Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 15, Problem 25P
Draw short segments of the
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Chapter 15 Solutions
Essential Organic Chemistry, Global Edition
Ch. 15.2 - Prob. 1PCh. 15.2 - Prob. 2PCh. 15.2 - Prob. 3PCh. 15.2 - Prob. 4PCh. 15.2 - List the following groups of monomers in order...Ch. 15.2 - List the following groups of monomers in order...Ch. 15.2 - Prob. 7PCh. 15.2 - Why does methyl methacrylate not undergo cationic...Ch. 15.2 - Which monomer and which type of initiator would...Ch. 15.2 - Prob. 10P
Ch. 15.2 - Prob. 11PCh. 15.5 - Draw a short segment of gutta-percha.Ch. 15.5 - Prob. 13PCh. 15.6 - Prob. 14PCh. 15.8 - Prob. 15PCh. 15.8 - Prob. 16PCh. 15.8 - Prob. 17PCh. 15.8 - a. Propose a mechanism for the formation of the...Ch. 15.8 - Propose a mechanism for the formation of Melmac.Ch. 15.8 - Explain why, when a small amount of glycerol is...Ch. 15.10 - Prob. 21PCh. 15 - Draw short segments of the polymers obtained from...Ch. 15 - Prob. 23PCh. 15 - Draw the structure of the monomer or monomers used...Ch. 15 - Draw short segments of the polymers obtained from...Ch. 15 - Prob. 26PCh. 15 - Prob. 27PCh. 15 - Prob. 28PCh. 15 - A particularly strong and rigid polyester used for...Ch. 15 - Prob. 30PCh. 15 - Prob. 31PCh. 15 - Prob. 32PCh. 15 - Prob. 33PCh. 15 - Prob. 34PCh. 15 - Prob. 35PCh. 15 - Delrin (polyoxymethylene) is a tough...
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- | Exercises 317 9.21 Identify the reactants from which the following molecules were prepared. If an acetal, identify the carbonyl compound and the alcohol; if an imine, identify the carbonyl compound and the amine; if an alcohol, identify the carbonyl compound and the Grignard reagent (red = 0, blue = N): (a) (b) (c)arrow_forwardThe reaction of p-cresol with CH2=O resembles the reaction of phenol (PhOH) with CH2=O, except that the resulting polymer is thermoplastic but not thermosetting. Draw the structure of the polymer formed, and explain why the properties of these two polymers are so different.arrow_forwardDraw a structure of the polymer formed in the following reactionarrow_forward
- Which products are formed when hydrobromic acid is added to (a) trans-2-hexene, (b) 2-methyl- 2-pentene, and (c) 4-methylcyclohexene, and how many regioisomers can be formed in each case?arrow_forwardThe reaction of p-cresol with CH2=O resembles the reaction of phenol (PhOH) with CH2=O, except that the resulting polymer is thermoplastic but not thermosetting. Draw the structure of the polymer formed, and explain why the properties of these two polymers are so different.arrow_forwardNH2 Dry-erase boards, or whiteboards, in classrooms consist of a network polymer similar to Bakelite that is made from formaldehyde and melamine. (a) Propose a structure for the polymer formed. (b) Why is this type of polymer suitable for use in whiteboards? 'N. H2N `NH2 Melaminearrow_forward
- Describe a sequence of reactions by which trans-2-pentene can be prepared from propyne.arrow_forwardDescribe a sequence of reactions by which cis-2-pentene could be prepared from acetylene.arrow_forwardWhat is the major organic product obtained from the reaction of toluene with fuming sulfuric acid?arrow_forward
- Given the chemical equation in the synthesis of benzoic acid from toluene and potassium permanganate: C7H8(I) + 2KMnO4(aq) → KC7H5O2 + 2MnO2 (s) + KOH (aq) + H2O (I) KC2H5O2 (aq) + HCl (aq) → C7H8O2 (s) + KCl (aq) MW: C7H8 = 92.14 KMnO4 = 158.03 MnO2 = 86.94 KC7H5O2 = 160.21 C7H8O2 = 122 Density: C7H8 = 0.87 g/mL KMnO4 = 2.7 g/mL KC7H5O2 = 1.5 g/mL C7H8O2 = 1.27 g/mL If 1 mL of toluene and 4 mL of 50% w/v potassium permanganate solution are used to synthesize the benzoic acid in a reflux set-up, calculate the theoretical yield of benzoic acid. Show your complete solution and underline your final answer.arrow_forwardExplain this ? "Organic synthesis is the systematic preparation of a compound from areadily available starting material by one or many steps".arrow_forwardWrite a balanced equation for the reaction of dihydroxy dimethylsilane (right)to form the condensation polymer known as Silly Putty.arrow_forward
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