Introductory Chemistry: An Active Learning Approach
6th Edition
ISBN: 9781305079250
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Chapter 16, Problem 23PE
The freezing point of cyclohexane is
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4.
a) Give a suitable rationale for the following cyclization, stating the type of process involved
(e.g. 9-endo-dig), clearly showing the mechanistic details at each step.
H
CO₂Me
1) NaOMe
2) H3O®
CO₂Me
2. Platinum and other group 10 metals often act as solid phase hydrogenation catalysts for
unsaturated hydrocarbons such as propylene, CH3CHCH2. In order for the reaction to be
catalyzed the propylene molecules must first adsorb onto the surface. In order to completely
cover the surface of a piece of platinum that has an area of 1.50 cm² with propylene, a total
of 3.45 x 10¹7 molecules are needed. Determine the mass of the propylene molecules that
have been absorbed onto the platinum surface.
Chem 141, Dr. Haefner
2. (a) Many main group oxides form acidic solutions when added to water. For example solid
tetraphosphorous decaoxide reacts with water to produce phosphoric acid. Write a balanced
chemical equation for this reaction.
(b) Calcium phosphate reacts with silicon dioxide and carbon graphite at elevated temperatures
to produce white phosphorous (P4) as a gas along with calcium silicate (Silcate ion is SiO3²-)
and carbon monoxide. Write a balanced chemical equation for this reaction.
Chapter 16 Solutions
Introductory Chemistry: An Active Learning Approach
Ch. 16 - Mixtures of gases are always true solutions. True...Ch. 16 - Every pure substance has a definite and fixed set...Ch. 16 - Can you see particles in a solution? If yes, give...Ch. 16 - What kinds of solute particles are present in a...Ch. 16 - Distinguish between the solute and solvent in each...Ch. 16 - Explain why the distinction between solute and...Ch. 16 - Prob. 7ECh. 16 - Prob. 8ECh. 16 - What happens if you add a very small amount of...Ch. 16 - Prob. 10E
Ch. 16 - Prob. 11ECh. 16 - Prob. 12ECh. 16 - Prob. 13ECh. 16 - Prob. 14ECh. 16 - Prob. 15ECh. 16 - What does it mean to say that a solute particle is...Ch. 16 - Prob. 17ECh. 16 - Prob. 18ECh. 16 - Describe the changes that occur between the time...Ch. 16 - Prob. 20ECh. 16 - Prob. 21ECh. 16 - Prob. 22ECh. 16 - Prob. 23ECh. 16 - Prob. 24ECh. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - Prob. 27ECh. 16 - Which of the following solutes do you expect to be...Ch. 16 - Prob. 29ECh. 16 - Prob. 30ECh. 16 - Prob. 31ECh. 16 - Prob. 32ECh. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - Prob. 35ECh. 16 - Prob. 36ECh. 16 - Prob. 37ECh. 16 - A student weighs out a 4.80-g sample of aluminum...Ch. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - Prob. 42ECh. 16 - Potassium hydroxide is used in making liquid soap....Ch. 16 - You need to make an aqueous solution of 0.123M...Ch. 16 - What volume of concentrated sulfuric acid, which...Ch. 16 - Prob. 46ECh. 16 - Prob. 47ECh. 16 - Prob. 48ECh. 16 - Prob. 49ECh. 16 - Prob. 50ECh. 16 - Despite its intense purple color, potassium...Ch. 16 - Prob. 52ECh. 16 - 53. The density of 3.30M potassium nitrate is...Ch. 16 - Prob. 54ECh. 16 - Prob. 55ECh. 16 - Prob. 56ECh. 16 - Prob. 57ECh. 16 - Prob. 58ECh. 16 - Prob. 59ECh. 16 - Prob. 60ECh. 16 - Prob. 61ECh. 16 - Prob. 62ECh. 16 - Prob. 63ECh. 16 - Prob. 64ECh. 16 - Prob. 65ECh. 16 - Prob. 66ECh. 16 - Prob. 67ECh. 16 - Prob. 68ECh. 16 - What are the equivalent mass of Cu(OH)2 and...Ch. 16 - Prob. 70ECh. 16 - Prob. 71ECh. 16 - Prob. 72ECh. 16 - Prob. 73ECh. 16 - Prob. 74ECh. 16 - Prob. 75ECh. 16 - Prob. 76ECh. 16 - Prob. 77ECh. 16 - Prob. 78ECh. 16 - Prob. 79ECh. 16 - Prob. 80ECh. 16 - Prob. 81ECh. 16 - Prob. 82ECh. 16 - What is the molarity of the acetic acid solution...Ch. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - Prob. 86ECh. 16 - Prob. 87ECh. 16 - Prob. 88ECh. 16 - Prob. 89ECh. 16 - Prob. 90ECh. 16 - Prob. 91ECh. 16 - Prob. 92ECh. 16 - Calculate the mass of calcium phosphate that will...Ch. 16 - How many milliliters of 0.464M nitric acid...Ch. 16 - Prob. 95ECh. 16 - Prob. 96ECh. 16 - What volume of 0.842M sodium hydroxide solution...Ch. 16 - Prob. 98ECh. 16 - The equation for a reaction by which a solution of...Ch. 16 - Potassium hydrogen phthalate is a solid,...Ch. 16 - Prob. 101ECh. 16 - Oxalic acid dihydrate is a solid, diprotic acid...Ch. 16 - A student finds that 37.80mL of a 0.4052MNaHCO3...Ch. 16 - Prob. 104ECh. 16 - Prob. 105ECh. 16 - Prob. 106ECh. 16 - Prob. 107ECh. 16 - Prob. 108ECh. 16 - Prob. 109ECh. 16 - Prob. 110ECh. 16 - Prob. 111ECh. 16 - Prob. 112ECh. 16 - Prob. 113ECh. 16 - Prob. 114ECh. 16 - Prob. 115ECh. 16 - Prob. 116ECh. 16 - Prob. 117ECh. 16 - The specific gravity of a solution of KCl is...Ch. 16 - A student dissolves 27.2g of aniline, C6H5NH2, in...Ch. 16 - Prob. 120ECh. 16 - Prob. 121ECh. 16 - Prob. 122ECh. 16 - Prob. 123ECh. 16 - Prob. 124ECh. 16 - Prob. 125ECh. 16 - Prob. 126ECh. 16 - When 12.4g of an unknown solute is dissolved in...Ch. 16 - Prob. 128ECh. 16 - Prob. 129ECh. 16 - When 19.77g of glucose, C6H12O6(180.2g/mol), is...Ch. 16 - Prob. 131ECh. 16 - Prob. 132ECh. 16 - When you heat water on a stove, small bubbles...Ch. 16 - Antifreeze is put into the water in an automobile...Ch. 16 - Prob. 135ECh. 16 - Prob. 136ECh. 16 - Prob. 137ECh. 16 - Prob. 138ECh. 16 - Prob. 139ECh. 16 - Prob. 140ECh. 16 - The density of 18.0%HCl is 1.09g/mL. Calculate its...Ch. 16 - Prob. 142ECh. 16 - Prob. 143ECh. 16 - Prob. 144ECh. 16 - Prob. 145ECh. 16 - A student adds 25.0mL of 0.350M sodium hydroxide...Ch. 16 - Prob. 147ECh. 16 - An analytical procedure for finding the chloride...Ch. 16 - Prob. 149ECh. 16 - Prob. 150ECh. 16 - Prob. 151ECh. 16 - A chemist combines 60.0mL of 0.322M potassium...Ch. 16 - A solution is defined as a homogeneous mixture. Is...Ch. 16 - Prob. 154ECh. 16 - Prob. 16.1TCCh. 16 - 0.100gof A is dissolved in 1.00 103mL of water,...Ch. 16 - Prob. 16.3TCCh. 16 - If you are given the structural formulas of two...Ch. 16 - Prob. 1CLECh. 16 - Prob. 2CLECh. 16 - Write a brief description of the relationships...Ch. 16 - Prob. 4CLECh. 16 - Prob. 5CLECh. 16 - Write a brief description of the relationships...Ch. 16 - Prob. 1PECh. 16 - What mass of sodium chloride and what volume of...Ch. 16 - Prob. 3PECh. 16 - Prob. 4PECh. 16 - Prob. 5PECh. 16 - Prob. 6PECh. 16 - Prob. 7PECh. 16 - Determine the number of equivalents of acid and...Ch. 16 - Prob. 9PECh. 16 - Prob. 10PECh. 16 - Prob. 11PECh. 16 - Prob. 12PECh. 16 - Prob. 13PECh. 16 - Prob. 14PECh. 16 - Prob. 15PECh. 16 - Prob. 16PECh. 16 - What volume of 0.105M lithium nitrate must be...Ch. 16 - Prob. 18PECh. 16 - Prob. 19PECh. 16 - Prob. 20PECh. 16 - Prob. 21PECh. 16 - Prob. 22PECh. 16 - The freezing point of cyclohexane is 6.50C, and...
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY