Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 15, Problem 73QAP
Challenge Problems
Insoluble hydroxides such as Zn(OH)2 are better dissolved in solutions that are slightly acidic, such as aqueous HCN. Find the molar solubility of Ca(OH)2 in 0.15 M HCN and compare it with the solubility in water: (Hint: Find K for the following reaction.)
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
6. Which of the following processes will increase the pH of a buffer solution prepared by mixing 0.89 mol
HCOOH (formic acid) and 0.76 mol HCOONa (sodium formate) into a 1-L solution? Ka (HCOOH) = 1.8 x 104.
%3D
a) add some NaCl into the buffer solution.
b) add some HCl into the buffer solution.
c) add some NaOH into the buffer solution.
d) add more water into the buffer solution.
e) None of the above.
NaCl (s) ⇌ Na+(aq) + Cl-(aq)
When adding 6M HCl, the solid white precipitate is observed.
When adding 0.1M HCl, no change is observed, no solid white precipitate is observed in the NaCl solution.
Explain the similarities and differences by using Le Chatlier's principle.
A friend tells you: " The constant K sp of a salt is called the sol ubility product constant and is calculated from the concentra tions of ions in the solution . Thus, if salt A dissolves to a greater extent than salt B , salt A must have a higher K sp than salt B. Do you agree with your friend ? Explain . Explain the following phenomenon You a test tube with
Chapter 15 Solutions
Chemistry: Principles and Reactions
Ch. 15 - Write a net ionic equation for the reaction...Ch. 15 - Write a net ionic equation for the reaction...Ch. 15 - Write a balanced net ionic equation for the...Ch. 15 - Write a balanced net ionic equation for the...Ch. 15 - Calculate K for the reactions in Question 1.Ch. 15 - Calculate K for the reactions in Question 2.Ch. 15 - Calculate K for the reactions in Question 3.Ch. 15 - Calculate K for the reactions in Question 4.Ch. 15 - Calculate [H+] and pH in a solution in which...Ch. 15 - Calculate [OH-] and pH in a solution in which the...
Ch. 15 - A buffer is prepared by dissolving 0.0250 mol of...Ch. 15 - Prob. 12QAPCh. 15 - A buffer solution is prepared by adding 15.00 g of...Ch. 15 - A buffer solution is prepared by adding 5.50 g of...Ch. 15 - A solution with a pH of 9.22 is prepared by adding...Ch. 15 - An aqueous solution of 0.057 M weak acid, HX, has...Ch. 15 - Which of the following would form a buffer if...Ch. 15 - Which of the following would form a buffer if...Ch. 15 - Calculate the solubility (in grams per liter) of...Ch. 15 - Calculate the solubility (in grams per liter) of...Ch. 15 - Copper(l) chloride, CuCl, is the starting material...Ch. 15 - Prob. 22QAPCh. 15 - Prob. 23QAPCh. 15 - Ksp for CaSO4 at 100C is estimated to be1.6105. At...Ch. 15 - Prob. 25QAPCh. 15 - At 25C, 10.24 mg of Cr(OH)2 are dissolved in...Ch. 15 - Calcium nitrate is added to a sodium sulfate...Ch. 15 - Cadmium(ll) chloride is added to a solution of...Ch. 15 - Water from a well is found to contain 3.0 mg of...Ch. 15 - Silver(I) sulfate (Ksp=1.2105) is used in the...Ch. 15 - A solution is prepared by mixing 13.00 mL of...Ch. 15 - A solution is prepared by mixing 45.00 mL of 0.022...Ch. 15 - A solution is 0.047 M in both NaF and Na2CO3....Ch. 15 - Solid lead nitrate is added to a solution that is...Ch. 15 - A solution is made up by adding 0.632 g of barium...Ch. 15 - A solution is made up by adding 0.839 g of...Ch. 15 - Prob. 37QAPCh. 15 - To a beaker with 500 mL of water are added 95 mg...Ch. 15 - Write net ionic equations for the reaction of H+...Ch. 15 - Prob. 40QAPCh. 15 - Prob. 41QAPCh. 15 - Write a net ionic equation for the reaction with...Ch. 15 - Prob. 43QAPCh. 15 - Write a net ionic equation for the reaction with...Ch. 15 - Prob. 45QAPCh. 15 - Write an overall net ionic equation and calculate...Ch. 15 - Consider the reaction...Ch. 15 - Consider the reaction BaF2(s)+SO42(aq)BaSO4(s)+2...Ch. 15 - Aluminum hydroxide reacts with an excess of...Ch. 15 - Prob. 50QAPCh. 15 - Calculate the molar solubility of gold(I) chloride...Ch. 15 - Calculate the molar solubility of PbCl2 in 0.2 M...Ch. 15 - For the reaction...Ch. 15 - For the reaction Zn(OH)2(s)+2OH(aq)Zn(OH)42(aq)...Ch. 15 - What are the concentrations of Cu2+, NH3, and...Ch. 15 - Prob. 56QAPCh. 15 - Calcium ions in blood trigger clotting. To prevent...Ch. 15 - Prob. 58QAPCh. 15 - A town adds 2.0 ppm of F- ion to fluoridate its...Ch. 15 - Consider the following hypothetical dissociation:...Ch. 15 - Prob. 61QAPCh. 15 - Consider a 2.0-L aqueous solution of 4.17 M NH3,...Ch. 15 - Marble is almost pure CaCO3. Acid rain has a...Ch. 15 - Prob. 64QAPCh. 15 - Prob. 65QAPCh. 15 - The box below represents one liter of a saturated...Ch. 15 - Consider a saturated solution of BaCO3 at 7.5C....Ch. 15 - Prob. 68QAPCh. 15 - Consider the insoluble salts JQ, K2R, L2S3, MT2,...Ch. 15 - Prob. 70QAPCh. 15 - Consider the equilibrium curve for AgCl shown...Ch. 15 - Dissolving CaCO3 is an endothermic reaction. The...Ch. 15 - Challenge Problems Insoluble hydroxides such as...Ch. 15 - What is the solubility of CaF2 in a buffer...Ch. 15 - What is [Br-] just as AgCl begins to precipitate...Ch. 15 - Prob. 76QAPCh. 15 - Prob. 77QAPCh. 15 - Prob. 78QAP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- What do you suppose happens to the Ksp, value of a solid as the temperature of the solution changes? Consider both increasing and decreasing temperatures, and explain your answer.arrow_forwardMarble is almost pure CaCO3. Acid rain has a devastating effect on marble statuary left outdoors. Assume that the reaction which occurs is CoCO3(s)+ H+(aq)Ca2+(aq)+HCO3(aq) Neglecting all other competing equilibria and using Tables 15.1 and 13.2, calculate (a) K for the reaction. (b) the molar solubility of CaCO3 in pure water. (c) the molar solubility of CaCO3 in acid rainwater with a pH of 4.00.arrow_forwardHow many grams of Zn(CN)2(s) (117.44 g/mol) would be soluble in 100 mL of H2O? Include the balanced reaction and the expression for Ksp in your answer. The KSP value for Zn(CN)2(s) is 3.01016.arrow_forward
- How to solve thisarrow_forwardThe K sp for silver sulfate (Ag 2 SO 4 ) is 1.2 x 10 -5 .i) Write the chemical equation that shows the equilibrium between solid Ag 2 SO 4 and its aqueous ions. ii) Calculate its molar solubility of Ag 2 SO 4 in 0.20 M K 2 SO 4arrow_forward7. A common buffer solution can be prepared by using ammonia and ammonium salts. The base equilibrium constant of ammonia, NH3, is 1.815x10-5 A student worker is asked to prepare a buffer solution with NH3 and ammonium salt. However, after the student did a thorough search, no ammonium salt is found. After the student reported the result to the professor, the professor told the student the buffer can be prepared with ammonia and a strong acid. Can you help this student out? The pH of the buffer to be prepared is 10.08. The molarity of the ammonia in the buffer is 0.4717 M. The molarity of the ammonia solution found in the laboratory is 1.201 M, the strong acid solution is 0.9948 M HNO3. The volume of the buffer solution to be prepared is 500.0 mL. Please answer the following questions. A. B. What is the molarity of the ammonium ion in the buffer? Please provider your answer below. Check answer How many mL of 0.9948 M HNO3 solution is needed? Please provider your answer below. 0² 0₂ $…arrow_forward
- Please don't provide hnad writtin solution.....arrow_forward-5 chemistry graduate student is given 450. mL of a 0.60M propanoic acid (HC,H,CO,) solution. Propanoic acid is a weak acid with K=1.3 × 10 °. What ass of KC, H,CO, should the student dissolve in the HC,H,CO, solution to turn it into a buffer with pH =4.91? ou may assume that the volume of the solution doesn't change when the KC, H,CO, is dissolved in it. Be sure your answer has a unit symbol, and round it to significant digits.arrow_forwardTo an aqueous solution originally containing 1.0 x 10^-4 mol/L Ag+ was added enough of the weak acid HCN to reach an equilibrium concentration of [HCN] = 3.0 x 10^-4 mol/L. What must be the pH of the solution in order to observe a precipitate of AGCN? (Hint: Assume any change in pH will not change the value of [HCN]). K sp of AGCN = 1.2 x 10-16 Ka of HCN = 6.2 × 10-10 %3Darrow_forward
- You have 500.0 mL of a buffer solution containing 0.30 M acetic acid (CH3COOH) and 0.20 M sodium acetate (CH3COONa). What will the pH of this solution be after the addition of 20.0 mL of 1.00 M NaOH solution? [Ka(CH3COOH) = 1.8 × 10–5]arrow_forwardWhat is the equilibrium concentration of CN- in a solution that is initially 0.2M Ni2+ and 1.2M CN-. The K_f of Ni(CN)4 is 2*10^31.arrow_forwardThe solubility product of silver iodide is 8.5 X 10-17. AgI(s) --> Ag+(aq) + I-(aq) If 5.5 grams of AgI(s) is added to 100 mL water and allowed to equilibrate, what is the equilibrium concentration of I-?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Introductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Introductory Chemistry: A Foundation
Chemistry
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
General Chemistry | Acids & Bases; Author: Ninja Nerd;https://www.youtube.com/watch?v=AOr_5tbgfQ0;License: Standard YouTube License, CC-BY