(a) Interpretation: The molecular orbital that holds the “extra electrons” in allyl anion is to be identified by using the molecular orbital diagram. Concept introduction: An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable as compared to branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Question

Want to see the full answer?

Answer 1

Question

Chapter 15, Problem 15.25P

Interpretation Introduction

(a)

Interpretation:

The molecular orbital that holds the “extra electrons” in allyl anion is to be identified by using the molecular orbital diagram.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable as compared to branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(b)

Interpretation:

The carbon atom that bears the negative charge is to be identified according to the molecular orbital description.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable than branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(c)

Interpretation:

The same conclusion is to be shown by drawing resonance structures of allyl anion.

Concept introduction:

Resonance structures represent the delocalization of electrons. It is considered as a stabilizing effect. The energy associated with electron delocalization is known as resonance energy

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Could you crystallize one enantiomer of mandelic acid from a racemic mixture (using the typical achiral solvents found in our lab) without preparing a diastereomeric salt? Why or why not? No, because both enantiomers have the same solubility in achiral solvents. than the other. ооо Yes, because one enantiomer has a higher melting point No, because both enantiomers are liquids. Yes, because one enantiomer is more crystalline than the other.

If the literature value of specific rotation for a chiral compound is -53.6°, what is the enantiomeric excess of a compound with a measured specific rotation of -40.5°?

The process to determine the configuration, starts by placing the lowest priority substituent toward the back. If the substituents pointing forward decrease in priority in a clockwise order, the configuration is S. If the substituents decrease in priority in a counterclockwise order, the configuration is R. True False

Answer 2

Question

Chapter 15, Problem 15.25P

Interpretation Introduction

(a)

Interpretation:

The molecular orbital that holds the “extra electrons” in allyl anion is to be identified by using the molecular orbital diagram.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable as compared to branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(b)

Interpretation:

The carbon atom that bears the negative charge is to be identified according to the molecular orbital description.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable than branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(c)

Interpretation:

The same conclusion is to be shown by drawing resonance structures of allyl anion.

Concept introduction:

Resonance structures represent the delocalization of electrons. It is considered as a stabilizing effect. The energy associated with electron delocalization is known as resonance energy

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 15, Problem 15.25P

Interpretation Introduction

(a)

Interpretation:

The molecular orbital that holds the “extra electrons” in allyl anion is to be identified by using the molecular orbital diagram.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable as compared to branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(b)

Interpretation:

The carbon atom that bears the negative charge is to be identified according to the molecular orbital description.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable than branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(c)

Interpretation:

The same conclusion is to be shown by drawing resonance structures of allyl anion.

Concept introduction:

Resonance structures represent the delocalization of electrons. It is considered as a stabilizing effect. The energy associated with electron delocalization is known as resonance energy

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 15, Problem 15.25P

Interpretation Introduction

(a)

Interpretation:

The molecular orbital that holds the “extra electrons” in allyl anion is to be identified by using the molecular orbital diagram.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable as compared to branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(b)

Interpretation:

The carbon atom that bears the negative charge is to be identified according to the molecular orbital description.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable than branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(c)

Interpretation:

The same conclusion is to be shown by drawing resonance structures of allyl anion.

Concept introduction:

Resonance structures represent the delocalization of electrons. It is considered as a stabilizing effect. The energy associated with electron delocalization is known as resonance energy

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 15, Problem 15.25P

Interpretation Introduction

(a)

Interpretation:

The molecular orbital that holds the “extra electrons” in allyl anion is to be identified by using the molecular orbital diagram.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable as compared to branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(b)

Interpretation:

The carbon atom that bears the negative charge is to be identified according to the molecular orbital description.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable than branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(c)

Interpretation:

The same conclusion is to be shown by drawing resonance structures of allyl anion.

Concept introduction:

Resonance structures represent the delocalization of electrons. It is considered as a stabilizing effect. The energy associated with electron delocalization is known as resonance energy

Answer 6

Chapter 15, Problem 15.25P

Interpretation Introduction

(a)

Interpretation:

The molecular orbital that holds the “extra electrons” in allyl anion is to be identified by using the molecular orbital diagram.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable as compared to branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Answer 7

Chapter 15, Problem 15.25P

Interpretation Introduction

(a)

Interpretation:

The molecular orbital that holds the “extra electrons” in allyl anion is to be identified by using the molecular orbital diagram.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable as compared to branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The carbon atom that bears the negative charge is to be identified according to the molecular orbital description.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable than branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The carbon atom that bears the negative charge is to be identified according to the molecular orbital description.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable than branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The same conclusion is to be shown by drawing resonance structures of allyl anion.

Concept introduction:

Resonance structures represent the delocalization of electrons. It is considered as a stabilizing effect. The energy associated with electron delocalization is known as resonance energy

Answer 11

Interpretation Introduction

(c)

Interpretation:

The same conclusion is to be shown by drawing resonance structures of allyl anion.

Concept introduction:

Resonance structures represent the delocalization of electrons. It is considered as a stabilizing effect. The energy associated with electron delocalization is known as resonance energy

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 15

Ch. 15 - Prob. 15.1P Ch. 15 - Prob. 15.2P Ch. 15 - Prob. 15.3P Ch. 15 - Prob. 15.4P Ch. 15 - Prob. 15.5P Ch. 15 - Prob. 15.6P Ch. 15 - Prob. 15.7P Ch. 15 - Prob. 15.8P Ch. 15 - Prob. 15.9P Ch. 15 - Prob. 15.10P

Solution Summary: The author explains the molecular orbital that holds the "extra electrons" in allyl anion.

Concept explainers

Want to see the full answer?

Chapter 15 Solutions