Organic Chemistry, Ebook And Single-course Homework Access
Organic Chemistry, Ebook And Single-course Homework Access
6th Edition
ISBN: 9781319085841
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 16, Problem 16.38AP
Interpretation Introduction

(a)

Interpretation:

The increasing order of dipole moments of isomers of dichlorobenzene is to be stated.

Concept introduction:

The molecule containing two different electronegative atoms when joined through a covalent bond will have charge distribution. This uneven distribution of charges leads to positive and negative poles. The molecules containing opposite poles has some dipole moment and are said to be polar molecules.

Interpretation Introduction

(b)

Interpretation:

The increasing order of boiling points of isomers of dichlorobenzene is to be stated.

Concept introduction:

The temperature at which the atmospheric pressure equals to the vapor pressure is known as boiling point. As the intermolecular forces increase in the molecule the boiling point also increases. High intermolecular forces indicate that it is difficult for the molecules to be separated in order to change the state of the substance.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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Chapter 16 Solutions

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