The given compounds are to be synthesized by considering benzene and appropriate acyl chloride or anhydride as a starting material. Concept Introduction: The reaction of benzene with acyl chloride in the presence of a Lewis acid leads to the formation of acyl substituted benzene as a product. This reaction is called Friedel’s Craft acylation. Reduction of carbonyl group is done by its reaction with hydrazine and base in the presence of heat.

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Answer 1

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Chapter 15, Problem 5PP

Interpretation Introduction

Interpretation:

The given compounds are to be synthesized by considering benzene and appropriate acyl chloride or anhydride as a starting material.

Concept Introduction:

The reaction of benzene with acyl chloride in the presence of a Lewis acid leads to the formation of acyl substituted benzene as a product. This reaction is called Friedel’s Craft acylation.

Reduction of carbonyl group is done by its reaction with hydrazine and base in the presence of heat.

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Propose a reasonable synthesis for each of the following compounds from the indicated starting materials and any other reagents.

Answer 2

Question

Chapter 15, Problem 5PP

Interpretation Introduction

Interpretation:

The given compounds are to be synthesized by considering benzene and appropriate acyl chloride or anhydride as a starting material.

Concept Introduction:

The reaction of benzene with acyl chloride in the presence of a Lewis acid leads to the formation of acyl substituted benzene as a product. This reaction is called Friedel’s Craft acylation.

Reduction of carbonyl group is done by its reaction with hydrazine and base in the presence of heat.

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Answer 3

Question

Chapter 15, Problem 5PP

Interpretation Introduction

Interpretation:

The given compounds are to be synthesized by considering benzene and appropriate acyl chloride or anhydride as a starting material.

Concept Introduction:

The reaction of benzene with acyl chloride in the presence of a Lewis acid leads to the formation of acyl substituted benzene as a product. This reaction is called Friedel’s Craft acylation.

Reduction of carbonyl group is done by its reaction with hydrazine and base in the presence of heat.

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Answer 4

Question

Chapter 15, Problem 5PP

Interpretation Introduction

Interpretation:

The given compounds are to be synthesized by considering benzene and appropriate acyl chloride or anhydride as a starting material.

Concept Introduction:

The reaction of benzene with acyl chloride in the presence of a Lewis acid leads to the formation of acyl substituted benzene as a product. This reaction is called Friedel’s Craft acylation.

Reduction of carbonyl group is done by its reaction with hydrazine and base in the presence of heat.

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Answer 5

Chapter 15, Problem 5PP

Interpretation Introduction

Interpretation:

The given compounds are to be synthesized by considering benzene and appropriate acyl chloride or anhydride as a starting material.

Concept Introduction:

The reaction of benzene with acyl chloride in the presence of a Lewis acid leads to the formation of acyl substituted benzene as a product. This reaction is called Friedel’s Craft acylation.

Reduction of carbonyl group is done by its reaction with hydrazine and base in the presence of heat.

Answer 6

Chapter 15, Problem 5PP

Interpretation Introduction

Interpretation:

The given compounds are to be synthesized by considering benzene and appropriate acyl chloride or anhydride as a starting material.

Concept Introduction:

The reaction of benzene with acyl chloride in the presence of a Lewis acid leads to the formation of acyl substituted benzene as a product. This reaction is called Friedel’s Craft acylation.

Reduction of carbonyl group is done by its reaction with hydrazine and base in the presence of heat.

Answer 7

Chapter 15, Problem 5PP

Interpretation Introduction

Interpretation:

The given compounds are to be synthesized by considering benzene and appropriate acyl chloride or anhydride as a starting material.

Concept Introduction:

The reaction of benzene with acyl chloride in the presence of a Lewis acid leads to the formation of acyl substituted benzene as a product. This reaction is called Friedel’s Craft acylation.

Reduction of carbonyl group is done by its reaction with hydrazine and base in the presence of heat.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 15 - PRACTICE PROBLEM 15.1 Show how loss of a proton...Ch. 15 - Prob. 2PP Ch. 15 - PRACTICE PROBLEM 15.3 Outline all steps in a...Ch. 15 - PRACTICE PROBLEM 15.4 Provide a mechanism that...Ch. 15 - Prob. 5PP Ch. 15 - PRACTICE PROBLEM 15.6 Explain how the percentages...Ch. 15 - PRACTICE PROBLEM 15.7 Predict the major products...Ch. 15 - Prob. 8PP Ch. 15 - Prob. 9PP Ch. 15 - Prob. 10PP

Solution Summary: The author describes the reaction of acyl chloride with benzene in the presence of Lewis acid, which leads to a product in which carbonyl carbon is bonded to the ring.

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