(a) Interpretation: Whether the acid-catalyzed dehydration of alcohol A is kinetically controlled or thermo-dynamically controlled reaction is to be stated with explanation. Concept introduction: In the given conditions of the reaction, if the products of any reaction do not attain the equilibrium then the reaction is known as kinetically controlled reaction. In the given conditions of the reaction, if the products of any reaction attain the equilibrium then the reaction is known as thermodynamically controlled reaction.

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Answer 1

Question

Chapter 15, Problem 15.67AP

Interpretation Introduction

(a)

Interpretation:

Whether the acid-catalyzed dehydration of alcohol A is kinetically controlled or thermo-dynamically controlled reaction is to be stated with explanation.

Concept introduction:

In the given conditions of the reaction, if the products of any reaction do not attain the equilibrium then the reaction is known as kinetically controlled reaction.

In the given conditions of the reaction, if the products of any reaction attain the equilibrium then the reaction is known as thermodynamically controlled reaction.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the compound C is favored at equilibrium is to be stated.

Concept introduction:

The rule that is used to identify the favored alkene products during the elimination reaction is known as Zaitsev’s rule. According to this rule, the most substituted product is highly stable and favored than the less substituted product.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the alkene B is formed more rapidly is to be stated.

Concept introduction:

In the given conditions of the reaction, if the products of any reaction do not attain the equilibrium then the reaction is known as kinetically controlled reaction.

In the given conditions of the reaction, if the products of any reaction attain the equilibrium then the reaction is known as thermodynamically controlled reaction.

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Experiment: Each team will be provided with 5g of a mixture of acetanilide and salicylic acid. You will divide it into three 1.5 g portions in separate 125 mL Erlenmeyer flasks savıng some for melting point analysis. Dissolve the mixture in each flask in ~60mL of DI water by heating to boiling on a hotplate. Take the flasks off the hotplate once you have a clear solution and let them stand on the bench top for 5 mins and then allow them to cool as described below. Sample A-Let the first sample cool slowly to room temperature by letting it stand on your lab bench, with occasional stirring to promote crystallization. Sample B-Cool the second sample 1n a tap-water bath to 10-15 °C Sample C-Cool the third sample in an ice-bath to 0-2 °C Results: weight after recrystalization and melting point temp. A=0.624g,102-115° B=0.765g, 80-105° C=1.135g, 77-108 What is the percent yield of A,B, and C.

Answer 2

Question

Chapter 15, Problem 15.67AP

Interpretation Introduction

(a)

Interpretation:

Whether the acid-catalyzed dehydration of alcohol A is kinetically controlled or thermo-dynamically controlled reaction is to be stated with explanation.

Concept introduction:

In the given conditions of the reaction, if the products of any reaction do not attain the equilibrium then the reaction is known as kinetically controlled reaction.

In the given conditions of the reaction, if the products of any reaction attain the equilibrium then the reaction is known as thermodynamically controlled reaction.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the compound C is favored at equilibrium is to be stated.

Concept introduction:

The rule that is used to identify the favored alkene products during the elimination reaction is known as Zaitsev’s rule. According to this rule, the most substituted product is highly stable and favored than the less substituted product.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the alkene B is formed more rapidly is to be stated.

Concept introduction:

In the given conditions of the reaction, if the products of any reaction do not attain the equilibrium then the reaction is known as kinetically controlled reaction.

In the given conditions of the reaction, if the products of any reaction attain the equilibrium then the reaction is known as thermodynamically controlled reaction.

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Answer 3

Question

Chapter 15, Problem 15.67AP

Interpretation Introduction

(a)

Interpretation:

Whether the acid-catalyzed dehydration of alcohol A is kinetically controlled or thermo-dynamically controlled reaction is to be stated with explanation.

Concept introduction:

In the given conditions of the reaction, if the products of any reaction do not attain the equilibrium then the reaction is known as kinetically controlled reaction.

In the given conditions of the reaction, if the products of any reaction attain the equilibrium then the reaction is known as thermodynamically controlled reaction.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the compound C is favored at equilibrium is to be stated.

Concept introduction:

The rule that is used to identify the favored alkene products during the elimination reaction is known as Zaitsev’s rule. According to this rule, the most substituted product is highly stable and favored than the less substituted product.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the alkene B is formed more rapidly is to be stated.

Concept introduction:

In the given conditions of the reaction, if the products of any reaction do not attain the equilibrium then the reaction is known as kinetically controlled reaction.

In the given conditions of the reaction, if the products of any reaction attain the equilibrium then the reaction is known as thermodynamically controlled reaction.

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Answer 4

Question

Chapter 15, Problem 15.67AP

Interpretation Introduction

(a)

Interpretation:

Whether the acid-catalyzed dehydration of alcohol A is kinetically controlled or thermo-dynamically controlled reaction is to be stated with explanation.

Concept introduction:

In the given conditions of the reaction, if the products of any reaction do not attain the equilibrium then the reaction is known as kinetically controlled reaction.

In the given conditions of the reaction, if the products of any reaction attain the equilibrium then the reaction is known as thermodynamically controlled reaction.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the compound C is favored at equilibrium is to be stated.

Concept introduction:

The rule that is used to identify the favored alkene products during the elimination reaction is known as Zaitsev’s rule. According to this rule, the most substituted product is highly stable and favored than the less substituted product.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the alkene B is formed more rapidly is to be stated.

Concept introduction:

In the given conditions of the reaction, if the products of any reaction do not attain the equilibrium then the reaction is known as kinetically controlled reaction.

In the given conditions of the reaction, if the products of any reaction attain the equilibrium then the reaction is known as thermodynamically controlled reaction.

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Answer 5

Chapter 15, Problem 15.67AP

Interpretation Introduction

(a)

Interpretation:

Whether the acid-catalyzed dehydration of alcohol A is kinetically controlled or thermo-dynamically controlled reaction is to be stated with explanation.

Concept introduction:

In the given conditions of the reaction, if the products of any reaction do not attain the equilibrium then the reaction is known as kinetically controlled reaction.

In the given conditions of the reaction, if the products of any reaction attain the equilibrium then the reaction is known as thermodynamically controlled reaction.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the compound C is favored at equilibrium is to be stated.

Concept introduction:

The rule that is used to identify the favored alkene products during the elimination reaction is known as Zaitsev’s rule. According to this rule, the most substituted product is highly stable and favored than the less substituted product.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the alkene B is formed more rapidly is to be stated.

Concept introduction:

In the given conditions of the reaction, if the products of any reaction do not attain the equilibrium then the reaction is known as kinetically controlled reaction.

In the given conditions of the reaction, if the products of any reaction attain the equilibrium then the reaction is known as thermodynamically controlled reaction.

Answer 6

Chapter 15, Problem 15.67AP

Interpretation Introduction

(a)

Interpretation:

Whether the acid-catalyzed dehydration of alcohol A is kinetically controlled or thermo-dynamically controlled reaction is to be stated with explanation.

Concept introduction:

In the given conditions of the reaction, if the products of any reaction do not attain the equilibrium then the reaction is known as kinetically controlled reaction.

In the given conditions of the reaction, if the products of any reaction attain the equilibrium then the reaction is known as thermodynamically controlled reaction.

Answer 7

Chapter 15, Problem 15.67AP

Interpretation Introduction

(a)

Interpretation:

Whether the acid-catalyzed dehydration of alcohol A is kinetically controlled or thermo-dynamically controlled reaction is to be stated with explanation.

Concept introduction:

In the given conditions of the reaction, if the products of any reaction do not attain the equilibrium then the reaction is known as kinetically controlled reaction.

In the given conditions of the reaction, if the products of any reaction attain the equilibrium then the reaction is known as thermodynamically controlled reaction.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The reason as to why the compound C is favored at equilibrium is to be stated.

Concept introduction:

The rule that is used to identify the favored alkene products during the elimination reaction is known as Zaitsev’s rule. According to this rule, the most substituted product is highly stable and favored than the less substituted product.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The reason as to why the compound C is favored at equilibrium is to be stated.

Concept introduction:

The rule that is used to identify the favored alkene products during the elimination reaction is known as Zaitsev’s rule. According to this rule, the most substituted product is highly stable and favored than the less substituted product.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The reason as to why the alkene B is formed more rapidly is to be stated.

Concept introduction:

In the given conditions of the reaction, if the products of any reaction do not attain the equilibrium then the reaction is known as kinetically controlled reaction.

In the given conditions of the reaction, if the products of any reaction attain the equilibrium then the reaction is known as thermodynamically controlled reaction.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The reason as to why the alkene B is formed more rapidly is to be stated.

Concept introduction:

In the given conditions of the reaction, if the products of any reaction do not attain the equilibrium then the reaction is known as kinetically controlled reaction.

In the given conditions of the reaction, if the products of any reaction attain the equilibrium then the reaction is known as thermodynamically controlled reaction.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 15 - Prob. 15.1P Ch. 15 - Prob. 15.2P Ch. 15 - Prob. 15.3P Ch. 15 - Prob. 15.4P Ch. 15 - Prob. 15.5P Ch. 15 - Prob. 15.6P Ch. 15 - Prob. 15.7P Ch. 15 - Prob. 15.8P Ch. 15 - Prob. 15.9P Ch. 15 - Prob. 15.10P

Solution Summary: The author explains that the acid-catalyzed dehydration of alcohol A is a thermodynamically controlled reaction.

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