The structure of sorbitol including stereochemistry is to be written. Concept introduction: Reduction of a compound can be carried out by hydrogenation reaction in the presence of a metal catalyst. Aldehydes are reduced to the corresponding primary alcohols upon reduction. Hydroxyl groups are not affected when subjected to hydrogenation in presence of nickel catalyst.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 19P

Interpretation Introduction

Interpretation:

The structure of sorbitol including stereochemistry is to be written.

Concept introduction:

Reduction of a compound can be carried out by hydrogenation reaction in the presence of a metal catalyst.

Aldehydes are reduced to the corresponding primary alcohols upon reduction.

Hydroxyl groups are not affected when subjected to hydrogenation in presence of nickel catalyst.

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Based on the 1H NMR, 13C NMR, DEPT 135 NMR and DEPT 90 NMR, provide a reasoning step and arrive at the final structure of an unknown organic compound containing 7 carbons. Dept 135 shows peak to be positive at 128.62 and 13.63 Dept 135 shows peak to be negative at 130.28, 64.32, 30.62 and 19.10. Provide assignment for the provided structure

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 19P

Interpretation Introduction

Interpretation:

The structure of sorbitol including stereochemistry is to be written.

Concept introduction:

Reduction of a compound can be carried out by hydrogenation reaction in the presence of a metal catalyst.

Aldehydes are reduced to the corresponding primary alcohols upon reduction.

Hydroxyl groups are not affected when subjected to hydrogenation in presence of nickel catalyst.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 19P

Interpretation Introduction

Interpretation:

The structure of sorbitol including stereochemistry is to be written.

Concept introduction:

Reduction of a compound can be carried out by hydrogenation reaction in the presence of a metal catalyst.

Aldehydes are reduced to the corresponding primary alcohols upon reduction.

Hydroxyl groups are not affected when subjected to hydrogenation in presence of nickel catalyst.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 19P

Interpretation Introduction