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(a)
Interpretation:
A compound that contains an acetal with the molecular formula C5H12O2 should be drawn.
Concept Introduction:
Addition of one molecule of alcohol to an
(b)
Interpretation:
A compound that contains a hemiacetal with the molecular formula C5H12O2 should be drawn.
Concept Introduction:
Addition of one molecule of alcohol to an aldehyde or ketone results in a hemiacetal. Here, the C=O double bond breaks and single bonds are formed. If the hemiacetal is acyclic, it is not stable. Acyclic hemiacetal reacts with a second alcohol molecule and forms acetal.
(c)
Interpretation:
A compound that contains two ethers with the molecular formula C5H12O2 should be drawn.
Concept Introduction:
Even though acetals contain C-O-R bond, acetals are not ethers. Acetals have 2 OR groups attached to a single C atom. But an ether has one O atom which is bonded to 2 carbons.
(d)
Interpretation:
A compound that contains an alcohol and ether, but is not a hemiacetal with the molecular formula C5H12O2 should be drawn.
Concept Introduction:
Addition of one molecule of alcohol to an aldehyde or ketone results in a hemiacetal. Here, the C=O double bond breaks and single bonds are formed. If the hemiacetal is acyclic, it is not stable. Acyclic hemiacetal reacts with a second alcohol molecule and forms acetal.
Even though acetals contain C-O-R bond, acetals are not ethers. Acetals have 2 OR groups attached to a single C atom. But an ether has one O atom which is bonded to 2 carbons.
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Chapter 16 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
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- 2H2S(g)+3O2(g)→2SO2(g)+2H2O(g) A 1.2mol sample of H2S(g) is combined with excess O2(g), and the reaction goes to completion. Question Which of the following predicts the theoretical yield of SO2(g) from the reaction? Responses 1.2 g Answer A: 1.2 grams A 41 g Answer B: 41 grams B 77 g Answer C: 77 grams C 154 g Answer D: 154 grams Darrow_forwardPart VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10arrow_forwardQ: Arrange BCC and Fec metals, in sequence from the Fable (Dr. R's slides) and Calculate Volume and Density. Aa BCC V 52 5 SFCCarrow_forward
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