(a) Interpretation: The product for the exothermic reaction of nitrobenzene with chlorine gas and FeCl 3 is to be predicted. Concept introduction: An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

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Answer 1

Question

Chapter 16, Problem 16.36AP

Interpretation Introduction

(a)

Interpretation:

The product for the exothermic reaction of nitrobenzene with chlorine gas and $FeCl3$ is to be predicted.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(b)

Interpretation:

The product for the reaction of nitrobenzene with fuming $HNO3$ and $H2SO4$ is to be predicted.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(c)

Interpretation:

The product for the reaction of nitobenzene with acetyl chloride and $AlCl3(1.1 equiv.)$ , then with water is to be predicted.

Concept introduction:

Friedel Craft acylation is an electrophilic aromatic substitution reaction. In this reaction, the synthesis of the monoacylated product takes place from the reaction between aromatic rings and acyl chlorides.

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Curved arrows are used to illustrate the flow of electrons. Use the reaction conditions provided and the follow the arrows to draw the intermediate and product in this reaction or mechanistic step(s).

Answer 2

Question

Chapter 16, Problem 16.36AP

Interpretation Introduction

(a)

Interpretation:

The product for the exothermic reaction of nitrobenzene with chlorine gas and $FeCl3$ is to be predicted.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(b)

Interpretation:

The product for the reaction of nitrobenzene with fuming $HNO3$ and $H2SO4$ is to be predicted.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(c)

Interpretation:

The product for the reaction of nitobenzene with acetyl chloride and $AlCl3(1.1 equiv.)$ , then with water is to be predicted.

Concept introduction:

Friedel Craft acylation is an electrophilic aromatic substitution reaction. In this reaction, the synthesis of the monoacylated product takes place from the reaction between aromatic rings and acyl chlorides.

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Answer 3

Question

Chapter 16, Problem 16.36AP

Interpretation Introduction

(a)

Interpretation:

The product for the exothermic reaction of nitrobenzene with chlorine gas and $FeCl3$ is to be predicted.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(b)

Interpretation:

The product for the reaction of nitrobenzene with fuming $HNO3$ and $H2SO4$ is to be predicted.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(c)

Interpretation:

The product for the reaction of nitobenzene with acetyl chloride and $AlCl3(1.1 equiv.)$ , then with water is to be predicted.

Concept introduction:

Friedel Craft acylation is an electrophilic aromatic substitution reaction. In this reaction, the synthesis of the monoacylated product takes place from the reaction between aromatic rings and acyl chlorides.

Expert Solution & Answer

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Answer 4

Question

Chapter 16, Problem 16.36AP

Interpretation Introduction

(a)

Interpretation:

The product for the exothermic reaction of nitrobenzene with chlorine gas and $FeCl3$ is to be predicted.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(b)

Interpretation:

The product for the reaction of nitrobenzene with fuming $HNO3$ and $H2SO4$ is to be predicted.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(c)

Interpretation:

The product for the reaction of nitobenzene with acetyl chloride and $AlCl3(1.1 equiv.)$ , then with water is to be predicted.

Concept introduction:

Friedel Craft acylation is an electrophilic aromatic substitution reaction. In this reaction, the synthesis of the monoacylated product takes place from the reaction between aromatic rings and acyl chlorides.

Expert Solution & Answer

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Answer 5

Chapter 16, Problem 16.36AP

Interpretation Introduction

(a)

Interpretation:

The product for the exothermic reaction of nitrobenzene with chlorine gas and $FeCl3$ is to be predicted.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(b)

Interpretation:

The product for the reaction of nitrobenzene with fuming $HNO3$ and $H2SO4$ is to be predicted.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(c)

Interpretation:

The product for the reaction of nitobenzene with acetyl chloride and $AlCl3(1.1 equiv.)$ , then with water is to be predicted.

Concept introduction:

Friedel Craft acylation is an electrophilic aromatic substitution reaction. In this reaction, the synthesis of the monoacylated product takes place from the reaction between aromatic rings and acyl chlorides.

Answer 6

Chapter 16, Problem 16.36AP

Interpretation Introduction

(a)

Interpretation:

The product for the exothermic reaction of nitrobenzene with chlorine gas and $FeCl3$ is to be predicted.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Answer 7

Chapter 16, Problem 16.36AP

Interpretation Introduction

(a)

Interpretation:

The product for the exothermic reaction of nitrobenzene with chlorine gas and $FeCl3$ is to be predicted.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The product for the reaction of nitrobenzene with fuming $HNO3$ and $H2SO4$ is to be predicted.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The product for the reaction of nitrobenzene with fuming $HNO3$ and $H2SO4$ is to be predicted.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The product for the reaction of nitobenzene with acetyl chloride and $AlCl3(1.1 equiv.)$ , then with water is to be predicted.

Concept introduction:

Friedel Craft acylation is an electrophilic aromatic substitution reaction. In this reaction, the synthesis of the monoacylated product takes place from the reaction between aromatic rings and acyl chlorides.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The product for the reaction of nitobenzene with acetyl chloride and $AlCl3(1.1 equiv.)$ , then with water is to be predicted.

Concept introduction:

Friedel Craft acylation is an electrophilic aromatic substitution reaction. In this reaction, the synthesis of the monoacylated product takes place from the reaction between aromatic rings and acyl chlorides.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 16 - Prob. 16.1P Ch. 16 - Prob. 16.2P Ch. 16 - Prob. 16.3P Ch. 16 - Prob. 16.4P Ch. 16 - Prob. 16.5P Ch. 16 - Prob. 16.6P Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - Prob. 16.9P Ch. 16 - Prob. 16.10P

Solution Summary: The author explains the electrophilic aromatic substitution reaction, which involves substituting a hydrogen atom of the benzene ring.

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Chapter 16 Solutions