Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Chapter 16, Problem 20E
The masses of three electrodes (A, B, and C), each from three different galvanic cells, were measured before and after the cells were allowed to pass current for a while. The mass of electrode A increased, that of electrode B was unchanged, and that of electrode C decreased. Identify each electrode as active or inert, and note (if possible) whether it functioned as anode or cathode.
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111
States of Matter
Understanding conceptual components of the enthalpy of solution
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A small amount of acetonitrile (CH, CN) is dissolved in a large amount of water. Imagine separating this process into the four stages sketched below. (These
sketches show only a portion of the substances, so you can see the density and distribution of atoms and molecules in them.)
CH,CN
H₂O
B
88
C
Use these sketches to answer the questions in the table below.
The enthalpy of solution AH is negative
soln
when CH3CN dissolves in water. Use this
information to list the stages in order of increasing
enthalpy.
Would heat be absorbed or released if the system
moved from Stage C to D?
What force would oppose or favor the system
moving from Stage C to D? Check all that apply.
1
absorbed
O released
neither absorbed nor released.
none
O ionic bonding force
covalent bonding force…
In a system with an anodic overpotential, the variation of ŋ as a function of
the current density:
1. at low fields is linear 2. at higher fields, it follows Tafel's law
Find the range of current densities for which the overpotential has the same
value as when calculated for cases 1 and 2 (maximum relative difference of
5% with respect to the behavior for higher fields). To which overpotential
range does this correspond?
Data: 10 = 1.5 mA cm², T = 300°C, ẞ = 0.64, R = 8.314 J K 1 mol¹ and F = 96485
C mol-1.
Indicate 10.6 with only one significant figure.
Chapter 16 Solutions
Chemistry Atoms First2e
Ch. 16 - Identify each half-reaction below as either...Ch. 16 - Identify each half-reaction below as either...Ch. 16 - Assuming each pair of half-reactions below takes...Ch. 16 - Balance the equations below assuming they occur in...Ch. 16 - Identify the oxidant and reductant of each...Ch. 16 - Balance the equations below assuming they occur in...Ch. 16 - Identify the oxidant and reductant of each...Ch. 16 - Why dont hydroxide ions appear in equations for...Ch. 16 - Why dont hydrogen ions appear in equations for...Ch. 16 - Why must the charge balance in oxidation-reduction...
Ch. 16 - Write cell schematics for the following cell...Ch. 16 - Assuming the schematics below represent galvanic...Ch. 16 - Write a balanced equation for the cell reaction of...Ch. 16 - Balance each reaction below, and write a cell...Ch. 16 - Identify the oxidant and reductant in each...Ch. 16 - From the information provided, use cell notation...Ch. 16 - Why is a salt bridge necessary in galvanic cell...Ch. 16 - An active (metal) electrode was found to gain mass...Ch. 16 - An active (metal) electrode was found to lose mass...Ch. 16 - The masses of three electrodes (A, B, and C), each...Ch. 16 - Calculate the standard cell potential for each...Ch. 16 - Calculate the standard cell potential for each...Ch. 16 - Write the balanced cell reaction for the cell...Ch. 16 - Determine the cell reaction and standard cell...Ch. 16 - Determine the cell reaction and standard cell...Ch. 16 - Write the balanced cell reaction for the cell...Ch. 16 - For each pair of standard cell potential and...Ch. 16 - For each pair of standard free energy change and...Ch. 16 - Determine the standard cell potential and the cell...Ch. 16 - Determine ∆G and ∆G for each of the reactions...Ch. 16 - Use the data in Appendix L to calculate...Ch. 16 - Consider a battery made from one half-cell that...Ch. 16 - Consider a battery with the overall reaction:...Ch. 16 - Why do batteries go dead, but fuel cells do not?Ch. 16 - Use the Nernst equation to explain the drop in...Ch. 16 - Using the information thus far in this chapter,...Ch. 16 - Which member of each pair of metals is more likely...Ch. 16 - Consider the following metals: Ag, Au, Mg, Ni, and...Ch. 16 - Aluminum (EoA13+/A1=-2.07V) is easily oxidized...Ch. 16 - If a sample of iron and a sample of zinc come into...Ch. 16 - Suppose you have three different metals. A, B, and...Ch. 16 - Why would a sacrificial anode made of lithium...Ch. 16 - If a 2.5 A current flows through a circuit for 35...Ch. 16 - For the scenario in the previous question, how...Ch. 16 - Write the half-reactions and cell reaction...Ch. 16 - What mass of each product is produced in each of...Ch. 16 - How long would it take to reduce 1 mole of each of...Ch. 16 - A Current of 2.345 A passes through the Shown in...Ch. 16 - An irregularly shaped metal part made from a...
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