To explain the following result obtain from theHammett equation. Concept introduction: Hammett reaction constant ( ρ )is the slope of logarithm of rate constant ( logk ) versusHammett substitution constant ( σ ) graph. The logk Vs σ graph can be represented as: The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

Question

2. Provide the structure of the major organic product in the following reaction. Pay particular attention to the regio- and stereochemistry of your product. H3CO + H CN A

Answer 1

Question

Chapter 15, Problem 92P

(a)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction:

Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

(b)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction:

Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

(c)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction: Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

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2. Provide the structure of the major organic product in the following reaction. Pay particular attention to the regio- and stereochemistry of your product. H3CO + H CN A

Predict the major products of the following organic reaction.

1) The isoamyl acetate report requires eight paragraphs - four for comparison of isoamyl alcohol and isoamyl acetate (one paragraph each devoted to MS, HNMR, CNMR and IR) and four for comparison of acetic acid and isoamyl acetate ((one paragraph each devoted to MS, HNMR, CNMR and IR. 2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too. 3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of…

Answer 2

Question

Chapter 15, Problem 92P

(a)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction:

Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

(b)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction:

Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

(c)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction: Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

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Answer 3

Question

Chapter 15, Problem 92P

(a)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction:

Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

(b)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction:

Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

(c)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction: Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

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Answer 4

Question

Chapter 15, Problem 92P

(a)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction:

Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

(b)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction:

Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

(c)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction: Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

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Answer 5

Chapter 15, Problem 92P

(a)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction:

Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

(b)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction:

Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

(c)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction: Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

Answer 6

Chapter 15, Problem 92P

(a)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction:

Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

Answer 7

Chapter 15, Problem 92P

(a)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction:

Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

Answer 8

(b)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction:

Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

Answer 9

(b)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction:

Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

Answer 10

(c)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction: Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

Answer 11

(c)

Interpretation Introduction

Interpretation:

To explain the following result obtain from theHammett equation.

Concept introduction: Hammett reaction constant (ρ)is the slope of logarithm of rate constant (logk) versusHammett substitution constant (σ) graph. The logk Vs σ graph can be represented as:

The negative value of the ρ means electrons flow out from the aromatic ring in the rate-determining step and positive value of ρ electrons flow into the aromatic ring in the rate determining step.

Answer 12

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Ch. 15.1 - The aromas of many flowers and fruits are due to...Ch. 15.1 - Name the following:Ch. 15.1 - Prob. 3P Ch. 15.2 - Which is longer, the carbon-oxygen single bond in...Ch. 15.2 - There are three carbon-oxygen bonds in methyl...Ch. 15.2 - Prob. 6P Ch. 15.4 - a. What is the product of the reaction of acetyl...Ch. 15.4 - What is the product of an acyl substitution...Ch. 15.5 - a. Which compound has the stretching vibration for...Ch. 15.5 - Using the pKa values listed in Table 15.1, predict...

Solution Summary: The author explains the Hammett reaction constant, which is the slope of logarithm of rate constant ( logk ) versusHammet

Chapter 15 Solutions