb2+]=0.01M,[PO43]=11013Marrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
General Chemistry | Acids & Bases; Author: Ninja Nerd;https://www.youtube.com/watch?v=AOr_5tbgfQ0;License: Standard YouTube License, CC-BY