ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
6th Edition
ISBN: 9781319306977
Author: LOUDON
Publisher: INTER MAC
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Chapter 16, Problem 16.36AP
Interpretation Introduction

(a)

Interpretation:

The product for the exothermic reaction of nitrobenzene with chlorine gas and FeCl3 is to be predicted.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(b)

Interpretation:

The product for the reaction of nitrobenzene with fuming HNO3 and H2SO4 is to be predicted.

Concept introduction:

An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.

Interpretation Introduction

(c)

Interpretation:

The product for the reaction of nitobenzene with acetyl chloride and AlCl3(1.1 equiv.), then with water is to be predicted.

Concept introduction:

Friedel Craft acylation is an electrophilic aromatic substitution reaction. In this reaction, the synthesis of the monoacylated product takes place from the reaction between aromatic rings and acyl chlorides.

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Chapter 16 Solutions

ORGANIC CHEMISTRY SAPLING ACCESS + ETEX

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