Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 15, Problem 15.11P
15-11 In what way are constitutional isomers different from stereoisomers? In what way are they the same?
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Cortisone is a compound that is used as an anti-inflammatory drug to treat
2)
diseases like arthritis. Cortisone is a steroid which contains four rings (A, B, C and D), and
has the following structure:
он
"OH
Cortisone
Provide the data to complete each of the following statements:
The total number of chiral carbons (stereocentres) in Cortisone is
The maximum number of stereoisomers possible is:
The degree of unsaturation (IHD) of Cortisone is
The total number of 2° hydrogens is
The ring fusion between rings B and C is trans or cis?
The absolute configuration of the carbon with * in the structure is
The total number of n bonds is
Two compounds have the same composition and
also have the same atoms attached to the same atoms, although
with different orientations in space. These compounds are
اخترأحد الخيارات
a. Identical
b. Structural isomers
c. Stereoisomers
Question 8
Structure A
H
|
H3C.C
HO
CH₂Br
Structure B
CH3
|
HC
Br
CH₂OH
Determine the relationship between the structures above. Are they the same
molecule, constitutional isomers, or stereoisomers? If A and B are stereoisomers,
futher classify them as diastereomers or enantiomers.
A and B are the same molecule
A and B are constitutional isomers
A and B are stereoisomers and diastereomers
A and B are stereoisomers and enantiomers
Chapter 15 Solutions
Introduction to General, Organic and Biochemistry
Ch. 15.1 - Prob. 15.1PCh. 15.2 - Problem 15-2 Assign priorities to the groups in...Ch. 15.2 - Problem 15-3 Assign an R or S configuration to the...Ch. 15.3 - Problem 15-4 3-Amino-2-butanol has two...Ch. 15.3 - Prob. 15.5PCh. 15.3 - Prob. 15.6PCh. 15 - 15-7 Answer true or false. The cis and trans...Ch. 15 - 15-8 What does the term “chiral” mean? Give an...Ch. 15 - 15-9 What does the term “achiral” mean? Give an...Ch. 15 - 15-10 Define the term “stereoisomer.” Name three...
Ch. 15 - 15-11 In what way are constitutional isomers...Ch. 15 - 15-12 Which of the following objects are chiral...Ch. 15 - Prob. 15.13PCh. 15 - Prob. 15.14PCh. 15 - 15-15 Explain why the carbon of a carbonyl group...Ch. 15 - 15-16 Which of the following compounds contain...Ch. 15 - 15-17 Which of the following compounds contain...Ch. 15 - Prob. 15.18PCh. 15 - 15-19 Draw the mirror image for each molecule: OH...Ch. 15 - Prob. 15.20PCh. 15 - 15-21 Answer true or false. For a molecule with...Ch. 15 - Prob. 15.22PCh. 15 - Prob. 15.23PCh. 15 - Prob. 15.24PCh. 15 - Prob. 15.25PCh. 15 - 15-26 For centuries, Chinese herbal medicine has...Ch. 15 - Prob. 15.27PCh. 15 - Prob. 15.28PCh. 15 - Prob. 15.29PCh. 15 - 15-30 (Chemical Connections 15A) What does it mean...Ch. 15 - Prob. 15.31PCh. 15 - Prob. 15.32PCh. 15 - Prob. 15.33PCh. 15 - Prob. 15.34PCh. 15 - 15-35 Following are structural formulas for three...Ch. 15 - Prob. 15.36PCh. 15 - 15-37 Consider a cyclohexane ring substituted with...Ch. 15 - Prob. 15.38PCh. 15 - Prob. 15.39PCh. 15 - Prob. 15.40PCh. 15 - 15-41 Compound A(C5Hh, is not optically active and...Ch. 15 - Prob. 15.42PCh. 15 - 15-43 Triamcinolone acetonide, the active...Ch. 15 - 15-44 Consider the structure of the...Ch. 15 - Prob. 15.45PCh. 15 - 15-46 Consider Lunesta, a nonbenzodiazepine...Ch. 15 - Prob. 15.47P
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Consider the following structural formula for Nos. 19-20: CI СООН H3C CH2B. - он CI A. Which is a chiral molecule? A or B? Which can exist as a pair of enantiomers? Draw the pair of enantiomers. HIarrow_forwardPart 1 of 2 Each of the following compounds can exhibit optical activity. Enter the label number of chiral center(s) in the following compounds. If more than one, separate them with commas. H OF || | | HO-C-C-C=C-H 121 H 3 The chiral center(s) is/are at Part 2 of 2 H-C-H H Garrow_forward17-74 Glucose, C6H12O6, contains an aldehyde group but exists predominantly in the form of the cyclic hemiacetal shown here. We will discuss this cyclic form of glucose in Chapter 20. A cyclic hemiacetal is formed when the —OH group of one carbon bonds to the carbonyl group of another carbon. (a) Which carbon in glucose provides the —OH group and which provides the —CHO group? (b) Draw the alternative chair confirmations of D-glucose and state which of the two is the more stable.arrow_forward
- 11-58 (Chemical Connections 11A) How many rings in te trodotoxin contain only carbon atoms? How many contain nitrogen atoms? How many contain two oxygen atoms?arrow_forward1 Hyaluronic acid acts as a lubricant in the synovial fluid of joints. In rheumatoid arthritis, inflammation breaks hyaluronic acid down to smaller molecules. Under these conditions, what happens to the lubricating power of the synovial fluid?arrow_forward13-27 Define autoxidation.arrow_forward
- Q1 Chiral Carbons (Wade 5-25) The following four structures are naturally occurring optically active compounds. Star (*) the asymmetric carbon atoms in these structures. СНО H CH, СООН -ОН CH,OH H. H- -ОН Н.N CH,OH ОН H serine erythrose menthol camphorarrow_forwardfor each of the following compounds... a. Build a model using the molecular model kit b. Name the compound, using R, S nomenclaturearrow_forwardc) For the following compound identify how many chiral carbons present and how many isomers are possible. HO C4H6NOF OH OH d) Figure out elements of unsaturation for the following compoundarrow_forward
- E O Biological Macromolecules Predicting the products or reactants of triacylglycerol hydrogenation Predict the product of the following organic reaction: CH2−O−C—(CH2)3 — CH=CH–CH2CH3 CH—O−C–CH2–CH=CH–CH=CH–CH2–CH3 CH,−O−C−CH2–CH=CH-CH=CH-CH2-CH3 + 5 H₂ Ni P Specifically, in the drawing area below, draw the chemical structure of the product P. If there is no product, because this reaction won't ha reaction box under the drawing area.arrow_forwardOf the choices, could you please clarify what molecule this is?arrow_forwardHow do you read HOC₆H₄CO₂H or C₇H₆O₃ verbally?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
ENVIRONMENTAL POLLUTION; Author: 7activestudio;https://www.youtube.com/watch?v=oxtMFmDTv3Q;License: Standard YouTube License, CC-BY