(a)
Interpretation:
The kinetic and the
Concept introduction:
In the given conditions of the reaction, if the products of any reaction do not attain the equilibrium then the reaction is known as kinetically controlled reaction.
In the given conditions of the reaction, if the products of any reaction attain the equilibrium then the reaction is known as thermodynamically controlled reaction.
(b)
Interpretation:
A structural reason for the fact that the thermodynamic product is more stable than the kinetic product is to be stated.
Concept introduction:
In the given conditions of the reaction, if the products of any reaction do not attain the equilibrium then the reaction is known as kinetically controlled reaction.
In the given conditions of the reaction, if the products of any reaction attain the equilibrium then the reaction is known as thermodynamically controlled reaction.
(c)
Interpretation:
A mechanism that explains the reason as to why the kinetic product is formed more rapidly even though it is less stable is to be stated.
Concept introduction:
In the given conditions of the reaction, if the products of any reaction do not attain the equilibrium then the reaction is known as kinetically controlled reaction.
In the given conditions of the reaction, if the products of any reaction attain the equilibrium then the reaction is known as thermodynamically controlled reaction.
(d)
Interpretation:
A mechanism for the equilibration of the two compounds that does not involve the
Concept introduction:
In the given conditions of the reaction, if the products of any reaction do not attain the equilibrium then the reaction is known as kinetically controlled reaction.
In the given conditions of the reaction, if the products of any reaction attain the equilibrium then the reaction is known as thermodynamically controlled reaction.
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Chapter 15 Solutions
EBK ORGANIC CHEMISTRY STUDY GUIDE AND S
- Determine the rate order and rate constant for sucrose hydrolysis. Time (hours) [C6H12O6] 0 0.501 0.500 0.451 1.00 0.404 1.50 0.363 3.00 0.267arrow_forwardDraw the products of the reaction shown below. Use wedge and dash bonds to indicate stereochemistry. Ignore inorganic byproducts. OSO4 (cat) (CH3)3COOH Select to Draw ઘarrow_forwardCalculate the reaction rate for selenious acid, H2SeO3, if 0.1150 M I-1 decreases to 0.0770 M in 12.0 minutes. H2SeO3(aq) + 6I-1(aq) + 4H+1(aq) ⟶ Se(s) + 2I3-1(aq) + 3H2O(l)arrow_forward
- Problem 5-31 Which of the following objects are chiral? (a) A basketball (d) A golf club (b) A fork (c) A wine glass (e) A spiral staircase (f) A snowflake Problem 5-32 Which of the following compounds are chiral? Draw them, and label the chirality centers. (a) 2,4-Dimethylheptane (b) 5-Ethyl-3,3-dimethylheptane (c) cis-1,4-Dichlorocyclohexane Problem 5-33 Draw chiral molecules that meet the following descriptions: (a) A chloroalkane, C5H11Cl (c) An alkene, C6H12 (b) An alcohol, C6H140 (d) An alkane, C8H18 Problem 5-36 Erythronolide B is the biological precursor of erythromycin, a broad-spectrum antibiotic. How H3C CH3 many chirality centers does erythronolide B have? OH Identify them. H3C -CH3 OH Erythronolide B H3C. H3C. OH OH CH3arrow_forwardPLEASE HELP! URGENT! PLEASE RESPOND!arrow_forward2. Propose a mechanism for this reaction. ہلی سے ملی N H (excess)arrow_forward
- Steps and explanationn please.arrow_forwardProblem 5-48 Assign R or S configurations to the chirality centers in ascorbic acid (vitamin C). OH H OH HO CH2OH Ascorbic acid O H Problem 5-49 Assign R or S stereochemistry to the chirality centers in the following Newman projections: H Cl H CH3 H3C. OH H3C (a) H H H3C (b) CH3 H Problem 5-52 Draw the meso form of each of the following molecules, and indicate the plane of symmetry in each: OH OH (a) CH3CHCH2CH2CHCH3 CH3 H3C. -OH (c) H3C CH3 (b) Problem 5-66 Assign R or S configurations to the chiral centers in cephalexin, trade-named Keflex, the most widely prescribed antibiotic in the United States. H2N H IHH S Cephalexin N. CH3 CO₂Harrow_forwardSteps and explanationn please.arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
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