Chemistry In Focus
Chemistry In Focus
7th Edition
ISBN: 9781337399692
Author: Tro, Nivaldo J.
Publisher: Cengage Learning,
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Chapter 16, Problem 49E
Interpretation Introduction

Interpretation:

The carbohydrate is to be identified from among the given molecules.

Concept Introduction:

Carbohydrates are polyhydroxy aldehydes or ketones, or their derivatives.

Straight-chain carbohydrates are characterized by the presence of a C=O group, OH groups along the chain, and a CH2OH group.

Ring-form carbohydrates are characterized by the presence of a ring containing carbon atoms and one oxygen atom. The ring also contains OH and CH2OH groups.

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Part I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400
• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peak
Could you redraw these and also explain how to solve them for me pleas

Chapter 16 Solutions

Chemistry In Focus

Ch. 16 - DNA Complementarity Draw the complementary strand...Ch. 16 - List the four major classes of biochemical...Ch. 16 - Why are fats more efficient than carbohydrates for...Ch. 16 - Prob. 3ECh. 16 - Prob. 4ECh. 16 - Prob. 5ECh. 16 - Why do carbohydrates contain less energy per gram...Ch. 16 - Prob. 7ECh. 16 - Prob. 8ECh. 16 - Prob. 9ECh. 16 - Prob. 10ECh. 16 - Prob. 11ECh. 16 - Prob. 12ECh. 16 - Prob. 13ECh. 16 - Prob. 14ECh. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Prob. 17ECh. 16 - Prob. 18ECh. 16 - Prob. 19ECh. 16 - Prob. 20ECh. 16 - Prob. 21ECh. 16 - Prob. 22ECh. 16 - Prob. 23ECh. 16 - What is the difference between DNA and RNA?Ch. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - What are chromosomes? How many exist in humans?Ch. 16 - Prob. 28ECh. 16 - Prob. 29ECh. 16 - Prob. 30ECh. 16 - Draw a schematic diagram of DNA. Show the...Ch. 16 - Prob. 32ECh. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - Explain how recombinant DNA technology has made...Ch. 16 - Prob. 36ECh. 16 - Prob. 37ECh. 16 - How can genetic engineering be used to treat...Ch. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - What are the dangers inherent in applying genetic...Ch. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - Prob. 45ECh. 16 - Prob. 46ECh. 16 - Prob. 47ECh. 16 - Prob. 48ECh. 16 - Prob. 49ECh. 16 - Prob. 50ECh. 16 - Prob. 51ECh. 16 - Prob. 52ECh. 16 - Prob. 53ECh. 16 - Prob. 54ECh. 16 - Which molecule is an amino acid?Ch. 16 - Which molecule is an amino acid?Ch. 16 - Prob. 57ECh. 16 - Classify each molecule as a lipid, carbohydrate,...Ch. 16 - Prob. 59ECh. 16 - Draw the structure for the dipeptide Ala-Gly. How...Ch. 16 - Draw the structure for the tripeptide Leu-Leu-Leu....Ch. 16 - Draw the structure for the tripeptide Ser-Ser-Ser....Ch. 16 - Prob. 63ECh. 16 - Prob. 64ECh. 16 - Prob. 65ECh. 16 - Prob. 66ECh. 16 - Prob. 67ECh. 16 - Prob. 68ECh. 16 - Prob. 69ECh. 16 - Prob. 70ECh. 16 - Prob. 71ECh. 16 - Prob. 72ECh. 16 - Prob. 73E
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