(a) Interpretation: Whether the benzeneboronic acid would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of benzeneboronic acid is to be predicted. The explanation for the corresponding answer is to be stated. Concept introduction: An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

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Answer 1

Question

Chapter 16, Problem 16.45AP

Interpretation Introduction

(a)

Interpretation:

Whether the benzeneboronic acid would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of benzeneboronic acid is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(b)

Interpretation:

Whether the N, N, N- trimethylbenzenamonium would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of N, N, N- trimethylbenzenamonium is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(c)

Interpretation:

Whether the biphenyl would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of biphenyl is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(d)

Interpretation:

Whether the 3-methoxybiphenyl would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of 3-methoxybiphenyl is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

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2. 200 LOD For an unknown compound with a molecular ion of 101 m/z: a. Use the molecular ion to propose at least two molecular formulas. (show your work) b. What is the DU for each of your possible formulas? (show your work) C. Solve the structure and assign each of the following spectra. 8 6 4 2 (ppm) 150 100 50 ō (ppm) 4000 3000 2000 1500 1000 500 HAVENUMBERI-11

Answer 2

Question

Chapter 16, Problem 16.45AP

Interpretation Introduction

(a)

Interpretation:

Whether the benzeneboronic acid would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of benzeneboronic acid is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(b)

Interpretation:

Whether the N, N, N- trimethylbenzenamonium would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of N, N, N- trimethylbenzenamonium is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(c)

Interpretation:

Whether the biphenyl would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of biphenyl is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(d)

Interpretation:

Whether the 3-methoxybiphenyl would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of 3-methoxybiphenyl is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

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Answer 3

Question

Chapter 16, Problem 16.45AP

Interpretation Introduction

(a)

Interpretation:

Whether the benzeneboronic acid would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of benzeneboronic acid is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(b)

Interpretation:

Whether the N, N, N- trimethylbenzenamonium would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of N, N, N- trimethylbenzenamonium is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(c)

Interpretation:

Whether the biphenyl would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of biphenyl is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(d)

Interpretation:

Whether the 3-methoxybiphenyl would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of 3-methoxybiphenyl is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

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Answer 4

Question

Chapter 16, Problem 16.45AP

Interpretation Introduction

(a)

Interpretation:

Whether the benzeneboronic acid would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of benzeneboronic acid is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(b)

Interpretation:

Whether the N, N, N- trimethylbenzenamonium would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of N, N, N- trimethylbenzenamonium is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(c)

Interpretation:

Whether the biphenyl would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of biphenyl is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(d)

Interpretation:

Whether the 3-methoxybiphenyl would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of 3-methoxybiphenyl is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

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Answer 5

Chapter 16, Problem 16.45AP

Interpretation Introduction

(a)

Interpretation:

Whether the benzeneboronic acid would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of benzeneboronic acid is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(b)

Interpretation:

Whether the N, N, N- trimethylbenzenamonium would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of N, N, N- trimethylbenzenamonium is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(c)

Interpretation:

Whether the biphenyl would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of biphenyl is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(d)

Interpretation:

Whether the 3-methoxybiphenyl would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of 3-methoxybiphenyl is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Answer 6

Chapter 16, Problem 16.45AP

Interpretation Introduction

(a)

Interpretation:

Whether the benzeneboronic acid would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of benzeneboronic acid is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Answer 7

Chapter 16, Problem 16.45AP

Interpretation Introduction

(a)

Interpretation:

Whether the benzeneboronic acid would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of benzeneboronic acid is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether the N, N, N- trimethylbenzenamonium would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of N, N, N- trimethylbenzenamonium is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether the N, N, N- trimethylbenzenamonium would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of N, N, N- trimethylbenzenamonium is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Whether the biphenyl would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of biphenyl is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Whether the biphenyl would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of biphenyl is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Whether the 3-methoxybiphenyl would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of 3-methoxybiphenyl is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Whether the 3-methoxybiphenyl would be nitrated more rapidly or more slowly than benzene is to be stated. The structure of the principal mononitration product of 3-methoxybiphenyl is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 16 - Prob. 16.1P Ch. 16 - Prob. 16.2P Ch. 16 - Prob. 16.3P Ch. 16 - Prob. 16.4P Ch. 16 - Prob. 16.5P Ch. 16 - Prob. 16.6P Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - Prob. 16.9P Ch. 16 - Prob. 16.10P

Solution Summary: The author explains the structure of the principal mononitration product of benzeneboronic acid.

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