Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 16, Problem 49E
An irregularly shaped metal part made from a particular alloy was galvanized with zinc using a
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hybridization of nitrogen of complex molecules
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NO2 (g) = N2O4(g)
AGº = -5.4 kJ
Now suppose a reaction vessel is filled with 4.53 atm of dinitrogen tetroxide (N2O4) at 279. °C. Answer the following questions about this system:
Under these conditions, will the pressure of N2O4 tend to rise or fall?
Is it possible to reverse this tendency by adding NO2?
In other words, if you said the pressure of N2O4 will tend to rise, can that
be changed to a tendency to fall by adding NO2? Similarly, if you said the
pressure of N2O4 will tend to fall, can that be changed to a tendency to
'2'
rise by adding NO2?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO 2 needed to reverse it.
Round your answer to 2 significant digits.
00
rise
☐ x10
fall
yes
no
☐ atm
G
Ar
1
Why do we analyse salt?
Chapter 16 Solutions
Chemistry Atoms First2e
Ch. 16 - Identify each half-reaction below as either...Ch. 16 - Identify each half-reaction below as either...Ch. 16 - Assuming each pair of half-reactions below takes...Ch. 16 - Balance the equations below assuming they occur in...Ch. 16 - Identify the oxidant and reductant of each...Ch. 16 - Balance the equations below assuming they occur in...Ch. 16 - Identify the oxidant and reductant of each...Ch. 16 - Why dont hydroxide ions appear in equations for...Ch. 16 - Why dont hydrogen ions appear in equations for...Ch. 16 - Why must the charge balance in oxidation-reduction...
Ch. 16 - Write cell schematics for the following cell...Ch. 16 - Assuming the schematics below represent galvanic...Ch. 16 - Write a balanced equation for the cell reaction of...Ch. 16 - Balance each reaction below, and write a cell...Ch. 16 - Identify the oxidant and reductant in each...Ch. 16 - From the information provided, use cell notation...Ch. 16 - Why is a salt bridge necessary in galvanic cell...Ch. 16 - An active (metal) electrode was found to gain mass...Ch. 16 - An active (metal) electrode was found to lose mass...Ch. 16 - The masses of three electrodes (A, B, and C), each...Ch. 16 - Calculate the standard cell potential for each...Ch. 16 - Calculate the standard cell potential for each...Ch. 16 - Write the balanced cell reaction for the cell...Ch. 16 - Determine the cell reaction and standard cell...Ch. 16 - Determine the cell reaction and standard cell...Ch. 16 - Write the balanced cell reaction for the cell...Ch. 16 - For each pair of standard cell potential and...Ch. 16 - For each pair of standard free energy change and...Ch. 16 - Determine the standard cell potential and the cell...Ch. 16 - Determine ∆G and ∆G for each of the reactions...Ch. 16 - Use the data in Appendix L to calculate...Ch. 16 - Consider a battery made from one half-cell that...Ch. 16 - Consider a battery with the overall reaction:...Ch. 16 - Why do batteries go dead, but fuel cells do not?Ch. 16 - Use the Nernst equation to explain the drop in...Ch. 16 - Using the information thus far in this chapter,...Ch. 16 - Which member of each pair of metals is more likely...Ch. 16 - Consider the following metals: Ag, Au, Mg, Ni, and...Ch. 16 - Aluminum (EoA13+/A1=-2.07V) is easily oxidized...Ch. 16 - If a sample of iron and a sample of zinc come into...Ch. 16 - Suppose you have three different metals. A, B, and...Ch. 16 - Why would a sacrificial anode made of lithium...Ch. 16 - If a 2.5 A current flows through a circuit for 35...Ch. 16 - For the scenario in the previous question, how...Ch. 16 - Write the half-reactions and cell reaction...Ch. 16 - What mass of each product is produced in each of...Ch. 16 - How long would it take to reduce 1 mole of each of...Ch. 16 - A Current of 2.345 A passes through the Shown in...Ch. 16 - An irregularly shaped metal part made from a...
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