Concept explainers
(a)
Interpretation:
The concentration of
Concept introduction:
The equilibrium equation and
To write the expression of solubility product, one must remember that the solid does not appear in the expression and the concentration of each ion is raised to a power equal to its coefficient in the chemical equation.
(b)
Interpretation:
The concentration of
Concept introduction:
The equilibrium equation and
To write the expression of solubility product, one must remember that the solid does not appear in the expression and the concentration of each ion is raised to a power equal to its coefficient in the chemical equation.
(c)
Interpretation:
The concentration of
Concept introduction:
The equilibrium equation and
To write the expression of solubility product, one must remember that the solid does not appear in the expression and the concentration of each ion is raised to a power equal to its coefficient in the chemical equation.
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Chapter 15 Solutions
Chemistry: Principles and Reactions
- Ka for formic acid is 1.7 104 at 25C. A buffer is made by mixing 529 mL of 0.465 M formic acid, HCHO2, and 494 mL of 0.524 M sodium formate, NaCHO2. Calculate the pH of this solution at 25C after 110 mL of 0.152 M HCl has been added to this buffer.arrow_forwardA solution is prepared by dissolving 0.350 g of benzoic acid, HC7H5O2, in water to make 100.0 mL of solution. A 30.00-mL sample of the solution is titrated with 0.272 M KOH. Calculate the pH of the solution (a) before titration. (b) halfway to the equivalence point. (c) at the equivalence point.arrow_forwardBriefly describe how a buffer solution can control the pH of a solution when strong acid is added and when strong base is added. Use NH3/NH4Cl as an example of a buffer and HCl and NaOH as the strong acid and strong base.arrow_forward
- A buffer solution is prepared from 5.15 g NH4NO3 and 0.10 L of 0.15-M NH3; calculate the pH of the solution.arrow_forwardWhat is the pH of a buffer that is 0.150 M in a weak acid and 0.150 M in the acids conjugate base? The acids ionization constant is 6.8 106.arrow_forwardA buffer solution is prepared by adding 0.125 mol ammonium chloride to 500. mL of 0.500-M aqueous ammonia. Calculate the pH of the buffer. If 0.0100 mol HCl gas is bubbled into 500. mL buffer and all of the gas dissolves, calculate the new pH of the solution.arrow_forward
- Calculate the pH change when 10.0 mL of 0.100-M NaOH is added to 90.0 mL pure water, and compare the pH change with that when the same amount of NaOH solution is added to 90.0 mL of a buffer consisting of 1.00-M NH3 and 1.00-M NH4Cl. Assume that the volumes are additive. Kb of NH3 = 1.8 × 10-5.arrow_forwardWithout doing calculations, determine the pH of a buffer made front equimolar amounts of these acid-base pairs. (a) Nitrous acid and sodium nitrite (b) Ammonia and ammonium chloride (c) Formic acid and potassium formatearrow_forwardA buffer is prepared by dissolving 0.062 mol of sodium fluoride in 127 mL of 0.0399 M hydrofluoric acid. Assume no volume change after NaF is added. Calculate the pH of this buffer.arrow_forward
- Ammonia gas is bubbled into 275 mL of water to make an aqueous solution of ammonia. To prepare a buffer with a pH of 9.56, 15.0 g of NH4Cl are added. How many liters of NH3; at 25C and 0.981 atm should be used to prepare the buffer? Assume no volume changes and ignore the vapor pressure of water.arrow_forwardYou want to make a buffer with a pH of 10.00 from NH4+/NH3. (a) What must the [ NH4+ ]/[ NH3 ]ratio be? (b) How many moles of NH4Cl must be added to 465 mL of an aqueous solution of 1.24 M NH3 to give this pH? (c) How many milliliters of 0.236 M NH3 must be added to 2.08 g of NH4Cl to give this pH? (d) What volume of 0.499 M NH3 must be added to 395 mL, of 0.109 M NH4Cl to give this pH?arrow_forwardA sodium hydrogen carbonate-sodium carbonate buffer is to be prepared with a pH of 9.40. (a) What must the [ HCO3 ]/[ CO32 ]ratio be? (b) How many moles of sodium hydrogen carbonate must be added to a liter of 0.225 M Na2CO3 to give this pH? (c) How many grams of sodium carbonate must be added to 475 mL of 0.336 M NaHCO3 to give this pH? (Assume no volume change.) (d) What volume of 0.200 M NaHCO3 must be added to 735 mL of a 0.139 M solution of Na2CO3 to give this pH? (Assume that volumes are additive.)arrow_forward
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