(a)
Interpretation: The products formed for the given Diels-Alder reaction are to be drawn.
Concept introduction: Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
Answer to Problem 16.50P
The products formed by the given Diels-Alder reaction are shown below.
Explanation of Solution
The given reaction is shown below.
Figure 1
Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
The products formed by the given Diels-Alder reaction are shown below
Figure 2
The products formed for the given Diels-Alder reaction is shown in Figure 2.
(b)
Interpretation: The products formed for the given Diels-Alder reaction are to be drawn.
Concept introduction: Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
Answer to Problem 16.50P
The products formed by the given Diels-Alder reaction are shown below.
Explanation of Solution
Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
The products formed by the given Diels-Alder reaction are shown below
Figure 4
The products formed for the given Diels-Alder reaction is shown in Figure 4.
(c)
Interpretation: The products formed for the given Diels-Alder reaction are to be drawn.
Concept introduction: Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene.
Answer to Problem 16.50P
The products formed by the given Diels-Alder reaction are shown below.
Explanation of Solution
The given reaction is shown below.
Figure 5
Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
Therefore, the product formed for the given Diels-Alder reaction is shown below.
Figure 6
The product formed for the given Diels-Alder reaction is shown in Figure 6.
(d)
Interpretation: The product formed for the given Diels-Alder reaction is to be drawn.
Concept introduction: Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
Answer to Problem 16.50P
The product formed for the given Diels-Alder reaction is shown below.
Explanation of Solution
The given reaction is shown below.
Figure 7
Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
Therefore, the product formed for the given Diels-Alder reaction is shown below.
Figure 8
The product formed for the given Diels-Alder reaction is shown in Figure 8.
(e)
Interpretation: The product formed for the given Diels-Alder reaction is to be drawn.
Concept introduction: Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
Answer to Problem 16.50P
The product formed for the given Diels-Alder reaction is shown below.
Explanation of Solution
The given reaction is shown below.
Figure 9
Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
The product formed for the given Diels-Alder reaction is shown below.
Figure 10
The products formed for the given Diels-Alder reaction are shown in Figure 10.
(f)
Interpretation: The product formed for the given Diels-Alder reaction is to be drawn.
Concept introduction: Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
Answer to Problem 16.50P
The product formed for the given Diels-Alder reaction is shown below.
Explanation of Solution
The given reaction is shown below.
Figure 11
Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
The product formed for the given Diels-Alder reaction is shown below.
Figure 12
The products formed for the given Diels-Alder reaction are shown in Figure 12.
Want to see more full solutions like this?
Chapter 16 Solutions
Organic Chemistry-Package(Custom)
- Draw the product formed when each diene and dienophile react in a Diels–Alder reaction.arrow_forwardIntramolecular Diels–Alder reactions are possible when a substrate contains both a 1,3-diene and a dienophile, as shown in the following general reaction.With this in mind, draw the product when each compound undergoes an intramolecular Diels–Alder reaction.arrow_forwardWhat diene and dienophile are needed to prepare each compound by a Diels–Alder reaction?arrow_forward
- Which of the following conformations would undergo Diels-Alder reaction? D. C. B. A.arrow_forwardNonearrow_forwardDevise a stepwise synthesis of each compound from dicyclopentadiene using a Diels–Alder reaction as one step. You may also use organic compounds having ≤ 4 C's, and any required organic or inorganic reagents.arrow_forward
- Draw the product formed when each diene and dienophile react in a Diels-Alder reaction. соон CH3 a. b. C. čoOCH3arrow_forwardHow could the following compounds be synthesized using a Diels–Alder reaction?arrow_forwardWhich of the following could act as an effective dienophile in a Diels-Alder cyclization? A. C.arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY