(a) Interpretation: The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined: CH 3 CH 2 CH 2 CH 2 CH 2 OH Concept Introduction: In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when an aldehyde is reduced by H 2 in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H 2 is added across this C=O double bond forming a primary alcohol.

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 16.63P

Interpretation Introduction

(a)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

CH₃CH₂CH₂CH₂CH₂OH

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when an aldehyde is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a primary alcohol.

Interpretation Introduction

(b)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when a ketone is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a secondary alcohol.

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3. Consider the compounds below and determine if they are aromatic, antiaromatic, or non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly drawn and you should be able to tell that the bonding electrons and lone pair electrons should reside in which hybridized atomic orbital 2. You should consider ring strain- flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti- aromaticity) H H N N: NH2 N Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic TT electrons Me H Me Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic πT electrons H HH…

A chemistry graduate student is studying the rate of this reaction: 2 HI (g) →H2(g) +12(g) She fills a reaction vessel with HI and measures its concentration as the reaction proceeds: time (minutes) [IH] 0 0.800M 1.0 0.301 M 2.0 0.185 M 3.0 0.134M 4.0 0.105 M Use this data to answer the following questions. Write the rate law for this reaction. rate = 0 Calculate the value of the rate constant k. k = Round your answer to 2 significant digits. Also be sure your answer has the correct unit symbol.

Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 16.63P

Interpretation Introduction

(a)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

CH₃CH₂CH₂CH₂CH₂OH

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when an aldehyde is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a primary alcohol.

Interpretation Introduction

(b)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when a ketone is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a secondary alcohol.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 16.63P

Interpretation Introduction

(a)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

CH₃CH₂CH₂CH₂CH₂OH

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when an aldehyde is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a primary alcohol.

Interpretation Introduction

(b)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when a ketone is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a secondary alcohol.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 16.63P

Interpretation Introduction

(a)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

CH₃CH₂CH₂CH₂CH₂OH

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when an aldehyde is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a primary alcohol.

Interpretation Introduction

(b)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when a ketone is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a secondary alcohol.

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Answer 5

Chapter 16, Problem 16.63P

Interpretation Introduction

(a)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

CH₃CH₂CH₂CH₂CH₂OH

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when an aldehyde is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a primary alcohol.

Interpretation Introduction

(b)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when a ketone is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a secondary alcohol.

Answer 6

Chapter 16, Problem 16.63P

Interpretation Introduction

(a)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

CH₃CH₂CH₂CH₂CH₂OH

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when an aldehyde is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a primary alcohol.

Answer 7

Chapter 16, Problem 16.63P

Interpretation Introduction

(a)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

CH₃CH₂CH₂CH₂CH₂OH

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when an aldehyde is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a primary alcohol.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when a ketone is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a secondary alcohol.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when a ketone is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a secondary alcohol.

Answer 10

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Answer 12

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Answer 13

Ch. 16.1 - Prob. 16.1P Ch. 16.1 - Draw the structure of the three constitutional...Ch. 16.2 - Prob. 16.3P Ch. 16.2 - Give the structure corresponding to each TUPAC...Ch. 16.2 - Prob. 16.5P Ch. 16.2 - Prob. 16.6P Ch. 16.2 - Give the structure corresponding to each name. a....Ch. 16.3 - Which compound in each pair has the higher boiling...Ch. 16.3 - Acetone and progesterone are two ketones that...Ch. 16.4 - Prob. 16.10P

Solution Summary: The author explains the carbonyl compound needed to produce the following alcohol by a reduction reaction.

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