Organic Chemistry-Package(Custom)
Organic Chemistry-Package(Custom)
4th Edition
ISBN: 9781259141089
Author: SMITH
Publisher: MCG
Question
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Chapter 16, Problem 16.1P
Interpretation Introduction

(a)

Interpretation: The given diene is to be classified as isolated or conjugated.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Organic Chemistry-Package(Custom), Chapter 16, Problem 16.1P , additional homework tip  1

Figure 1

Expert Solution
Check Mark

Answer to Problem 16.1P

The given diene is a conjugated diene.

Explanation of Solution

Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The given diene is shown below.

Organic Chemistry-Package(Custom), Chapter 16, Problem 16.1P , additional homework tip  2

Figure 2

In the given diene, two double bonds are separated by a single bond. Thus, the given diene is a conjugated diene.

Conclusion

The given diene is a conjugated diene.

Interpretation Introduction

(b)

Interpretation: The given diene is to be classified as isolated or conjugated.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Organic Chemistry-Package(Custom), Chapter 16, Problem 16.1P , additional homework tip  3

Figure 1

Expert Solution
Check Mark

Answer to Problem 16.1P

The given diene is an isolated diene.

Explanation of Solution

Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The given diene is shown below.

Organic Chemistry-Package(Custom), Chapter 16, Problem 16.1P , additional homework tip  4

Figure 3

In the given diene, two double bonds are separated by a two sigma bonds. Thus, the given diene is an isolated diene.

Conclusion

The given diene is an isolated diene.

Interpretation Introduction

(c)

Interpretation: The given diene is to be classified as isolated or conjugated.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Organic Chemistry-Package(Custom), Chapter 16, Problem 16.1P , additional homework tip  5

Figure 1

Expert Solution
Check Mark

Answer to Problem 16.1P

The given diene is a conjugated diene.

Explanation of Solution

Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The given diene is shown below.

Organic Chemistry-Package(Custom), Chapter 16, Problem 16.1P , additional homework tip  6

Figure 4

In the given diene, two double bonds are separated by a single bond. Thus, the given diene is a conjugated diene.

Conclusion

The given diene is a conjugated diene.

Interpretation Introduction

(d)

Interpretation: The given diene is to be classified as isolated or conjugated.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated idene is shown below.

Organic Chemistry-Package(Custom), Chapter 16, Problem 16.1P , additional homework tip  7

Figure 1

Expert Solution
Check Mark

Answer to Problem 16.1P

The given diene is an isolated diene.

Explanation of Solution

Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The given diene is shown below.

Organic Chemistry-Package(Custom), Chapter 16, Problem 16.1P , additional homework tip  8

Figure 5

In the given diene, two double bonds are separated by more than single bond. Thus, the given diene is an isolated diene.

Conclusion

The given diene is an isolated diene.

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Chapter 16 Solutions

Organic Chemistry-Package(Custom)

Ch. 16 - Problem 16.12 Using hybridization, predict how the...Ch. 16 - Problem 16.13 Use resonance theory to explain why...Ch. 16 - Prob. 16.13PCh. 16 - Prob. 16.14PCh. 16 - Prob. 16.15PCh. 16 - Problem 16.17 Draw a stepwise mechanism for the...Ch. 16 - Prob. 16.17PCh. 16 - Problem 16.19 Draw the product formed when each...Ch. 16 - Prob. 16.19PCh. 16 - Prob. 16.20PCh. 16 - Rank the following dienophiles in order of...Ch. 16 - Prob. 16.22PCh. 16 - Prob. 16.23PCh. 16 - Prob. 16.24PCh. 16 - Prob. 16.25PCh. 16 - Problem 16.27 Which compound in each pair absorbs...Ch. 16 - Prob. 16.27PCh. 16 - 16.29 Name each diene and state whether the...Ch. 16 - Prob. 16.29PCh. 16 - Prob. 16.30PCh. 16 - Prob. 16.31PCh. 16 - Prob. 16.32PCh. 16 - Prob. 16.33PCh. 16 - Prob. 16.34PCh. 16 - 16.35 Explain why the cyclopentadienide anion A...Ch. 16 - Explain each statement using resonance theory. a....Ch. 16 - 16.37 Draw the structure of each compound. a. in...Ch. 16 - Draw and name all dienes of molecular formula...Ch. 16 - Prob. 16.39PCh. 16 - 16.39 Label each pair of compounds as...Ch. 16 - Prob. 16.41PCh. 16 - 16.41 Draw the products formed when each compound...Ch. 16 - Prob. 16.43PCh. 16 - 16.43 Treatment of alkenes A and B with gives the...Ch. 16 - 16.44 Draw a stepwise mechanism for the following...Ch. 16 - Prob. 16.46PCh. 16 - 16.46 Explain, with reference to the mechanism,...Ch. 16 - Prob. 16.48PCh. 16 - Prob. 16.49PCh. 16 - Prob. 16.50PCh. 16 - Prob. 16.51PCh. 16 - Prob. 16.52PCh. 16 - Prob. 16.53PCh. 16 - 16.53 Diels–Alder reaction of a monosubstituted...Ch. 16 - Prob. 16.55PCh. 16 - Prob. 16.56PCh. 16 - 16.55 Devise a stepwise synthesis of each compound...Ch. 16 - Prob. 16.58PCh. 16 - 16.57 A transannular Diels–Alder reaction is an...Ch. 16 - Draw a stepwise mechanism for the following...Ch. 16 - Draw the products of each reaction. Indicate the...Ch. 16 - Prob. 16.62PCh. 16 - Prob. 16.63PCh. 16 - Prob. 16.64PCh. 16 - 16.65 The treatment of isoprene with one...Ch. 16 - 16.66 The treatment of with forms B (molecular...Ch. 16 - Rank the following compounds in the order of...Ch. 16 - Prob. 16.68PCh. 16 - Prob. 16.69PCh. 16 - Prob. 16.70PCh. 16 - Prob. 16.71PCh. 16 - Prob. 16.72PCh. 16 - Prob. 16.73PCh. 16 - Prob. 16.74P
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