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Describe the mesomeric or resonance effect and differentiate between types +E or +M and -R or -M.
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- What effect does increasing the operating frequency of a 1H NMR spectrum have on each value: (a) the chemical shift in δ; (b) the frequency of an absorption in Hz; (c) the magnitude of a coupling constant J in Hz?Given that Kb For ammonia is 1.8 x 105 and that For hydroxylamine is 1.1 x1D-8 A.What is the ha value For NHyt B. What is the ha value For N3 NO HWhat factors do you have to consider when differentiating the relative strength of the IMF’s in methanol,ethanol, propanol, and butanol?
- Plot the interaction potential for a Na+ ion and Cl- ion as a function of separation distance in three different solvents: a) Water (? = 80.2) b) Ethylene glycol (? = 37) c) Chloroform (? = 4.8)(b) Molecule X undergoes the photophysical processes listed below. Name each process (1) - (5) and represent them on a Jablonski diagram. So +hv → S, (1) S >S, +hv (2) S, – >T; + A (3) T →S, +hv (4) k4 T,- > S, + A (5)35 70 105 140 Mass M/e 175 210 1.1 1.0 0.9 0.8 0.7 what functional groups arepresent? 0.6 0.5 0.4 0.3 0.2 500 1000 2000 0 1500 Q.1 500 Wavenumbers (cm-1) Transmitance B
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