Concept explainers
Interpretation:
Acid-base reaction between perchloric acid and hydroxide ion should be written and each of the acid-base and conjugates has to be identified.
Concept Introduction:
Bronsted-Lowry acid outlined the definition of acids that donate
In accordance with Bronsted definition, the most usual type of acid-base reaction involves lone pair of base that reaches out for an acidic proton. Once deprotonation has occurred species assumes a negative charge and is referred to as the conjugate base of acid and other species with a positive charge as a result of proton acceptance is termed conjugate acid of given base. For example;
The strength of conjugate acid-base pairs is inversely related to each other; thus strong acid has a weak and strong base has weak conjugate counterparts and vice-versa.
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Foundations of College Chemistry, Binder Ready Version
- (a) What is the pH of a 0.105 M HCl solution? (b) What is the hydronium ion concentration in a solution with a pH of 2.56? Is the solution acidic or basic? (c) A solution has a pH of 9.67. What is the hydronium ion concentration in the solution? Is the solution acidic or basic? (d) A 10.0-mL sample of 2.56 M HCl is diluted with water to 250. mL What is the pH of the dilute solution?arrow_forwardA Liquid HF undergoes an autoionization reaction: 2HFH2F++F (a) Is KF an acid or a base in this solvent? (b) Perchloric acid, HCIO4, is a strong acid in liquid HF. Write the chemical equation for the ionization reaction. (c) Ammonia is a strong base in this solvent. Write the chemical equation for the ionization reaction. (d) Write the net ionic equation for the neutralization of perchloric acid with ammonia in this solvent.arrow_forwardClassify each of the following as a strong or weak acid or base. a NH3 b HCNO c Mg(OH)2 d HClO3arrow_forward
- Write two BrnstedLowry acid-base reactions and show how they represent proton-transfer reactions.arrow_forwardConsider the following ions: NH4+, CO32, Br, S2, and ClO4. (a) Which of these ions in water gives an acidic solution and which gives a basic solution? (b) Which of these anions will have no effect on the pH of an aqueous solution? (c) Which ion is the strong base? (d) Write a chemical equation for the reaction of each basic anion with water.arrow_forwardWrite chemical equations showing the individual proton-transfer steps that occur in aqueous solution for each of the following acids. a. H2C2O4 (oxalic acid) b. H2C4H4O6 (tartaric acid)arrow_forward
- Two strategies are also followed when solving for the pH of a base in water. What is the strategy for calculating the pH of a strong base in water? List the strong bases mentioned in the text that should be committed to memory. Why is calculating the pH of Ca(OH)2 solutions a little more difficult than calculating the pH of NaOH solutions? Most bases are weak bases. The presence of what element most commonly results in basic properties for an organic compound? What is present on this element in compounds that allows it to accept a proton? Table 13-3 and Appendix 5 of the text list Kb values for some weak bases. What strategy is used to solve for the pH of a weak base in water? What assumptions are made when solving for the pH of weak base solutions? If the 5% rule fails, how do you calculate the pH of a weak base in water?arrow_forwardWrite chemical equations showing the individual proton-transfer steps that occur in aqueous solution for each of the following acids. a. H2CO3 (carbonic acid) b. H2C3H2O4 (malonic acid)arrow_forwardAcids You make a solution by dissolving 0.0010 mol of HCl in enough water to make 1.0 L of solution. a Write the chemical equation for the reaction of HCl(aq) and water. b Without performing calculations, give a rough estimate of the pH of the HCl solution. Justify your answer. c Calculate the H3O+ concentration and the pH of the solution. d Is there any concentration of the base OH present in this solution of HCl(aq)? If so, where did it come from? e If you increase the OH concentration of the solution by adding NaOH, does the H3O+ concentration change? If you think it does, explain why this change occurs and whether the H3O+ concentration increases or decreases. f If you were to measure the pH of 10 drops of the original HCl solution, would you expect it to be different from the pH of the entire sample? Explain. g Explain how two different volumes of your original HCl solution can have the same pH yet contain different moles of H3O+. h If 1.0 L of pure water were added to the HCl solution, would this have any impact on the pH? Explain.arrow_forward
- 12.62 Write the formula of the conjugate acid of each of the following bases, (a) OH-, (b) NHj, (c) CHjNHt, (d) HPO/-, (e) CO.,2’arrow_forwardExplain the difference between a monoprotic acid, a diprotic acid, and a triprotic acid. Give an example of each.arrow_forwardDraw a curve similar to that shown in Figure 14.23 for a series of solutions of NH3. Plot [OH-] on the vertical axis and the total concentration of NH3 (both ionized and nonionized NH3 molecules) on the horizontal axis. Let the total concentration of NH3 vary from 11010M to 1102M.arrow_forward
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