Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 16, Problem 28E
For each pair of standard free energy change and electron stoichiometry values below, calculate a corresponding standard cell potential.
(a)
(b)
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In one electrode: Pt, H2(1 atm) | H+(a=1), the interchange current density at 298K is 0.79 mA·cm-2. If the voltage difference of the interface is +5 mV. What will be the correct intensity at pH = 2?. Maximum transfer voltage and beta = 0.5.
In a Pt electrode, H2(1 atm) | H+(a=1), the interchange current density of an electrode is 0.79 mA cm-2. ¿Qué corriente flow across the electrode of área 5 cm2 when the difference in potential of the interface is +5 mV?.
If the current voltage is n = 0.14 V, indicate which of the 2 voltage
formulas of the ley of Tafel must be applied
i
a
a) == exp (1-B).
xp[(1 - ß³):
Fn
Fn
a
b) == exp B
RT
RT
Chapter 16 Solutions
Chemistry Atoms First2e
Ch. 16 - Identify each half-reaction below as either...Ch. 16 - Identify each half-reaction below as either...Ch. 16 - Assuming each pair of half-reactions below takes...Ch. 16 - Balance the equations below assuming they occur in...Ch. 16 - Identify the oxidant and reductant of each...Ch. 16 - Balance the equations below assuming they occur in...Ch. 16 - Identify the oxidant and reductant of each...Ch. 16 - Why dont hydroxide ions appear in equations for...Ch. 16 - Why dont hydrogen ions appear in equations for...Ch. 16 - Why must the charge balance in oxidation-reduction...
Ch. 16 - Write cell schematics for the following cell...Ch. 16 - Assuming the schematics below represent galvanic...Ch. 16 - Write a balanced equation for the cell reaction of...Ch. 16 - Balance each reaction below, and write a cell...Ch. 16 - Identify the oxidant and reductant in each...Ch. 16 - From the information provided, use cell notation...Ch. 16 - Why is a salt bridge necessary in galvanic cell...Ch. 16 - An active (metal) electrode was found to gain mass...Ch. 16 - An active (metal) electrode was found to lose mass...Ch. 16 - The masses of three electrodes (A, B, and C), each...Ch. 16 - Calculate the standard cell potential for each...Ch. 16 - Calculate the standard cell potential for each...Ch. 16 - Write the balanced cell reaction for the cell...Ch. 16 - Determine the cell reaction and standard cell...Ch. 16 - Determine the cell reaction and standard cell...Ch. 16 - Write the balanced cell reaction for the cell...Ch. 16 - For each pair of standard cell potential and...Ch. 16 - For each pair of standard free energy change and...Ch. 16 - Determine the standard cell potential and the cell...Ch. 16 - Determine ∆G and ∆G for each of the reactions...Ch. 16 - Use the data in Appendix L to calculate...Ch. 16 - Consider a battery made from one half-cell that...Ch. 16 - Consider a battery with the overall reaction:...Ch. 16 - Why do batteries go dead, but fuel cells do not?Ch. 16 - Use the Nernst equation to explain the drop in...Ch. 16 - Using the information thus far in this chapter,...Ch. 16 - Which member of each pair of metals is more likely...Ch. 16 - Consider the following metals: Ag, Au, Mg, Ni, and...Ch. 16 - Aluminum (EoA13+/A1=-2.07V) is easily oxidized...Ch. 16 - If a sample of iron and a sample of zinc come into...Ch. 16 - Suppose you have three different metals. A, B, and...Ch. 16 - Why would a sacrificial anode made of lithium...Ch. 16 - If a 2.5 A current flows through a circuit for 35...Ch. 16 - For the scenario in the previous question, how...Ch. 16 - Write the half-reactions and cell reaction...Ch. 16 - What mass of each product is produced in each of...Ch. 16 - How long would it take to reduce 1 mole of each of...Ch. 16 - A Current of 2.345 A passes through the Shown in...Ch. 16 - An irregularly shaped metal part made from a...
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- If the current voltage is n = 0.14 V. Indicate which of the 2 formulas must be applied a) = a T = i exp[(1 - p) F Fn Fn b) i==exp B RTarrow_forwardTopic: Photochemistry and Photophysics of Supramoleculesarrow_forwardTwo cations that exchange an electron in an interface, the exchange density is worth 1.39 mA/cm2 and the current density is worth 15 mA/cm2 at 25°C. If the overvoltage is 0.14 V, calculate the reaction rate and symmetry factor. Data: R = 8,314 J mol-1 k-1: F = 96500 Carrow_forward
- With the help of the Tafel line, it is estimated that the interchange density of the VO2+/VO2+ system on the carbon paper has a value of 3 mA cm-2. Calculate a) the current density if the voltage has a value of 1.6 mV and the temperature is 25°C. b) the beta value of the anódico process if the Tafel pendulum is 0.6 V at 25°C. Data: R = 8.314 JK-1mol-1, y F = 96485 C mol-1.arrow_forwardApply the NANSTE law to the MnO4- + 8H+ + 5e- ⇄ Mn2+ + 4H2Oarrow_forwardIn the Nernst Law, how much is RT / F?arrow_forward
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