Organic Chemistry; Organic Chemistry Study Guide A Format: Kit/package/shrinkwrap

8th Edition

ISBN: 9780134581064

Author: Bruice, Paula Yurkanis

Publisher: Prentice Hall

See similar textbooks

Concept explainers

Catalysis and Enzymatic Reactions

Catalysis is the kind of chemical reaction in which the rate (speed) of a reaction is enhanced by the catalyst which is not consumed during the process of reaction and afterward it is removed when the catalyst is not used to make up the impurity in the p…

Lock And Key Model

The lock-and-key model is used to describe the catalytic enzyme activity, based on the interaction between enzyme and substrate. This model considers the lock as an enzyme and the key as a substrate to explain this model. The concept of how a unique dist…

Videos

Textbook Question

Chapter 15.4, Problem 8P

What is the product of an acyl substitution reaction—a new carboxylic acid derivative, a mixture of two carboxylic acid derivatives, or no reaction—if the new group in the tetrahedral intermediate is the following?

a. a stronger base than the substituent that is attached to the acyl group
b. a weaker base than the substituent that is attached to the acyl group
c. similar in basicity to the substituent that is attached to the acyl group

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Chapter 15.4, Problem 7P

Chapter 15.5, Problem 9P

Students have asked these similar questions

(f) SO: Best Lewis Structure 3 e group geometry:_ shape/molecular geometry:, (g) CF2CF2 Best Lewis Structure polarity: e group arrangement:_ shape/molecular geometry: (h) (NH4)2SO4 Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):

1. Problem Set 3b Chem 141 For each of the following compounds draw the BEST Lewis Structure then sketch the molecule (showing bond angles). Identify (i) electron group geometry (ii) shape around EACH central atom (iii) whether the molecule is polar or non-polar (iv) (a) SeF4 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: (b) AsOBr3 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles):

(c) SOCI Best Lewis Structure 2 e group arrangement: shape/molecular geometry:_ (d) PCls Best Lewis Structure polarity: e group geometry:_ shape/molecular geometry:_ (e) Ba(BrO2): Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):

Chapter 15 Solutions

Organic Chemistry; Organic Chemistry Study Guide A Format: Kit/package/shrinkwrap

Ch. 15.1 - The aromas of many flowers and fruits are due to...Ch. 15.1 - Name the following:Ch. 15.1 - Prob. 3P Ch. 15.2 - Which is longer, the carbon-oxygen single bond in...Ch. 15.2 - There are three carbon-oxygen bonds in methyl...Ch. 15.2 - Prob. 6P Ch. 15.4 - a. What is the product of the reaction of acetyl...Ch. 15.4 - What is the product of an acyl substitution...Ch. 15.5 - a. Which compound has the stretching vibration for...Ch. 15.5 - Using the pKa values listed in Table 15.1, predict...

Ch. 15.5 - Is the following statement true or false? If the...Ch. 15.6 - Starting with acetyl chloride, what neutral...Ch. 15.6 - Prob. 13P Ch. 15.7 - Starting with methyl acetate, what neutral...Ch. 15.7 - We saw that it is necessary to use excess amine in...Ch. 15.7 - Prob. 17P Ch. 15.7 - Which ester hydrolyzes more rapidly? a. methyl...Ch. 15.7 - a. state three factors that cause the uncatalyzed...Ch. 15.8 - Prob. 21P Ch. 15.8 - Using the mechanism for the acid-catalyzed...Ch. 15.8 - Prob. 23P Ch. 15.8 - Show the mechanism for the acid-catalyzed...Ch. 15.8 - Prob. 25P Ch. 15.8 - Write the mechanism for the acid-catalyzed...Ch. 15.8 - Write the mechanism for the acid-catalyzed...Ch. 15.9 - Prob. 28P Ch. 15.9 - Prob. 29P Ch. 15.10 - Show how each of the following esters could he...Ch. 15.10 - Prob. 32P Ch. 15.11 - Prob. 33P Ch. 15.11 - Which of the following reactions leads to the...Ch. 15.12 - Prob. 35P Ch. 15.12 - Prob. 36P Ch. 15.13 - Prob. 37P Ch. 15.14 - Prob. 38P Ch. 15.14 - Prob. 39P Ch. 15.15 - Prob. 40P Ch. 15.15 - Which alkyl halides from the carboxylic acids...Ch. 15.16 - Prob. 43P Ch. 15.16 - Prob. 44P Ch. 15.16 - Prob. 45P Ch. 15.17 - Prob. 46P Ch. 15.18 - How could you synthesize the following compounds...Ch. 15 - Prob. 48P Ch. 15 - Name the following:Ch. 15 - Prob. 50P Ch. 15 - What compound are obtained from the fallowing...Ch. 15 - a. Rank the following esters in order of...Ch. 15 - Because bromocyclohexane is a secondary alkyl...Ch. 15 - a. Which compound would you expect to have a...Ch. 15 - How could you use 1H NMR spectroscopy to...Ch. 15 - Rank the following compounds in order of...Ch. 15 - Prob. 57P Ch. 15 - Prob. 58P Ch. 15 - Prob. 59P Ch. 15 - A compound with molecular formula C5H10O2 gives...Ch. 15 - Prob. 61P Ch. 15 - Prob. 62P Ch. 15 - Prob. 63P Ch. 15 - Prob. 64P Ch. 15 - Prob. 65P Ch. 15 - Prob. 66P Ch. 15 - Two products, A and B, are obtained from the...Ch. 15 - Prob. 68P Ch. 15 - Prob. 69P Ch. 15 - Prob. 70P Ch. 15 - Prob. 71P Ch. 15 - Prob. 72P Ch. 15 - When treated with an equivalent of methanol,...Ch. 15 - a. Identify the two products obtained from the...Ch. 15 - Prob. 75P Ch. 15 - Prob. 76P Ch. 15 - a. When a carboxylic acid is dissolved in...Ch. 15 - Prob. 78P Ch. 15 - Identity the major and minor products of the...Ch. 15 - When a compound with molecular formula C11H14O2...Ch. 15 - Prob. 81P Ch. 15 - Prob. 82P Ch. 15 - Prob. 83P Ch. 15 - The 1H NMR spectra for two esters with molecular...Ch. 15 - Show how the following compounds could be prepared...Ch. 15 - Prob. 86P Ch. 15 - Prob. 87P Ch. 15 - The intermediate shown here is formed during the...Ch. 15 - Prob. 89P Ch. 15 - Propose a mechanism that accounts for the...Ch. 15 - Catalytic antibodies catalyze a reaction by...Ch. 15 - Prob. 92P

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Solution Summary: The author explains that the carboxylic acid and its derivatives undergo nucleophilic acyl substitution reaction.

Concept explainers

Videos

Want to see the full answer?

Chapter 15 Solutions