Draw the four most importantcontributing structures of the cation intermediate thatforms in the electrophilic chlorination of phenol,(C6H5OH) to form p-chlorophenol. Put a circle aroundthe best one. Can you please each step and also how you would approach a similar problem. Thank you!
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contributing structures of the cation intermediate that
forms in the electrophilic chlorination of phenol,
(C6H5OH) to form p-chlorophenol. Put a circle around
the best one. Can you please each step and also how you would approach a similar problem. Thank you!
Step by step
Solved in 2 steps with 2 images
- Br Brz CH3 CH3 H3C CH2CI2 H3C Br Electrophilic addition of bromine, Br2; to alkenes yields a 1,2-dibromoalkane. The reaction proceeds through a cyclic intermediate known as a bromonium ion. The reaction occurs in an anhydrous solvent such as CH,Cl). In the second step of the reaction, bromide is the nucleophile and attacks at one of the carbons of the bromonium ion to yield the product. Due to steric clashes, the bromide ion always attacks the carbon from the opposite face of the bromonium ion so that a product with anti stereochemistry is formed. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions Br: :Br: .CH3 H3C H3C CH3 Br:The question is: "Draw the curved arrow mechanism for the reaction between pentan-2-one and (CH3)3O– in t-butanol to form an enolate. Draw all electrons and charges on both resonance structures. Then answer the question about the reaction." I got the initial arrows correct, but am not entirely sure what the carbanion intermediate would look like and then what the curved arrows would be to convert it to its final oxanion form#8).
- Please help answer the attached question...thank you!Write out the mechanism (intermediate/transition state) for this reaction; NaOCH, Ę₂ CH3 For the following use ONLY reactions we have studied in class. Check your notes or the Powerpoint slides for preparations and reactions of relevant functional groups a) Write out 6 completely different reactions of cyclohexanone (reagent, product). b) Write out 3 preparations of 2-butanol, using a different starting material for each one. You may use preps where you just change the functional group, and/or preps where you construct the carbon chain. c) Write out 3 preparations of 4-phenylbutanoic acid, a different starting material for each one. You may use preps where you just change the functional group, and/or preps where you construct the carbon chain.Complete the synthesis of ethyl (E)-2,2,4-trimethyl-3-oxo-5-phenylpent-4-enoate from the starting material given (ethyl propionate). You must list out all reagents/solvents next to the reaction arrows and draw the intermediate structures in the boxes. I am giving you one restriction. You are not allowed to introduce any enolates as reagents next to the reaction arrows. orff ion
- Complete the synthesis of ethyl (E)-2,2,4-trimethyl-3-oxo-5-phenylpent-4-enoate from the starting material given (ethyl propionate). You must list out all reagents/solvents next to the reaction arrows and draw the intermediate structures in the boxes. I am giving you one restriction. You are not allowed to introduce any enolates as reagents next to the reaction arrows.In an E2 mediated elimination reaction of an alkyl halide (H-X) using NaOCH3 as base, which of the following statement is not true? O The reactivity order for alkyl halides (RX) is tertiary secondary> primary. O The rate of reaction = k2 (alkyl halide] [NaOCH₂] O The reaction occurs in a single step. O The rate is independent of the leaving group.Illustrate the reaction mechanism for the ethylation of p-cyclopropylphenol (other reactants: AlCI3 and ethylchloride). Refer to Friedel-Craft Alkylation mechanism as your guide in doing this mechanism. Show ALL partial charges in the EACH structure using BLUE ink. Arrows should be written using RED ink.
- Illustrate the reaction mechanism for the ethylation of p-cyclopropyllphenol (other reactants: AlCl3 and ethylchloride). Refer to Friedel-Craft Alkylation mechanism as your guide in doing this mechanism. Show ALL partial charges in the EACH structure using BLUE color. Arrows should be written using RED color.(j) (k) Predict the major product or the necessary reagent or reactant to complete each of the following reactions. In the box before each reaction, indicate the mechanism followed by the reaction. (Free radical (FR), SN2, SN1). (h) + KBr CH3 1 2 CI CH3 -H -CH3 CH₂CH3 NEC Na+ (i) Na+ N3 Br₂, light CH3CH2 Hu Br 'H (k) H₂OCompare the two reactions shown below. excess LICH,CH3 excess LICH,CH3 Both electrophiles, an ester and a ketone, are reacted with an excess amount of LICH2CH2. Which reaction will result in the formation of a product with the molecular formula C9H200 and why? O A: Only the reaction with the ester. LICH2CH3 results in an addition mechanism with both starting materials. However, the product from the ketone reaction contains fewer than 9 carbons. O B. Only the reaction with the ketone. LICH2CH3 results in an addition mechanism with both starting materials. However, the product from the ester reaction contains two oxygen atoms. O C. Both reactions. LICH2CH3 results in an addition mechanism with the ketone. However, the ester goes through a SNAC mechanism because it contains a leaving group, which allows two equivalents of LICH2CH3 to attack. O D. Neither reaction. LICH2CH3 results in a SNAC mechanism with both starting materials. Both products contain more than 9 carbons.
