(a) Interpretation: The predominant product that is obtained from the monosulfonation of m − bromotoluene is to be predicted. Concept introduction: The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

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Answer 1

Question

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

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Answer 2

Question

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

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Answer 3

Question

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

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Answer 4

Question

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

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Answer 5

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

Answer 6

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Answer 7

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 16 - Prob. 16.1P Ch. 16 - Prob. 16.2P Ch. 16 - Prob. 16.3P Ch. 16 - Prob. 16.4P Ch. 16 - Prob. 16.5P Ch. 16 - Prob. 16.6P Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - Prob. 16.9P Ch. 16 - Prob. 16.10P

Solution Summary: The author explains that the predominant product obtained from the monosulfonation of m-bromotoluene is to be predicted.

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Chapter 16 Solutions