Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
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Textbook Question
Chapter 16, Problem 33E
Consider a battery with the overall reaction:
(a) What is the reaction at the anode and cathode?.
(b) A battery is “dead" when it has no cell potential. What is the value of Q when this battery is dead?.
(c) If a particular dead battery was found to have
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Predict the major products of this organic reaction:
HBr (1 equiv)
cold
?
Some important notes:
• Draw the major product, or products, of this reaction in the drawing area below.
• You can draw the products in any arrangement you like.
• Pay careful attention to the reaction conditions, and only include the major products.
• Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers.
• Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions.
Erase something
Explanation
Check
2025 McGraw Hill LLC. All Rights Reserved. Ter
Q14. Fill this chart: (please refer to ppt notes/browser to answer these questions)
What alcohol is also called wood alcohol?
What is the common name of ethanol?
Draw the structure of phenol and thiophene?
Are bigger chain alcohol like heptanol and octanol
are soluble or insoluble in water and explain it ?
Are ethers soluble or insoluble in water?
What suffix and prefix are used for alcohol while
naming alcohol and ether?
What the process called when we add water to any
alkene to make alcohol?
Q16. Draw the diagram of following aromatic compound (practice from previous module)
Aniline
Phenol
Benzoic acid
Methyl benzoate
Q17. a. Write the oxidation reactions for the 2 propanol.
b. Write the oxidation reaction of the ethanol.
Question 11 of 18 (1 point) Question Attempt: 3 of
How many signals do you expect in the 'H NMR spectrum for this molecule?
Br
Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: In this question, any multiplet is counted as one signal.
Number of signals in the 'H NMR spectrum.
1
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in top
molecule
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box…
Chapter 16 Solutions
Chemistry Atoms First2e
Ch. 16 - Identify each half-reaction below as either...Ch. 16 - Identify each half-reaction below as either...Ch. 16 - Assuming each pair of half-reactions below takes...Ch. 16 - Balance the equations below assuming they occur in...Ch. 16 - Identify the oxidant and reductant of each...Ch. 16 - Balance the equations below assuming they occur in...Ch. 16 - Identify the oxidant and reductant of each...Ch. 16 - Why dont hydroxide ions appear in equations for...Ch. 16 - Why dont hydrogen ions appear in equations for...Ch. 16 - Why must the charge balance in oxidation-reduction...
Ch. 16 - Write cell schematics for the following cell...Ch. 16 - Assuming the schematics below represent galvanic...Ch. 16 - Write a balanced equation for the cell reaction of...Ch. 16 - Balance each reaction below, and write a cell...Ch. 16 - Identify the oxidant and reductant in each...Ch. 16 - From the information provided, use cell notation...Ch. 16 - Why is a salt bridge necessary in galvanic cell...Ch. 16 - An active (metal) electrode was found to gain mass...Ch. 16 - An active (metal) electrode was found to lose mass...Ch. 16 - The masses of three electrodes (A, B, and C), each...Ch. 16 - Calculate the standard cell potential for each...Ch. 16 - Calculate the standard cell potential for each...Ch. 16 - Write the balanced cell reaction for the cell...Ch. 16 - Determine the cell reaction and standard cell...Ch. 16 - Determine the cell reaction and standard cell...Ch. 16 - Write the balanced cell reaction for the cell...Ch. 16 - For each pair of standard cell potential and...Ch. 16 - For each pair of standard free energy change and...Ch. 16 - Determine the standard cell potential and the cell...Ch. 16 - Determine ∆G and ∆G for each of the reactions...Ch. 16 - Use the data in Appendix L to calculate...Ch. 16 - Consider a battery made from one half-cell that...Ch. 16 - Consider a battery with the overall reaction:...Ch. 16 - Why do batteries go dead, but fuel cells do not?Ch. 16 - Use the Nernst equation to explain the drop in...Ch. 16 - Using the information thus far in this chapter,...Ch. 16 - Which member of each pair of metals is more likely...Ch. 16 - Consider the following metals: Ag, Au, Mg, Ni, and...Ch. 16 - Aluminum (EoA13+/A1=-2.07V) is easily oxidized...Ch. 16 - If a sample of iron and a sample of zinc come into...Ch. 16 - Suppose you have three different metals. A, B, and...Ch. 16 - Why would a sacrificial anode made of lithium...Ch. 16 - If a 2.5 A current flows through a circuit for 35...Ch. 16 - For the scenario in the previous question, how...Ch. 16 - Write the half-reactions and cell reaction...Ch. 16 - What mass of each product is produced in each of...Ch. 16 - How long would it take to reduce 1 mole of each of...Ch. 16 - A Current of 2.345 A passes through the Shown in...Ch. 16 - An irregularly shaped metal part made from a...
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- Organic Chemistry Esterification reactions 1. Write the steps to prepare ester. 2. Write complete reaction of ethanol and acetic acid to make ester. 3. What does ester smell like? What are the uses of ester. 4. What the role of sulfuric acid in the esterification reactionarrow_forward11. Complete the following esterification reaction with names of all the reactants and products under. Hint: Remove the water and end up with ester R-C-OH + ROH R-C-OR + H₂O A carboxylic acid An alcohol An ester Water BYJU'S H-C-C O-H Нин C-C-C-H HAAA H O-C-C-C-H AAA Ethanoic acid Propanol Water Propyl ethanoate By com CH3COOH + CH3CH2CH2CH₂CH₂OH → Practice for alcohols aldehydes and ketones: 12. Draw the structures from the following names mixed of alcohol/aldehyde and ketone: a. 4-methyl cyclohexanone b. 3-methyl-2-pentenal c. 2,3-dimethylcyclohexanone d. 1,3propanediol or Propane 1,3 diol 13. Write systematic names for the following compounds identify functional group: a. b. (CH3)2CH-C OH c) CH(CH₂)-- OH -,-,arrow_forwardmay you please show all steps! i am having a hard time understanding and applying in this format, thank you!arrow_forward
- 10. Complete the substitution reaction of 2 pentanol with these reagents. Reagents & Reaction Conditions use practice sheet. Please write only major products, minor product like water, other gases are not required. Hint: In substitution of alcohol, we generally substitute OH group with Halogens like cl, Br, F using some reagent containing halogens. Ensure to add halogens to the same carbon number where you are removing OH from Examples Alcohols can be converted to Alkyl Halides with HX acids HBr H₂O HCI + H₂O HI + H₂O CH,CH₂OH + SOCI₂ CH,CH₂OH + PCI₁₂ A BBYJU'S CH CHCI + SO₂+ HCI CH₂CH CIP(OH), + HCI CH,CH₂OH + PCI CHCHCI + POCI + HCI CH,CH₂OH + PBr, CH,CH,Br + P(OH), + HBr 1. Reaction with HBr with 2 Pentanol 2.Reaction with HI with 2 pentanol © Byjus.com 3.Reaction with HCI+ZnCl,, with 2 pentanol (Zncl2 is catalyst no role) 4.Reaction with SOCI,, with 2 Pentanol 5.Reaction with PBr; or PCl, with 2 pentanolarrow_forward3. Is 2-methyl-2-propanol a primary, secondary, or tertiary alcohol? Write out the structures of 2-methyl-2-propanol and also any oxidation products of 2- methyl-2- propanol. If there is more than one oxidation product, give the structure of each of the products. 4. 2-Propanol is the IUPAC systematic name of this alcohol. It has a common name by which it is much better known (You'll see it in the grocery store or pharmacy). Give that common name 5. Aldehydes can be synthesized by the oxidation of. Please choose from below choices A. Primary alcohols B. Secondary alcohols C. Organic acids D. Inorganic acids 6. Tertiary alcohol Can undergo oxidation. yes or no. ? If yes then answer the product.arrow_forwardFinish the reactions hand written pleasearrow_forward
- Part A Identify each alcohol as primary, secondary, or tertiary Drag the appropriate items to their respective bins. CH₂ H₂C- -C-OH HO CH₂ Primary Он OH CH₂ OH CCH₂OH CH₂ сн Secondary Tertiary Reset Help CH,CH₂ (CH)CHCH,OH CH,CH,CH,CCH, CHOH CH₂ Different types of alcohol groups Alcohol and its reaction: 8. Combing two alcohol molecules below and completing the reaction with Product .( Hint Reaction called etherification as ether is formed and name the ether once you complete the reaction. Hint.: R-O-H+H-O-RR-O-R Do the reaction: CH₂OH + CH₂OH---→ + H-O-H 9. Write the reaction of formation of alcohol from alkene by adding water: Addition reaction also called hydration reaction as we are adding water which occur always in presence of acid Hint: Break the double bond and add H and OH if symmetrical then add anywhere if unsymmetrical then follow Markovnikov rule H should go to that double bone carbon which has more hydrogen CH2=CH2 + H₂O-→arrow_forwardComplete the reaction hand written pleasearrow_forwardPredict the major products of this organic reaction: HBr (1 equiv) cold ? Some important notes: • Draw the major product, or products, of this reaction in the drawing area below. • You can draw the products in any arrangement you like. • Pay careful attention to the reaction conditions, and only include the major products. • Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. • Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions. dm Re Explanation Check ©2025 McGraw Hill LLC. All Rights Reserved. Termarrow_forward
- b) Use curved arrows to show the reaction of the radical with hydrogen bromide. Br: Br H .. Answer Bankarrow_forwardIndicate the reaction products when CH3COCH2COOCH2COOC2H5 (ethyl acetoacetoacetate) reacts with 1º OH-/H2O and 2º H3O+arrow_forwardDraw the formula of the compound 4-cyclohexyl butanamide?arrow_forward
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