Hydrolysis of ester in acidic medium gives carboxylic acid and alcohol. Concept introduction: • Acidic hydrolysis of an ester gives a carboxylic acid and an alcohol. • Basic hydrolysis of an ester gives a carboxylate salt and an alcohol. • Acidic hydrolysis is simply the reverse of esterification, in which water breaks the ester bond to give carboxylic acid and alcohol. • The ester is heated with a large excess of water containing a strong-acid catalyst. Like esterification, the reaction is reversible and does not go to completion.

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Answer 1

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 16.62AQAP

Interpretation Introduction

Interpretation:

Hydrolysis of ester in acidic medium gives carboxylic acid and alcohol.

Concept introduction:

• Acidic hydrolysis of an ester gives a carboxylic acid and an alcohol.

• Basic hydrolysis of an ester gives a carboxylate salt and an alcohol.

• Acidic hydrolysis is simply the reverse of esterification, in which water breaks the ester bond to give carboxylic acid and alcohol.

• The ester is heated with a large excess of water containing a strong-acid catalyst. Like esterification, the reaction is reversible and does not go to completion.

Interpretation Introduction

To determine:

IUPAC names of the carboxylic acid and alcohol needed to produce the given esters.

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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15% glycerin by weight. If the original charge is 500 kg, evaluate; e. The ratio of sucrose to water in the original charge (wt/wt). f. Moles of CO2 evolved. g. Maximum possible amount of ethanol that could be formed. h. Conversion efficiency. i. Per cent excess of excess reactant. Reactions: Inversion reaction: C12H22O11 + H2O →2C6H12O6 Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2 Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3

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13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. cleavage Bond A •CH3 + 26.← Cleavage 2°C. + Bond C +3°C• CH3 2C Cleavage E 2°C. 26. weakest bond Intact molecule Strongest 3°C 20. Gund Largest argest a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. C Weakest bond A Produces Most Bond Strongest Bond Strongest Gund produces least stable radicals Weakest Stable radical b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 13°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. • CH3 methyl radical Formed in Gund A Cleavage c.…

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 16.62AQAP

Interpretation Introduction

Interpretation:

Hydrolysis of ester in acidic medium gives carboxylic acid and alcohol.

Concept introduction:

• Acidic hydrolysis of an ester gives a carboxylic acid and an alcohol.

• Basic hydrolysis of an ester gives a carboxylate salt and an alcohol.

• Acidic hydrolysis is simply the reverse of esterification, in which water breaks the ester bond to give carboxylic acid and alcohol.

• The ester is heated with a large excess of water containing a strong-acid catalyst. Like esterification, the reaction is reversible and does not go to completion.

Interpretation Introduction

To determine:

IUPAC names of the carboxylic acid and alcohol needed to produce the given esters.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 16.62AQAP

Interpretation Introduction

Interpretation:

Hydrolysis of ester in acidic medium gives carboxylic acid and alcohol.

Concept introduction:

• Acidic hydrolysis of an ester gives a carboxylic acid and an alcohol.

• Basic hydrolysis of an ester gives a carboxylate salt and an alcohol.

• Acidic hydrolysis is simply the reverse of esterification, in which water breaks the ester bond to give carboxylic acid and alcohol.

• The ester is heated with a large excess of water containing a strong-acid catalyst. Like esterification, the reaction is reversible and does not go to completion.

Interpretation Introduction

To determine:

IUPAC names of the carboxylic acid and alcohol needed to produce the given esters.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 16.62AQAP

Interpretation Introduction

Interpretation:

Hydrolysis of ester in acidic medium gives carboxylic acid and alcohol.

Concept introduction:

• Acidic hydrolysis of an ester gives a carboxylic acid and an alcohol.

• Basic hydrolysis of an ester gives a carboxylate salt and an alcohol.

• Acidic hydrolysis is simply the reverse of esterification, in which water breaks the ester bond to give carboxylic acid and alcohol.

• The ester is heated with a large excess of water containing a strong-acid catalyst. Like esterification, the reaction is reversible and does not go to completion.

Interpretation Introduction

To determine:

IUPAC names of the carboxylic acid and alcohol needed to produce the given esters.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 16, Problem 16.62AQAP

Interpretation Introduction

Interpretation:

Hydrolysis of ester in acidic medium gives carboxylic acid and alcohol.

Concept introduction:

• Acidic hydrolysis of an ester gives a carboxylic acid and an alcohol.

• Basic hydrolysis of an ester gives a carboxylate salt and an alcohol.

• Acidic hydrolysis is simply the reverse of esterification, in which water breaks the ester bond to give carboxylic acid and alcohol.

• The ester is heated with a large excess of water containing a strong-acid catalyst. Like esterification, the reaction is reversible and does not go to completion.

Interpretation Introduction

To determine:

IUPAC names of the carboxylic acid and alcohol needed to produce the given esters.

Answer 6

Chapter 16, Problem 16.62AQAP

Interpretation Introduction

Interpretation:

Hydrolysis of ester in acidic medium gives carboxylic acid and alcohol.

Concept introduction:

• Acidic hydrolysis of an ester gives a carboxylic acid and an alcohol.

• Basic hydrolysis of an ester gives a carboxylate salt and an alcohol.

• Acidic hydrolysis is simply the reverse of esterification, in which water breaks the ester bond to give carboxylic acid and alcohol.

• The ester is heated with a large excess of water containing a strong-acid catalyst. Like esterification, the reaction is reversible and does not go to completion.

Answer 7

Chapter 16, Problem 16.62AQAP

Interpretation Introduction

Interpretation:

Hydrolysis of ester in acidic medium gives carboxylic acid and alcohol.

Concept introduction:

• Acidic hydrolysis of an ester gives a carboxylic acid and an alcohol.

• Basic hydrolysis of an ester gives a carboxylate salt and an alcohol.

• Acidic hydrolysis is simply the reverse of esterification, in which water breaks the ester bond to give carboxylic acid and alcohol.

• The ester is heated with a large excess of water containing a strong-acid catalyst. Like esterification, the reaction is reversible and does not go to completion.

Answer 8

Interpretation Introduction

To determine:

IUPAC names of the carboxylic acid and alcohol needed to produce the given esters.

Answer 9

Interpretation Introduction

To determine:

IUPAC names of the carboxylic acid and alcohol needed to produce the given esters.

Answer 10

Expert Solution & Answer

Answer 11

Expert Solution & Answer

Answer 12

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Answer 13

Ch. 16.1 - What carboxylic acid is responsible for the pain...Ch. 16.1 - What carboxylic acid is found in vinegar?Ch. 16.1 - Prob. 16.3QAP Ch. 16.1 - Draw the condensed structural formula and give the...Ch. 16.1 - Prob. 16.5QAP Ch. 16.1 - Prob. 16.6QAP Ch. 16.1 - Draw the condensed structural formula for each of...Ch. 16.1 - Prob. 16.8QAP Ch. 16.1 - Prob. 16.9QAP Ch. 16.1 - Prob. 16.10QAP

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To determine:

IUPAC names of the carboxylic acid and alcohol needed to produce the given esters.

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Chapter 16 Solutions

Concept explainers

Videos

To determine: IUPAC names of the carboxylic acid and alcohol needed to produce the given esters.

Want to see the full answer?

Chapter 16 Solutions

To determine:

IUPAC names of the carboxylic acid and alcohol needed to produce the given esters.