Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 15, Problem 59QAP
A town adds 2.0 ppm of F- ion to fluoridate its water supply. (Fluoridation of water reduces the incidence of dental caries). If the concentration of Ca2+ in the water is
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Chapter 15 Solutions
Chemistry: Principles and Reactions
Ch. 15 - Write a net ionic equation for the reaction...Ch. 15 - Write a net ionic equation for the reaction...Ch. 15 - Write a balanced net ionic equation for the...Ch. 15 - Write a balanced net ionic equation for the...Ch. 15 - Calculate K for the reactions in Question 1.Ch. 15 - Calculate K for the reactions in Question 2.Ch. 15 - Calculate K for the reactions in Question 3.Ch. 15 - Calculate K for the reactions in Question 4.Ch. 15 - Calculate [H+] and pH in a solution in which...Ch. 15 - Calculate [OH-] and pH in a solution in which the...
Ch. 15 - A buffer is prepared by dissolving 0.0250 mol of...Ch. 15 - Prob. 12QAPCh. 15 - A buffer solution is prepared by adding 15.00 g of...Ch. 15 - A buffer solution is prepared by adding 5.50 g of...Ch. 15 - A solution with a pH of 9.22 is prepared by adding...Ch. 15 - An aqueous solution of 0.057 M weak acid, HX, has...Ch. 15 - Which of the following would form a buffer if...Ch. 15 - Which of the following would form a buffer if...Ch. 15 - Calculate the solubility (in grams per liter) of...Ch. 15 - Calculate the solubility (in grams per liter) of...Ch. 15 - Copper(l) chloride, CuCl, is the starting material...Ch. 15 - Prob. 22QAPCh. 15 - Prob. 23QAPCh. 15 - Ksp for CaSO4 at 100C is estimated to be1.6105. At...Ch. 15 - Prob. 25QAPCh. 15 - At 25C, 10.24 mg of Cr(OH)2 are dissolved in...Ch. 15 - Calcium nitrate is added to a sodium sulfate...Ch. 15 - Cadmium(ll) chloride is added to a solution of...Ch. 15 - Water from a well is found to contain 3.0 mg of...Ch. 15 - Silver(I) sulfate (Ksp=1.2105) is used in the...Ch. 15 - A solution is prepared by mixing 13.00 mL of...Ch. 15 - A solution is prepared by mixing 45.00 mL of 0.022...Ch. 15 - A solution is 0.047 M in both NaF and Na2CO3....Ch. 15 - Solid lead nitrate is added to a solution that is...Ch. 15 - A solution is made up by adding 0.632 g of barium...Ch. 15 - A solution is made up by adding 0.839 g of...Ch. 15 - Prob. 37QAPCh. 15 - To a beaker with 500 mL of water are added 95 mg...Ch. 15 - Write net ionic equations for the reaction of H+...Ch. 15 - Prob. 40QAPCh. 15 - Prob. 41QAPCh. 15 - Write a net ionic equation for the reaction with...Ch. 15 - Prob. 43QAPCh. 15 - Write a net ionic equation for the reaction with...Ch. 15 - Prob. 45QAPCh. 15 - Write an overall net ionic equation and calculate...Ch. 15 - Consider the reaction...Ch. 15 - Consider the reaction BaF2(s)+SO42(aq)BaSO4(s)+2...Ch. 15 - Aluminum hydroxide reacts with an excess of...Ch. 15 - Prob. 50QAPCh. 15 - Calculate the molar solubility of gold(I) chloride...Ch. 15 - Calculate the molar solubility of PbCl2 in 0.2 M...Ch. 15 - For the reaction...Ch. 15 - For the reaction Zn(OH)2(s)+2OH(aq)Zn(OH)42(aq)...Ch. 15 - What are the concentrations of Cu2+, NH3, and...Ch. 15 - Prob. 56QAPCh. 15 - Calcium ions in blood trigger clotting. To prevent...Ch. 15 - Prob. 58QAPCh. 15 - A town adds 2.0 ppm of F- ion to fluoridate its...Ch. 15 - Consider the following hypothetical dissociation:...Ch. 15 - Prob. 61QAPCh. 15 - Consider a 2.0-L aqueous solution of 4.17 M NH3,...Ch. 15 - Marble is almost pure CaCO3. Acid rain has a...Ch. 15 - Prob. 64QAPCh. 15 - Prob. 65QAPCh. 15 - The box below represents one liter of a saturated...Ch. 15 - Consider a saturated solution of BaCO3 at 7.5C....Ch. 15 - Prob. 68QAPCh. 15 - Consider the insoluble salts JQ, K2R, L2S3, MT2,...Ch. 15 - Prob. 70QAPCh. 15 - Consider the equilibrium curve for AgCl shown...Ch. 15 - Dissolving CaCO3 is an endothermic reaction. The...Ch. 15 - Challenge Problems Insoluble hydroxides such as...Ch. 15 - What is the solubility of CaF2 in a buffer...Ch. 15 - What is [Br-] just as AgCl begins to precipitate...Ch. 15 - Prob. 76QAPCh. 15 - Prob. 77QAPCh. 15 - Prob. 78QAP
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- Assume that a sample of hard water contains 50. mg/L of Mg2+ and 150 mg/L of Ca2+, with HCO3 as the accompanying anion. What mass of CaO should be added to 1.0 L of this aqueous solution to precipitate all the Mg2+ and Ca2+ as CaCO3 and MgCO3? What is the total mass of the two solids formed?arrow_forwardThe Handbook of Chemistry and Physics (http://openstaxcollege.org/l/16Handbook) gives solubilities of the following compounds in grams per 100 mL of water. Because these compounds are only slightly soluble, assume that the volume does not change on dissolution and calculate the solubility product for each. (a) BaSiF6, 0.026 g/100 mL (contains SiF62- ions) (b) Ce(IO3)4, 1.5102 g/100 mL (c) Gd2(SO4)3, 3.98 g/100 mL (d) (NH4)2PtBr6, 0.59 g/100 mL (contains PtBr62- ions)arrow_forwardThe U.S. Public Health Service recommends the fluoridation of water as a means for preventing tooth decay. The recommended concentration is 1 mg F per liter. The presence of calcium ions in hard water can precipitate the added fluoride. What is the maximum molarity of calcium ions in hard water if the fluoride concentration is at the USPHS recommended level? (Ksp for CaF2 = 4.0 1011)arrow_forward
- Calculate the solubility in grams per 100 mL of BaF2 in a 0.10 M BaCl2 solution.arrow_forwardConsider the reaction BaF2(s)+SO42(aq)BaSO4(s)+2 F(aq) (a) Calculate K for the reaction. (b) Will BaSO4 precipitate if Na2SO4 is added to a saturated solution of BaF2?arrow_forwardA sample of hard water contains about 2.0 103 M Ca2+. A soluble fluoride-containing salt such as NaF is added to fluoridate the water (to aid in the prevention of dental cavities). What is the maximum concentration of F that can be present without precipitating CaF2?arrow_forward
- A solution contains 0.04900 M Ca²+ and 0.09100 M Agt. If solid Na3PO4 is added to this mixture, which of the phosphate species would precipitate out of solution first? When the second cation just starts to precipitate, what percentage of the first cation remains in solution? A solution contains 0.0490 M Ca²+ and 0.0910 M Agt. If solid Na3PO4 is added to this mixture, which of the phosphate species would precipitate out of solution first? O Ca3(PO4)2 Ag3PO4 O Na3PO4 When the second cation just starts to precipitate, what percentage of the first cation remains in solution? percentage: %arrow_forwardThe Kgp of Ca3 (PO4), is 1.3 x 10-26. Estimate the solubility of this salt in units of g. L-1. You must show any reaction equation(s) that you may think are necessary. If a sample of solid Ca3 (PO4)2 is stirred into exactly one litre of a 0.550M solution of NazPO4, how will the solubility of the salt compare with the answer that you have obtained in question 2.1? Explain you answer in a short sentence.arrow_forwardPredict whether a lead (II) iodide precipitate will form when 325.0 mL of a 0.00350 mol/L aqueous solution of lead (II) nitrate, Pb(NO3)2 (aq), is mixed with 50.0 mL of a 0.00800 mol/L aqueous solution of sodium iodide, Nal (aq) (Ksp of lead (II) iodide = 8.5 x 10-⁹) UPLOAD A FULL SOLUTION WITH THE NECESSARY BALANCED CHEMICAL REACTION(S), CALCULATIONS, AND A FINAL ANSWER.arrow_forward
- Calcium carbonate, CaCO3, has Ksp = 8.7 x 10–9. If a swimming pool water contain 225 mg/L of Ca2+, what is the maximum concentration of carbonate ion (CO32-) in the pool water that will not cause the precipitation of CaCO3?arrow_forwardThe concentration of dissolved O2 in water that is required to support aquatic life is 4.0 mg/L. Calculate the minimum partial pressure of oxygen (in kPa) in the atmosphere that is required to achieve this concentration. (Use kH= 1.30 x 10-2 mol m-3 kPa-1)arrow_forwardSolid aluminum hydroxide (Ksp = 1.3 x 1033) is added to 3.50 mM Al(NO3)3 solution until the solid no longer dissolves. What is the molar solubility of Al(OH)3 in the given solution? 2.63 x 10° M O 2.40 x 10-11 M O 1.24 x 1031 M O 3.46 x 10-11 Marrow_forward
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