s - cis and s - trans conformations of ( 2 E , 4 Z ) - 2 , 4 -hexadiene and ( 2 E , 4 E ) - 2 , 4 -hexadiene are to be drawn. The diene with greater proportion of gauche conformation is to be stated. Concept introduction: In s - trans conformation, the two double bonds are present opposite to each other that mean the double bonds are trans to each other in the conformation. In s - cis conformation, the two double bonds are present on the same side that means the double bonds are cis in the conformation. The stability of s - cis and s - trans conformation depends on Vander Waals repulsion.

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Answer 1

Question

Chapter 15, Problem 15.3P

Interpretation Introduction

Interpretation:

s-cis and s-trans conformations of (2E,4Z)-2,4-hexadiene and (2E,4E)-2,4-hexadiene are to be drawn. The diene with greater proportion of gauche conformation is to be stated.

Concept introduction:

In s-trans conformation, the two double bonds are present opposite to each other that mean the double bonds are trans to each other in the conformation.

In s-cis conformation, the two double bonds are present on the same side that means the double bonds are cis in the conformation. The stability of s-cis and s-trans conformation depends on Vander Waals repulsion.

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Answer 2

Question

Chapter 15, Problem 15.3P

Interpretation Introduction

Interpretation:

s-cis and s-trans conformations of (2E,4Z)-2,4-hexadiene and (2E,4E)-2,4-hexadiene are to be drawn. The diene with greater proportion of gauche conformation is to be stated.

Concept introduction:

In s-trans conformation, the two double bonds are present opposite to each other that mean the double bonds are trans to each other in the conformation.

In s-cis conformation, the two double bonds are present on the same side that means the double bonds are cis in the conformation. The stability of s-cis and s-trans conformation depends on Vander Waals repulsion.

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Answer 3

Question

Chapter 15, Problem 15.3P

Interpretation Introduction

Interpretation:

s-cis and s-trans conformations of (2E,4Z)-2,4-hexadiene and (2E,4E)-2,4-hexadiene are to be drawn. The diene with greater proportion of gauche conformation is to be stated.

Concept introduction:

In s-trans conformation, the two double bonds are present opposite to each other that mean the double bonds are trans to each other in the conformation.

In s-cis conformation, the two double bonds are present on the same side that means the double bonds are cis in the conformation. The stability of s-cis and s-trans conformation depends on Vander Waals repulsion.

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Answer 4

Question

Chapter 15, Problem 15.3P

Interpretation Introduction

Interpretation:

s-cis and s-trans conformations of (2E,4Z)-2,4-hexadiene and (2E,4E)-2,4-hexadiene are to be drawn. The diene with greater proportion of gauche conformation is to be stated.

Concept introduction:

In s-trans conformation, the two double bonds are present opposite to each other that mean the double bonds are trans to each other in the conformation.

In s-cis conformation, the two double bonds are present on the same side that means the double bonds are cis in the conformation. The stability of s-cis and s-trans conformation depends on Vander Waals repulsion.

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Answer 5

Chapter 15, Problem 15.3P

Interpretation Introduction

Interpretation:

s-cis and s-trans conformations of (2E,4Z)-2,4-hexadiene and (2E,4E)-2,4-hexadiene are to be drawn. The diene with greater proportion of gauche conformation is to be stated.

Concept introduction:

In s-trans conformation, the two double bonds are present opposite to each other that mean the double bonds are trans to each other in the conformation.

In s-cis conformation, the two double bonds are present on the same side that means the double bonds are cis in the conformation. The stability of s-cis and s-trans conformation depends on Vander Waals repulsion.

Answer 6

Chapter 15, Problem 15.3P

Interpretation Introduction

Interpretation:

s-cis and s-trans conformations of (2E,4Z)-2,4-hexadiene and (2E,4E)-2,4-hexadiene are to be drawn. The diene with greater proportion of gauche conformation is to be stated.

Concept introduction:

In s-trans conformation, the two double bonds are present opposite to each other that mean the double bonds are trans to each other in the conformation.

In s-cis conformation, the two double bonds are present on the same side that means the double bonds are cis in the conformation. The stability of s-cis and s-trans conformation depends on Vander Waals repulsion.

Answer 7

Chapter 15, Problem 15.3P

Interpretation Introduction

Interpretation:

s-cis and s-trans conformations of (2E,4Z)-2,4-hexadiene and (2E,4E)-2,4-hexadiene are to be drawn. The diene with greater proportion of gauche conformation is to be stated.

Concept introduction:

In s-trans conformation, the two double bonds are present opposite to each other that mean the double bonds are trans to each other in the conformation.

In s-cis conformation, the two double bonds are present on the same side that means the double bonds are cis in the conformation. The stability of s-cis and s-trans conformation depends on Vander Waals repulsion.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 15 - Prob. 15.1P Ch. 15 - Prob. 15.2P Ch. 15 - Prob. 15.3P Ch. 15 - Prob. 15.4P Ch. 15 - Prob. 15.5P Ch. 15 - Prob. 15.6P Ch. 15 - Prob. 15.7P Ch. 15 - Prob. 15.8P Ch. 15 - Prob. 15.9P Ch. 15 - Prob. 15.10P

Solution Summary: The author explains that the s-cis conformation exhibits lesser Vander Waals repulsions because the bulky molecules are on the opposite side of

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