It is to be explained why the OH group increases the chemical shift of the C atom to which it is attached but decreases the chemical shift of the C atom on the opposite side. Concept introduction: Chemical shift is a measure of a signal’s frequency relative to the signal frequency generated by tetramethylsilane (TMS). Electron-withdrawing groups deshield nuclei inductively, thereby increasing the chemical shift. Deshielding from inductive effects falls off rapidly with distance.

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Answer 1

Question

Chapter 16, Problem 16.52P

Interpretation Introduction

Interpretation:

It is to be explained why the OH group increases the chemical shift of the C atom to which it is attached but decreases the chemical shift of the C atom on the opposite side.

Concept introduction:

Chemical shift is a measure of a signal’s frequency relative to the signal frequency generated by tetramethylsilane (TMS). Electron-withdrawing groups deshield nuclei inductively, thereby increasing the chemical shift. Deshielding from inductive effects falls off rapidly with distance.

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Answer 2

Question

Chapter 16, Problem 16.52P

Interpretation Introduction

Interpretation:

It is to be explained why the OH group increases the chemical shift of the C atom to which it is attached but decreases the chemical shift of the C atom on the opposite side.

Concept introduction:

Chemical shift is a measure of a signal’s frequency relative to the signal frequency generated by tetramethylsilane (TMS). Electron-withdrawing groups deshield nuclei inductively, thereby increasing the chemical shift. Deshielding from inductive effects falls off rapidly with distance.

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Answer 3

Question

Chapter 16, Problem 16.52P

Interpretation Introduction

Interpretation:

It is to be explained why the OH group increases the chemical shift of the C atom to which it is attached but decreases the chemical shift of the C atom on the opposite side.

Concept introduction:

Chemical shift is a measure of a signal’s frequency relative to the signal frequency generated by tetramethylsilane (TMS). Electron-withdrawing groups deshield nuclei inductively, thereby increasing the chemical shift. Deshielding from inductive effects falls off rapidly with distance.

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Answer 4

Question

Chapter 16, Problem 16.52P

Interpretation Introduction

Interpretation:

It is to be explained why the OH group increases the chemical shift of the C atom to which it is attached but decreases the chemical shift of the C atom on the opposite side.

Concept introduction:

Chemical shift is a measure of a signal’s frequency relative to the signal frequency generated by tetramethylsilane (TMS). Electron-withdrawing groups deshield nuclei inductively, thereby increasing the chemical shift. Deshielding from inductive effects falls off rapidly with distance.

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Answer 5

Chapter 16, Problem 16.52P

Interpretation Introduction

Interpretation:

It is to be explained why the OH group increases the chemical shift of the C atom to which it is attached but decreases the chemical shift of the C atom on the opposite side.

Concept introduction:

Chemical shift is a measure of a signal’s frequency relative to the signal frequency generated by tetramethylsilane (TMS). Electron-withdrawing groups deshield nuclei inductively, thereby increasing the chemical shift. Deshielding from inductive effects falls off rapidly with distance.

Answer 6

Chapter 16, Problem 16.52P

Interpretation Introduction

Interpretation:

It is to be explained why the OH group increases the chemical shift of the C atom to which it is attached but decreases the chemical shift of the C atom on the opposite side.

Concept introduction:

Chemical shift is a measure of a signal’s frequency relative to the signal frequency generated by tetramethylsilane (TMS). Electron-withdrawing groups deshield nuclei inductively, thereby increasing the chemical shift. Deshielding from inductive effects falls off rapidly with distance.

Answer 7

Chapter 16, Problem 16.52P

Interpretation Introduction

Interpretation:

It is to be explained why the OH group increases the chemical shift of the C atom to which it is attached but decreases the chemical shift of the C atom on the opposite side.

Concept introduction:

Chemical shift is a measure of a signal’s frequency relative to the signal frequency generated by tetramethylsilane (TMS). Electron-withdrawing groups deshield nuclei inductively, thereby increasing the chemical shift. Deshielding from inductive effects falls off rapidly with distance.

Answer 8

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Answer 11

Ch. 16 - Prob. 16.1P Ch. 16 - Prob. 16.2P Ch. 16 - Prob. 16.3P Ch. 16 - Prob. 16.4P Ch. 16 - Prob. 16.5P Ch. 16 - Prob. 16.6P Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - Prob. 16.9P Ch. 16 - Prob. 16.10P

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Chapter 16 Solutions