Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 15, Problem 113E
What is the effect on the amount of CaHPO4 that dissolves and the concentrations of Ca2+ and HPO4- when each of the following are added to a mixture of solid CaHPO4 and water at equilibrium?
(a) CaCl2.
(b) HCl.
(c) KClO4.
(d) NaOH.
(e) CaHPO4
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
What is the effect on the amount of CaHPO4 that dissolves and the concentrations of Ca2+ and HPO4− when each of the following are added to a mixture of solid CaHPO4 and water at equilibrium?(a) CaCl2(b) HCl(c) KClO4(d) NaOH(e) CaHPO4
1) The equation below represents the equilibrium process of a saturated solution of Ca(OH)2 If the following changes are made to a saturated solution, what will be the effect on the [Ca2+]?
Ca(OH)2 (s) <--> Ca2+(aq) + 2 OH- (aq) ΔH = -16.6 kJ
A strong base is added to the solution (Decrease, Increase, No change)
More solid Ca(OH)2 is added to the container (Decrease, Increase, No change)
The solution is raised to a higher temperature (Decrease, Increase, No change)
A strong acid is added to the solution (Decrease, Increase, No change)
Ca(NO3)2 (s) is added. Ca(NO3)2 is very soluble (Decrease, Increase, No change)
Consider the buffer system of hydrofluoric acid, HF, and its salt, NaF:
HF(aq)+H2O(l) ⇌ H3O+(aq) +F-(aq)
a.) Which substance neutralizes the addition of OH-?
b.) When H3O+ is added, what happens to the equilibrium? Which way does it shift?
Chapter 15 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 15 - Complete the changes in concentrations for each of...Ch. 15 - Complete the changes in concentrations for each of...Ch. 15 - How do the concentrations of Ag+ and CrO42- in a...Ch. 15 - How do the concentrations of Pb2+ and S2- change...Ch. 15 - What additional information do we need to answer...Ch. 15 - Which of the following slightly soluble compounds...Ch. 15 - Which of the following slightly soluble compounds...Ch. 15 - Write the ionic equation for dissolution and the...Ch. 15 - Write the ionic equation for the dissolution and...Ch. 15 - The Handbook of Chemistry and Physics...
Ch. 15 - The Handbook of Chemistry and Physics...Ch. 15 - Use solubility products and predict which of the...Ch. 15 - Assuming that no equilibria other than dissolution...Ch. 15 - Assuming that no equilibria other than dissolution...Ch. 15 - Assuming that no equilibria other than dissolution...Ch. 15 - Assuming that no equilibria other than dissolution...Ch. 15 - Assuming that no equilibria other than dissolution...Ch. 15 - Explain why the changes in concentrations of the...Ch. 15 - Explain why the Changes in concentrations of the...Ch. 15 - Calculate the solubility of aluminum hydroxide,...Ch. 15 - Refer to Appendix J for solubility products for...Ch. 15 - Most barium compounds are very poisonous; however,...Ch. 15 - Public Health Service standards for drinking water...Ch. 15 - Perform the following calculations: (a) Calculate...Ch. 15 - The solubility product of CaSO42H2O is 2.4105....Ch. 15 - Assuming that no equilibria other than dissolution...Ch. 15 - Assuming that no equilibria other than dissolution...Ch. 15 - The following concentrations are found in mixtures...Ch. 15 - The following concentrations are found in mixtures...Ch. 15 - Which of the following compounds precipitates from...Ch. 15 - Which of the following compounds precipitates from...Ch. 15 - Calculate the concentration of Tl+ when TICl just...Ch. 15 - Calculate the concentration of sulfate ion when...Ch. 15 - Calculate the concentration of Sr2+ when SrF2...Ch. 15 - Calculate the concentration of PO43- when Ag3PO4...Ch. 15 - Calculate the concentration of F- required to...Ch. 15 - Calculate the concentration] of Ag+ required to...Ch. 15 - What [Ag+] is required to reduce [CO32-] to...Ch. 15 - What [F-] is required to reduce [Ca2+] to 1.0104M...Ch. 15 - A volume of 0.800 L of a 2104 -M Ba(NO3)2 solution...Ch. 15 - Perform these calculations for nickel(II)...Ch. 15 - Iron concentrations greater than 5.4106 M in water...Ch. 15 - A solution is 0.010 M in both Cu2+ and Cd2+. What...Ch. 15 - A solution is 0.15 M in both Pb2+ and Ag+. If Cl-...Ch. 15 - What reagent might be used to separate the ions in...Ch. 15 - A solution contains 1.0105 mol of KBr and 0.10 mol...Ch. 15 - A solution contains 1.0102 mol of Kl and 0.10 mol...Ch. 15 - The calcium ions in human blood serum are...Ch. 15 - About 50% of urinary calculi (kidney stones)...Ch. 15 - The pH of normal urine is 6.30, and the total...Ch. 15 - Magnesium metal (a component of alloys used in...Ch. 15 - Hydrogen sulfide is bubbled into a solution that...Ch. 15 - Perform the following calculations involving...Ch. 15 - Calculate the molar solubility of AgBr in 0.035 M...Ch. 15 - How many grams of Pb(OH)2 will dissolve in 500 mL...Ch. 15 - Use the simulation...Ch. 15 - How many grams of Milk of Magnesia, Mg(OH)2 (s)...Ch. 15 - Two hypothetical salts, LM2 and LQ, have the same...Ch. 15 - Which of the following carbonates will form first?...Ch. 15 - How many grams of Zn(CN)2(s) (117.44 g/mol) would...Ch. 15 - Under what circumstances, if any, does a sample of...Ch. 15 - Explain why the addition of NH3 or HNO3 to a...Ch. 15 - Calculate the cadmium ion concentration, [Cd2+],...Ch. 15 - Explain why addition of NH3 or HNO3 to a saturated...Ch. 15 - Sometimes equilibria fur complex ions are...Ch. 15 - Using the value of the formation constant for the...Ch. 15 - Using the dissociation constant, Kd=7.81018,...Ch. 15 - Using the dissociation constant, Kd=3.41015,...Ch. 15 - Using the dissociation constant, Kd=2.21034,...Ch. 15 - Using the dissociation constant kd=1*10-44...Ch. 15 - Calculate the mass of potassium cyanide ion that...Ch. 15 - Calculate the minimum concentration of ammonia...Ch. 15 - A roll of 35-mm black and white photographic film...Ch. 15 - We have seen an introductory definition of an...Ch. 15 - Write the Lewis structures of the reactants and...Ch. 15 - Write the Lewis structures of the reactants and...Ch. 15 - Using Lewis structures, write balanced equations...Ch. 15 - Calculate [HgCl42-] in a solution prepared by...Ch. 15 - In a titration of cyanide ion, 28.72 mL of 0.0100...Ch. 15 - What are the concentrations of Ag+, CN-, and...Ch. 15 - In dilute aqueous solution HF acts as a weak acid....Ch. 15 - The simplest amino acid is glycine, H2NCH2CO2H....Ch. 15 - Boric acid, H3303, is not a Bronsted-Lowry acid...Ch. 15 - A saturated solution of a slightly soluble...Ch. 15 - Calculate the equilibrium concentration of Ni2+ in...Ch. 15 - Calculate the equilibrium concentration of Zn2+ in...Ch. 15 - Calculate the equilibrium concentration of Cu2+ in...Ch. 15 - Calculate the equilibrium concentration of Zn2+ in...Ch. 15 - Calculate the Fe3+ equilibrium concentration when...Ch. 15 - Calculate the CO2+ equilibrium concentration when...Ch. 15 - The equilibrium constant for the reaction...Ch. 15 - Calculate the molar solubility of Sn(OH)2 in a...Ch. 15 - Calculate the molar solubility of Al(OH)3 in a...Ch. 15 - What is the molar solubility of CaF2 in a 0.100-M...Ch. 15 - What is the molar solubility of BaSO4 in a 0.250-M...Ch. 15 - What is the molar solubility of Tl(OH)3 in a...Ch. 15 - What is the molar solubility of Pb(OH)2 in a...Ch. 15 - A solution of 0.075 M CoBr2 is saturated with...Ch. 15 - A 0.125-M solution of 0.075 Mn(NO3)2 is saturated...Ch. 15 - Calculate the molar solubility of BaF2 in a buffer...Ch. 15 - Calculate the molar solubility of CdCO3 in a...Ch. 15 - To a 0.10-M solution of Pb(NO3)2 is added enough...Ch. 15 - Calculate the concentration of Cd2+ resulting from...Ch. 15 - Both AgCl and Agl dissolve in NH3.. (a) What mass...Ch. 15 - Calculate the volume of 1.50 M CH3CO2H required to...Ch. 15 - Even though Ca(OH)2 is an inexpensive base, its...Ch. 15 - What mass of NaCN must be added to 1 L of 0.010 M...Ch. 15 - Magnesium hydroxide and magnesium citrate function...Ch. 15 - The following question is taken from a Chemistry...Ch. 15 - Which of the following compounds, when dissolved...Ch. 15 - Which of the following compounds, when dissolved...Ch. 15 - What is the effect on the amount of solid Mg(OH)2...Ch. 15 - What is the effect on the amount of CaHPO4 that...Ch. 15 - Identify all chemical species present in an...Ch. 15 - A volume of 50 mL of 1.8 M NH3 is mixed with an...
Additional Science Textbook Solutions
Find more solutions based on key concepts
Explain why the forces in our joints are several times larger than the forces we exert on the outside world wit...
College Physics
For the generic equilibrium HA(aq) ⇌ H + (aq) + A- (aq), which of these statements is true?
The equilibrium con...
Chemistry: The Central Science (13th Edition)
Benzenedianium chloride decomposes by a first-enter reaction in water yielding as one product.
The reaction ca...
General Chemistry: Principles and Modern Applications (11th Edition)
Consider a galvanic cell that uses the following half-reactions: 2H+(aq)+2eH2(g)Al3+(aq)+3eAl(s) a) What materi...
CHEMISTRY-TEXT
Choose the more metallic element from each pair. a. Sb or Pb b. K or Ge c. Ge or Sb d. As or Sn
Introductory Chemistry (5th Edition) (Standalone Book)
An atom with a formal charge does not necessarily have more or less electron density than the atoms in the mole...
Essential Organic Chemistry (3rd Edition)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 10.00 mL of 0.45 M NaOH is added to 9.00 mL of 1.00 M HCOOH. What is the molar concentration of hydrogen ions, [H3O+], when the system reaches equilibrium?arrow_forward. (a) Calculate the pH of the following solution: 2.8 x 10-4 M Ba(OH)2 (b) What is the original molarity of a solution of HF whose pH is 1.7 at equilibrium? (Ka = 6.6 x 10-4) HF (aq) ⇌ H+ (aq) + F- (aq)arrow_forward6a. Draw the Lewis Dot structure for the following diprotic acid: HOOC-CH,-COOH. 38.5 mL of a 1.15 M solution of this acid is titrated to the equivalence point with 0.69 M KOH. Write the balanced equation for this reaction and determine the volume of base needed to completely neutralize the acid.arrow_forward
- Which of the following statements about buffers is FALSE? O a buffer consists of a weak acid and its soluble ionic salt O most body fluids contain natural buffer system a buffer solution can react with either H3O" or OH ions O the pH of a buffer never changes even after the addition of H30' or OH ionsarrow_forward4. The value of the solubility product, K for calcium hydroxide, Ca(OH), is 5.5 x 10, at25"C. (a) Write the K expression for calcium hydroxide. (b) What is the mass of Ca(OH), in 500 ml of a saturated solution at 25°C? (c) What is the pH of the solution in (b)? (d) If 1.0 mole of OH Is added to the solution in (b), what will be the resulting Ca concentration? Assume that the volume of the solution does not change.arrow_forwardAssume you titrate 20.0 mL of 0.11 M NH3 with 0.10 M HCl. (a) What is the pH of the NH3 solution before the titration begins? (b) What is the pH of the equivalence point? (c) What is the pH at the midpoint of the titration? (d) Which indicator would you suggest to detect the equivalence point? (e) Calculate the pH of the solution after adding 5.00, 11.0, 15.0, 20.0, 22.0, and 25.0 mL of the acid. Combine this information with that from (a) through (c) and plot the titration curve.arrow_forward
- You are asked to prepare a pH = 3.00 buffer solution startingfrom 1.25 L of a 1.00 M solution of hydrofluoric acid(HF) and any amount you need of sodium fluoride (NaF).(a) What is the pH of the hydrofluoric acid solution priorto adding sodium fluoride? (b) How many grams of sodiumfluoride should be added to prepare the buffer solution?Neglect the small volume change that occurs when the sodiumfluoride is added.arrow_forwardThe major component of vinegar is acetic acid, CH3COOH. Its Ka is 1.8 × 10-5 . One student used 1.000 M NaOH to titrate 25.00 mL vinegar. At the end point, 21.82 mL NaOH was used. (a) What is the concentration of CH3COOH in vinegar? (b) What is the pH of the solution at the end point? (c) What indicator(s) the student should use in this titration? Explainarrow_forwardThe drawing below represents a buffer composed of equal concentrations of a weak acid, HX, and its conjugate base, X-'. The heights of the columns are proportional to the concentrations of the components of the buffer. (a) Which of the three drawing (1), (2), or (3) represents the buffer after the addition of a strong acid? Explain. (b) Which of the three represents the buffer after the addition of a strong base? Explain. HX X HX X- HX X HX X (1) (2) (3) Copyright © 2006 Pearson Prentice Hall, Inc.arrow_forward
- What change will be caused by addition of a small amount of Ba(OH) 2 to a solution containing CN- and HCN? The concentration of CN- ion will increase as will the concentration of hydronium ions. The concentration of CN- ion will decrease and the concentration of HCN will increase. The concentration of hydronium ions will increase significantly. The concentration of HCN will decrease and the concentration of CN- ions will increase. The CN- ions will precipitate out of solution as its acid salt.arrow_forwardFor the titration of 50. mL of 0.10 M ammonia with 0.10 M HCI, calculate the pH. For ammonia, NH3, Kp = 1.8 x 10-5. (a) Before the addition of any HCl solution. pH = Use correct number of significant digits; (b) After 20. mL of the acid has been added. pH = Use correct number of significant digits; (c) After half of the NH3 has been neutralized. pH Use correct number of significant digits; (d) At the equivalence point. pH Use correct number of significant digits;arrow_forwardA buffer is prepared by adding 5.0 g of ammonia, NH3, and 20.0 g of ammonium chloride, NH4Cl, to enough water to form 2.50 L of solution. (a) What is the pH of the buffer? (b) Write the complete ionic equation for the reaction that occurs when a few drops of nitric acid are added to the buffer. (c) Write the complete ionic equation for the reaction that occurs when a few drops of potassium hydroxide solution are added to the buffer.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
General Chemistry | Acids & Bases; Author: Ninja Nerd;https://www.youtube.com/watch?v=AOr_5tbgfQ0;License: Standard YouTube License, CC-BY