Chemistry In Focus
7th Edition
ISBN: 9781337399692
Author: Tro, Nivaldo J.
Publisher: Cengage Learning,
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Chapter 16, Problem 38E
How can genetic engineering be used to treat certain diseases?
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3.
a.
Use the MS to propose at least two possible molecular formulas.
For an unknown compound:
101.
27.0
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41.0
50.0
52.0
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57.5
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58.5
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63.0
64.0
65.0
74.0
40
75.0
76.0
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60
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120
140
160
180
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m/z
99.5
68564810898409581251883040
115.0
116.0
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33.5
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36
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1.2
157.0
2.1
159.0
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Relative Intensity
2
2
8
ō (ppm)
6
2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
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4
2
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200
150
100
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ō (ppm)
LOD
D
4000
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HAVENUMBERI -11
Chapter 16 Solutions
Chemistry In Focus
Ch. 16 - Prob. 1SCCh. 16 - Prob. 2SCCh. 16 - Prob. 3SCCh. 16 - Prob. 4SCCh. 16 - Prob. 16.1YTCh. 16 - Saturated and Unsaturated Fats Which of the...Ch. 16 - Prob. 16.3YTCh. 16 - Prob. 16.4YTCh. 16 - Identifying Amino Acids Which of the following...Ch. 16 - Drawing Peptide Structures Draw the tripeptide...
Ch. 16 - DNA Complementarity Draw the complementary strand...Ch. 16 - List the four major classes of biochemical...Ch. 16 - Why are fats more efficient than carbohydrates for...Ch. 16 - Prob. 3ECh. 16 - Prob. 4ECh. 16 - Prob. 5ECh. 16 - Why do carbohydrates contain less energy per gram...Ch. 16 - Prob. 7ECh. 16 - Prob. 8ECh. 16 - Prob. 9ECh. 16 - Prob. 10ECh. 16 - Prob. 11ECh. 16 - Prob. 12ECh. 16 - Prob. 13ECh. 16 - Prob. 14ECh. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Prob. 17ECh. 16 - Prob. 18ECh. 16 - Prob. 19ECh. 16 - Prob. 20ECh. 16 - Prob. 21ECh. 16 - Prob. 22ECh. 16 - Prob. 23ECh. 16 - What is the difference between DNA and RNA?Ch. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - What are chromosomes? How many exist in humans?Ch. 16 - Prob. 28ECh. 16 - Prob. 29ECh. 16 - Prob. 30ECh. 16 - Draw a schematic diagram of DNA. Show the...Ch. 16 - Prob. 32ECh. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - Explain how recombinant DNA technology has made...Ch. 16 - Prob. 36ECh. 16 - Prob. 37ECh. 16 - How can genetic engineering be used to treat...Ch. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - What are the dangers inherent in applying genetic...Ch. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - Prob. 45ECh. 16 - Prob. 46ECh. 16 - Prob. 47ECh. 16 - Prob. 48ECh. 16 - Prob. 49ECh. 16 - Prob. 50ECh. 16 - Prob. 51ECh. 16 - Prob. 52ECh. 16 - Prob. 53ECh. 16 - Prob. 54ECh. 16 - Which molecule is an amino acid?Ch. 16 - Which molecule is an amino acid?Ch. 16 - Prob. 57ECh. 16 - Classify each molecule as a lipid, carbohydrate,...Ch. 16 - Prob. 59ECh. 16 - Draw the structure for the dipeptide Ala-Gly. How...Ch. 16 - Draw the structure for the tripeptide Leu-Leu-Leu....Ch. 16 - Draw the structure for the tripeptide Ser-Ser-Ser....Ch. 16 - Prob. 63ECh. 16 - Prob. 64ECh. 16 - Prob. 65ECh. 16 - Prob. 66ECh. 16 - Prob. 67ECh. 16 - Prob. 68ECh. 16 - Prob. 69ECh. 16 - Prob. 70ECh. 16 - Prob. 71ECh. 16 - Prob. 72ECh. 16 - Prob. 73E
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- 16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してしarrow_forward3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CNarrow_forwardShow work..don't give Ai generated solution...arrow_forward
- Label the spectrum with spectroscopyarrow_forwardQ1: Draw the most stable and the least stable Newman projections about the C2-C3 bond for each of the following isomers (A-C). Are the barriers to rotation identical for enantiomers A and B? How about the diastereomers (A versus C or B versus C)? enantiomers H Br H Br (S) CH3 H3C (S) (R) CH3 H3C H Br A Br H C H Br H3C (R) B (R)CH3 H Br H Br H3C (R) (S) CH3 Br H D identicalarrow_forwardLabel the spectrumarrow_forward
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Nucleic acids - DNA and RNA structure; Author: MEDSimplified;https://www.youtube.com/watch?v=0lZRAShqft0;License: Standard YouTube License, CC-BY