(a) Interpretation: The derived expression for the relationship between Δ G ° ' and p K a is to be stated. Concept introduction: A thermodynamic potential that is utilized in the calculation of the highest reversible function taking place in the thermodynamic system at the constant value pressure and temperature is known as Gibbs-free energy. It is denoted by Δ G ° .

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Answer 1

Question

Chapter 15, Problem 20P

Interpretation Introduction

(a)

Interpretation:

The derived expression for the relationship between ΔG°' and pKa is to be stated.

Concept introduction:

A thermodynamic potential that is utilized in the calculation of the highest reversible function taking place in the thermodynamic system at the constant value pressure and temperature is known as Gibbs-free energy. It is denoted by ΔG°.

Interpretation Introduction

(b)

Interpretation:

The value of ΔG° for the ionization of acetic acid at pKa equals to 4.8 is to be stated.

Concept introduction:

A thermodynamic potential that is utilized in the calculation of the highest reversible function taking place in the thermodynamic system at the constant value pressure and temperature is known as Gibbs-free energy. It is denoted by ΔG°.

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You’ve isolated a protein and determined that the Native molecular weight of the holoenzyme is 160 kD using size exclusion chromatography. Analysis of this protein using SDS-PAGE revealed 2 bands, one at 100 kD and one at 30 kD. The enzyme was found to be 0.829% NAD (by weight). What further can be said regarding the structure of the polypeptide?

Answer 2

Question

Chapter 15, Problem 20P

Interpretation Introduction

(a)

Interpretation:

The derived expression for the relationship between ΔG°' and pKa is to be stated.

Concept introduction:

A thermodynamic potential that is utilized in the calculation of the highest reversible function taking place in the thermodynamic system at the constant value pressure and temperature is known as Gibbs-free energy. It is denoted by ΔG°.

Interpretation Introduction

(b)

Interpretation:

The value of ΔG° for the ionization of acetic acid at pKa equals to 4.8 is to be stated.

Concept introduction:

A thermodynamic potential that is utilized in the calculation of the highest reversible function taking place in the thermodynamic system at the constant value pressure and temperature is known as Gibbs-free energy. It is denoted by ΔG°.

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Answer 3

Question

Chapter 15, Problem 20P

Interpretation Introduction

(a)

Interpretation:

The derived expression for the relationship between ΔG°' and pKa is to be stated.

Concept introduction:

A thermodynamic potential that is utilized in the calculation of the highest reversible function taking place in the thermodynamic system at the constant value pressure and temperature is known as Gibbs-free energy. It is denoted by ΔG°.

Interpretation Introduction

(b)

Interpretation:

The value of ΔG° for the ionization of acetic acid at pKa equals to 4.8 is to be stated.

Concept introduction:

A thermodynamic potential that is utilized in the calculation of the highest reversible function taking place in the thermodynamic system at the constant value pressure and temperature is known as Gibbs-free energy. It is denoted by ΔG°.

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Answer 4

Question

Chapter 15, Problem 20P

Interpretation Introduction

(a)

Interpretation:

The derived expression for the relationship between ΔG°' and pKa is to be stated.

Concept introduction:

A thermodynamic potential that is utilized in the calculation of the highest reversible function taking place in the thermodynamic system at the constant value pressure and temperature is known as Gibbs-free energy. It is denoted by ΔG°.

Interpretation Introduction

(b)

Interpretation:

The value of ΔG° for the ionization of acetic acid at pKa equals to 4.8 is to be stated.

Concept introduction:

A thermodynamic potential that is utilized in the calculation of the highest reversible function taking place in the thermodynamic system at the constant value pressure and temperature is known as Gibbs-free energy. It is denoted by ΔG°.

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Answer 5

Chapter 15, Problem 20P

Interpretation Introduction

(a)

Interpretation:

The derived expression for the relationship between ΔG°' and pKa is to be stated.

Concept introduction:

A thermodynamic potential that is utilized in the calculation of the highest reversible function taking place in the thermodynamic system at the constant value pressure and temperature is known as Gibbs-free energy. It is denoted by ΔG°.

Interpretation Introduction

(b)

Interpretation:

The value of ΔG° for the ionization of acetic acid at pKa equals to 4.8 is to be stated.

Concept introduction:

A thermodynamic potential that is utilized in the calculation of the highest reversible function taking place in the thermodynamic system at the constant value pressure and temperature is known as Gibbs-free energy. It is denoted by ΔG°.

Answer 6

Chapter 15, Problem 20P

Interpretation Introduction

(a)

Interpretation:

The derived expression for the relationship between ΔG°' and pKa is to be stated.

Concept introduction:

A thermodynamic potential that is utilized in the calculation of the highest reversible function taking place in the thermodynamic system at the constant value pressure and temperature is known as Gibbs-free energy. It is denoted by ΔG°.

Answer 7

Chapter 15, Problem 20P

Interpretation Introduction

(a)

Interpretation:

The derived expression for the relationship between ΔG°' and pKa is to be stated.

Concept introduction:

A thermodynamic potential that is utilized in the calculation of the highest reversible function taking place in the thermodynamic system at the constant value pressure and temperature is known as Gibbs-free energy. It is denoted by ΔG°.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The value of ΔG° for the ionization of acetic acid at pKa equals to 4.8 is to be stated.

Concept introduction:

A thermodynamic potential that is utilized in the calculation of the highest reversible function taking place in the thermodynamic system at the constant value pressure and temperature is known as Gibbs-free energy. It is denoted by ΔG°.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The value of ΔG° for the ionization of acetic acid at pKa equals to 4.8 is to be stated.

Concept introduction:

A thermodynamic potential that is utilized in the calculation of the highest reversible function taking place in the thermodynamic system at the constant value pressure and temperature is known as Gibbs-free energy. It is denoted by ΔG°.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 15 - Prob. 1P Ch. 15 - Prob. 2P Ch. 15 - Prob. 3P Ch. 15 - Prob. 4P Ch. 15 - Prob. 5P Ch. 15 - Prob. 6P Ch. 15 - Prob. 7P Ch. 15 - Prob. 8P Ch. 15 - Prob. 9P Ch. 15 - Prob. 10P

Solution Summary: The author explains the derived expression for the relationship between Delta G°' and

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Chapter 15 Solutions