Chemistry
9th Edition
ISBN: 9781133611097
Author: Steven S. Zumdahl
Publisher: Cengage Learning
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Textbook Question
Chapter 16, Problem 10RQ
Figure 15-3 outlines the classic scheme for separating a mixture of insoluble chloride salts from one another. Explain the chemistry involved in the various steps of the figure.
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Ethanol is needed as solvent when preparing phenolphthalein color indicator in volumetric titrations. What class of ethanol best suits the intended purpose? Explain your answer.
Suppose a student performed a similar standardization titration experiment. Below is the calculated concentration of NaOH from each of their titrations.
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Titration #2
Titration #3
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11 of 14
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Chapter 16 Solutions
Chemistry
Ch. 16 - To what reaction does the solubility product...Ch. 16 - Under what circumstances can you compare the...Ch. 16 - What is a common ion and how does its presence...Ch. 16 - List some salts whose solubility increases as the...Ch. 16 - What is the difference between the ion product, Q,...Ch. 16 - Mixtures of metal ions in aqueous solution can...Ch. 16 - Prob. 7RQCh. 16 - What is a complex ion? The stepwise formation...Ch. 16 - When 5 M ammonia is added to a solution containing...Ch. 16 - Figure 15-3 outlines the classic scheme for...
Ch. 16 - Which of the following will affect the total...Ch. 16 - Prob. 2ALQCh. 16 - You are browsing through the Handbook of...Ch. 16 - A friend tells you: The constant Ksp of a salt is...Ch. 16 - Explain the following phenomenon: You have a test...Ch. 16 - What happens to the Ksp value of a solid as the...Ch. 16 - Which is more likely to dissolve in an acidic...Ch. 16 - For which of the following is the Ksp value of the...Ch. 16 - Ag2S(s) has a larger molar solubility than CuS...Ch. 16 - Solubility is an equilibrium position, whereas Ksp...Ch. 16 - Prob. 11QCh. 16 - Prob. 12QCh. 16 - The common ion effect for ionic solids (salts) is...Ch. 16 - Sulfide precipitates are generally grouped as...Ch. 16 - List some ways one can increase the solubility of...Ch. 16 - The stepwise formation constants for a complex ion...Ch. 16 - Silver chloride dissolves readily in 2 M NH3 but...Ch. 16 - If a solution contains either Pb2+(aq) or Ag+(aq),...Ch. 16 - Write balanced equations for the dissolution...Ch. 16 - Write balanced equations for the dissolution...Ch. 16 - Prob. 21ECh. 16 - Use the following data to calculate the Ksp value...Ch. 16 - Approximately 0.14 g nickel(II) hydroxide,...Ch. 16 - The solubility of the ionic compound M2X3, having...Ch. 16 - The concentration of Pb2+ in a solution saturated...Ch. 16 - The concentration of Ag+ in a solution saturated...Ch. 16 - Calculate the solubility of each of the following...Ch. 16 - Calculate the solubility of each of the following...Ch. 16 - Cream of tartar, a common ingredient in cooking,...Ch. 16 - Barium sulfate is a contrast agent for X-ray scans...Ch. 16 - Calculate the molar solubility of Mg (OH)2, Ksp =...Ch. 16 - Prob. 32ECh. 16 - Calculate the molar solubility of Al(OH)3, Ksp = 2...Ch. 16 - Calculate the molar solubility of Co(OH)3, Ksp =...Ch. 16 - For each of the following pairs of solids,...Ch. 16 - For each of the following pairs of solids,...Ch. 16 - Calculate the solubility (in moles per liter) of...Ch. 16 - Calculate the solubility of Co(OH)2(s) (Ksp = 2.5 ...Ch. 16 - The Ksp for silver sulfate (Ag2SO4) is 1.2 105....Ch. 16 - The Ksp for lead iodide (PbI2) is 1.4 108....Ch. 16 - Calculate the solubility of solid Ca3(PO4)2 (Ksp =...Ch. 16 - Calculate the solubility of solid Pb3(P04)2 (Ksp =...Ch. 16 - Prob. 43ECh. 16 - The solubility of Pb(IO3)(s) in a 0.10-M KIO3...Ch. 16 - Which of the substances in Exercises 27 and 28...Ch. 16 - For which salt in each of the following groups...Ch. 16 - What mass of ZnS (Ksp = 2.5 1022) will dissolve...Ch. 16 - The concentration of Mg2+ in seawater is 0.052 M....Ch. 16 - Will a precipitate form when 100.0 mL of 4.0 104...Ch. 16 - A solution contains 1.0 105 M Ag+ and 2.0 106 M...Ch. 16 - A solution is prepared by mixing 100.0 mL of 1.0 ...Ch. 16 - Prob. 52ECh. 16 - Calculate the final concentrations of K+(aq),...Ch. 16 - A solution is prepared by mixing 75.0 mL of 0.020...Ch. 16 - A 50.0-mL sample of 0.00200 M AgNO3 is added to...Ch. 16 - Prob. 56ECh. 16 - A solution contains 1.0 105 M Na3PO4. What is the...Ch. 16 - The Ksp of Al(OH)3 is 2 1032. At what pH will a...Ch. 16 - A solution is 1 104 M in NaF, Na2S, and Na3PO4....Ch. 16 - A solution contains 0.25 M Ni(NO3)2 and 0.25 M...Ch. 16 - Write equations for the stepwise formation of each...Ch. 16 - Write equations for the stepwise formation of each...Ch. 16 - In the presence of CN, Fe3+ forms the complex ion...Ch. 16 - In the presence of NH3, Cu2+ forms the complex ion...Ch. 16 - Prob. 65ECh. 16 - Prob. 66ECh. 16 - The overall formation constant for HgI42 is 1.0 ...Ch. 16 - A solution is prepared by adding 0.10 mole of...Ch. 16 - A solution is formed by mixing 50.0 mL of 10.0 M...Ch. 16 - A solution is prepared by mixing 100.0 mL of 1.0 ...Ch. 16 - a. Calculate the molar solubility of AgI in pure...Ch. 16 - Solutions of sodium thiosulfate are used to...Ch. 16 - Kf for the complex ion Ag(NH3)2+ is 1.7 107. Ksp...Ch. 16 - Prob. 74ECh. 16 - Prob. 75ECh. 16 - The solubility of copper(II) hydroxide in water...Ch. 16 - A solution contains 0.018 mole each of I, Br, and...Ch. 16 - You have two salts, AgX and AgY, with very similar...Ch. 16 - Tooth enamel is composed of the mineral...Ch. 16 - The U.S. Public Health Service recommends the...Ch. 16 - Prob. 81AECh. 16 - Calculate the mass of manganese hydroxide present...Ch. 16 - Prob. 83AECh. 16 - The active ingredient of Pepto-Bismol is the...Ch. 16 - Nanotechnology has become an important field, with...Ch. 16 - The equilibrium constant for the following...Ch. 16 - Calculate the concentration of Pb2+ in each of the...Ch. 16 - Will a precipitate of Cd(OH)2 form if 1.0 mL of...Ch. 16 - a. Using the Ksp value for Cu(OH)2 (1.6 1019) and...Ch. 16 - Describe how you could separate the ions in each...Ch. 16 - The solubility rules outlined in Chapter 4 say...Ch. 16 - In the chapter discussion of precipitate...Ch. 16 - Assuming that the solubility of Ca3(PO4)2(s) is...Ch. 16 - Order the following solids (ad) from least soluble...Ch. 16 - The Ksp for PbI2(s) 1.4 108. Calculate the...Ch. 16 - The solubility of Pb(IO3)2(s) in a 7.2 102-M KIO3...Ch. 16 - A 50.0-mL sample of 0.0413 M AgNO3(aq) is added to...Ch. 16 - Prob. 99CPCh. 16 - Prob. 100CPCh. 16 - a. Calculate the molar solubility of AgBr in pure...Ch. 16 - Calculate the equilibrium concentrations of NH3,...Ch. 16 - Calculate the solubility of AgCN(s) (Ksp = 2.2 ...Ch. 16 - Calcium oxalate (CaC2O4) is relatively insoluble...Ch. 16 - A solution saturated with a salt of the type M3X2...Ch. 16 - Consider 1.0 L of an aqueous solution that...Ch. 16 - The Ksp for Q, a slightly soluble ionic compound...Ch. 16 - Aluminium ions react with the hydroxide ion to...
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Practice Problem ATTEMPT
Write the rate expressions for each of the following reactions:
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Practice Problem ATTEMPT
Write the rate expressions for each of the following reactions:
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- Suppose a student performed a similar standardization titration experiment. Below is the calculated concentration of NaOH from each of their titrations. Titration #1 Titration #2 Titration #3 The concentration of NaOH (M) 0.9554 0.9540 0.9551 Using the 3 concentrations, calculate the average concentration of the student's NaOH solution and calculate the ± error in parts per thousand (ppt). Show the complete calculation. Express your final answer in the form of average (with units) ± error in ppt.arrow_forwardoption É command command option REDOX TITRATIONS Part C. Answer the following questions as part of your lab report: 1. A standardized KMNO4 solution can be used to analyse compounds of unknown composition. One such compound is hydrated calcium oxalate, CaC204-x H2O. The degree of hydration is usually not known and may be determined based on the balanced equation below, by titrating a weighed sample of the hydrated calcium oxalate with KMNO4. 5 H2C2O4(aq) + 2 MnO4 (aq) + 6 H*(aq) → 10 CO2(g) + 2 Mn2"(aq) + 8 H20(1) EE MP If a 0.3215 g sample of CaC204-x H2O required 32.28 mL of a 0.02426 M KMNO4 solution, what would be the value of x? (Round your answer to the nearest integer.) Show all your calculations. Write the formula of the hydrate. table f5 graph lear H Marrow_forwardDrag and drop the terms to label this diagram of a titration apparatus accurately. burette stopcock ●NAAAAIANNI titrant Erlenmeyer flask (tube) (solution) 11 (container) (solution) clamp sample solutionarrow_forward
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- Which is the correct order of steps in the preparation of a hydrochoric acid standard solution with sodium bicarbonate standard solution. I. Dissolved sodium carbonate (13.25 g) in about 150 mL of distilled water in a beaker II. Solution of sodium carbonate was transferred into a volumetric flask and diluted to mark before mixing. III. Weigh the appropriate amount of the primary standard. IV. Titrate with enough volume of the acid to completely neutralize the base. V. Transfer 10.00 ml primary standard into an erlenmeyer flask and add indicator III, I, II, V, IV III, II, I, V, IV V, III, I, II, IV V, IV, III, I, IIarrow_forward8arrow_forward11.An acid-base equilibrium system is created by dissolving 0.20mol CH3COOH in water and diluting the resulting solution to a volume of 1.0 L. What is the effect of adding 0.020 mol CH3COO (aq) to this solution? How will pH change (calculate pH before and after the addition. Ka of CH3COOH is 1.76 x10-5)? How will concentrations of CH3COOH and CH3COO at equilibrium change?arrow_forward
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