Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 15.10, Problem 15.21P
Why is it much easier to overdose on a fat-soluble vitamin than a water-soluble vitamin?
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7. What is the IUPAC name of the following compound?
A) (R)-1-oxo-2-butanol
C) (R)-2-hydroxybutanal
E) (S)-1-formyl-1-propanol
B) (S)-1-oxo-2-butanol
D) (S)-2-hydroxybutanal
OH
H
Cual es la formula semidesarrollada del 3-metil-1-butino?
2. A graph shown below shows first ionization energies for elements from H to Ne.
First ionization energy/kJ mol
2500
2000
1500
1000
500
T
T
T
T
1
2
3
5
6
7
8
9
10
Atomic number
a) Using arguments of electronic structure, explain why ionization energy of Li is much
lower than that of H.
(2 points)
then dips at O.
b) Using the same arguments, explain why ionization energy increases from B to N, and
(3 points)
Chapter 15 Solutions
Principles of General, Organic, Biological Chemistry
Ch. 15.1 - In which solvents or solutions will a lipid be...Ch. 15.2 - (a) Draw a skeletal structure for each fatty acid....Ch. 15.2 - Prob. 15.3PCh. 15.2 - Prob. 15.4PCh. 15.3 - Draw the structure of a wax formed from stearic...Ch. 15.3 - One component of jojoba oil is a wax formed from...Ch. 15.3 - What hydrolysis products are formed when cetyl...Ch. 15.4 - Draw the structure of a triacylglycerol that...Ch. 15.4 - Prob. 15.9PCh. 15.4 - Draw the structure of a triacylglycerol that fits...
Ch. 15.5 - Draw the products formed from hydrolysis of each...Ch. 15.5 - Prob. 15.12PCh. 15.6 - Draw the structure of two different cephalins...Ch. 15.6 - Classify each lipid as a triacylglycerol,...Ch. 15.7 - Why are phospholipids rather than triacylglycerols...Ch. 15.7 - Prob. 15.16PCh. 15.8 - Prob. 15.17PCh. 15.8 - Prob. 15.18PCh. 15.9 - Prob. 15.19PCh. 15.9 - Prob. 15.20PCh. 15.10 - Why is it much easier to overdose on a fat-soluble...Ch. 15.10 - Prob. 15.22PCh. 15 - Prob. 15.23UKCCh. 15 - Prob. 15.24UKCCh. 15 - Prob. 15.25UKCCh. 15 - What hydrolysis products are formed when the wax...Ch. 15 - Prob. 15.27UKCCh. 15 - Prob. 15.28UKCCh. 15 - Draw the products formed when the given...Ch. 15 - Prob. 15.30UKCCh. 15 - Prob. 15.31UKCCh. 15 - Prob. 15.32UKCCh. 15 - Prob. 15.33APCh. 15 - Label each compound as a hydrolyzable or...Ch. 15 - Prob. 15.35APCh. 15 - Prob. 15.36APCh. 15 - Prob. 15.37APCh. 15 - How does each of the following affect the melting...Ch. 15 - Rank the fatty acids in order of increasing...Ch. 15 - How would you expect the melting points of the...Ch. 15 - Prob. 15.41APCh. 15 - Why are soaps water soluble, but the fatty acids...Ch. 15 - Draw the structure of a wax formed from palmitic...Ch. 15 - Prob. 15.44APCh. 15 - Prob. 15.45APCh. 15 - Prob. 15.46APCh. 15 - Prob. 15.47APCh. 15 - What hydrolysis products are formed when each wax...Ch. 15 - Draw a triacylglycerol that fits each description:...Ch. 15 - Draw a triacylglycerol that fits each description:...Ch. 15 - Prob. 15.51APCh. 15 - Prob. 15.52APCh. 15 - Prob. 15.53APCh. 15 - Prob. 15.54APCh. 15 - Prob. 15.55APCh. 15 - Draw the products formed when the given...Ch. 15 - Prob. 15.57APCh. 15 - Prob. 15.58APCh. 15 - Prob. 15.59APCh. 15 - Prob. 15.60APCh. 15 - Prob. 15.61APCh. 15 - Why are LDLs soluble in the blood?Ch. 15 - Describe the role of HDLs and LDLs in cholesterol...Ch. 15 - Prob. 15.64APCh. 15 - Prob. 15.65APCh. 15 - Prob. 15.66APCh. 15 - Answer each question with regards to vitamins A...Ch. 15 - Answer each question in Problem 15.67 for vitamins...Ch. 15 - Prob. 15.69APCh. 15 - Prob. 15.70APCh. 15 - Prob. 15.71APCh. 15 - How are soaps and phosphoacylglycerols similar in...Ch. 15 - Some fish oils contain triacylglycerols formed...Ch. 15 - Some marine plankton contain triacylglycerols...Ch. 15 - Prob. 15.75APCh. 15 - Prob. 15.76APCh. 15 - Prob. 15.77APCh. 15 - Prob. 15.78APCh. 15 - Prob. 15.79CPCh. 15 - Prob. 15.80CP
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- Give the name of this compound, including stereochemistry if relevant: CICH2 CH3 Br CH₂CH=CH2 Write in the product, including stereochemistry where relevant, for these reactions. See end of ch. 8, p. 301-303. 1. 03 a) 2-methyl-2-pentene -> 2. Zn, H* Br2 b) 1-ethylcyclopentene -->arrow_forwardNonearrow_forward3. You may want to read paragraph 1.5 in your textbook before answering this question. Give electron configuration (short-hand notation is fine) for: (5 points) 3+ a) Manganese atom and Mn³+ b) Se atom c) Cu atom and Cu+arrow_forward
- However, why are intermolecular forces in metallic and ionic compounds not discussed as extensively? Additionally, what specific types of intermolecular attractions exist in metals and ionic compoundsarrow_forwardWhat is the preparation of 1 Liter of 0.1M NH4Cl buffer at pH 9.0 with solid NH4Cl and 0.1M NaOH. How would I calculate the math to describe this preparation? How would I use Henderson-Hasselbach equation?arrow_forwardC Predict the major products of this organic reaction. Be sure you use wedge and dash bonds when necessary, for example to distinguish between major products with different stereochemistry. : ☐ + x G C RCO₂H Click and drag to start drawing a structure.arrow_forward
- Fill in the blanks by selecting the appropriate term from below: For a process that is non-spontaneous and that favors products at equilibrium, we know that a) ΔrG∘ΔrG∘ _________, b) ΔunivSΔunivS _________, c) ΔsysSΔsysS _________, and d) ΔrH∘ΔrH∘ _________.arrow_forwardHighest occupied molecular orbital Lowest unoccupied molecular orbital Label all nodes and regions of highest and lowest electron density for both orbitals.arrow_forwardRelative Intensity Part VI. consider the multi-step reaction below for compounds A, B, and C. These compounds were subjected to mass spectrometric analysis and the following spectra for A, B, and C was obtained. Draw the structure of B and C and match all three compounds to the correct spectra. Relative Intensity Relative Intensity 20 NaоH 0103 Br (B) H2504 → (c) (A) 100- MS-NU-0547 80 40 20 31 10 20 100- MS2016-05353CM 80 60 100 MS-NJ-09-3 80 60 40 20 45 J.L 80 S1 84 M+ absent राग 135 137 S2 62 164 166 11 S3 25 50 75 100 125 150 175 m/zarrow_forward
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