ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
6th Edition
ISBN: 9781319306977
Author: LOUDON
Publisher: INTER MAC
Question
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Chapter 16, Problem 16.21P
Interpretation Introduction

(a)

Interpretation:

The structure of the product obtained on reaction of acetyl chloride with anisole (methoxybenzene) in presence of AlCl3 is to be stated.

Concept introduction:

The reaction between acyl chloride with benzene in presence of AlCl3 is a friedal craft acylation reaction. In friedal craft acylation reaction, AlCl3 acts as a lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

Interpretation Introduction

(b)

Interpretation:

The structure of the product obtained on reaction of ethylbenzene with chloromethane in presence of AlCl3 is to be stated.

Concept introduction:

The reaction between ethylbenzene and chloromethane in presence of AlCl3 is a friedal craft alkylation reaction in which AlCl3 acts as a lewis acid catalyst. It is a method of insertion of alkyl group on benzene ring.

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Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…
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Chapter 16 Solutions

ORGANIC CHEMISTRY SAPLING ACCESS + ETEX

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