Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 15, Problem 35E
Calculate the concentration of PO43- when Ag3PO4 starts to precipitate from a solution that is 0.0125 M in Ag+.
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1,
How many signals do you expect in the H NMR spectrum for this molecule?
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: In this question, any multiplet is counted as one signal.
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in top
molecule
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute.
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in bottom
molecule
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Row 2: Your answer is incorrect.
Consider this molecule:
How many H atoms are in this molecule?
22
How many different signals could be found in its 'H NMR spectrum?
12
Note: A multiplet is considered one signal.
13
How many signals would you expect to see in the
Check
O
signal(s)
X
§
'C NMR spectrum for the following compound?
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Chapter 15 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 15 - Complete the changes in concentrations for each of...Ch. 15 - Complete the changes in concentrations for each of...Ch. 15 - How do the concentrations of Ag+ and CrO42- in a...Ch. 15 - How do the concentrations of Pb2+ and S2- change...Ch. 15 - What additional information do we need to answer...Ch. 15 - Which of the following slightly soluble compounds...Ch. 15 - Which of the following slightly soluble compounds...Ch. 15 - Write the ionic equation for dissolution and the...Ch. 15 - Write the ionic equation for the dissolution and...Ch. 15 - The Handbook of Chemistry and Physics...
Ch. 15 - The Handbook of Chemistry and Physics...Ch. 15 - Use solubility products and predict which of the...Ch. 15 - Assuming that no equilibria other than dissolution...Ch. 15 - Assuming that no equilibria other than dissolution...Ch. 15 - Assuming that no equilibria other than dissolution...Ch. 15 - Assuming that no equilibria other than dissolution...Ch. 15 - Assuming that no equilibria other than dissolution...Ch. 15 - Explain why the changes in concentrations of the...Ch. 15 - Explain why the Changes in concentrations of the...Ch. 15 - Calculate the solubility of aluminum hydroxide,...Ch. 15 - Refer to Appendix J for solubility products for...Ch. 15 - Most barium compounds are very poisonous; however,...Ch. 15 - Public Health Service standards for drinking water...Ch. 15 - Perform the following calculations: (a) Calculate...Ch. 15 - The solubility product of CaSO42H2O is 2.4105....Ch. 15 - Assuming that no equilibria other than dissolution...Ch. 15 - Assuming that no equilibria other than dissolution...Ch. 15 - The following concentrations are found in mixtures...Ch. 15 - The following concentrations are found in mixtures...Ch. 15 - Which of the following compounds precipitates from...Ch. 15 - Which of the following compounds precipitates from...Ch. 15 - Calculate the concentration of Tl+ when TICl just...Ch. 15 - Calculate the concentration of sulfate ion when...Ch. 15 - Calculate the concentration of Sr2+ when SrF2...Ch. 15 - Calculate the concentration of PO43- when Ag3PO4...Ch. 15 - Calculate the concentration of F- required to...Ch. 15 - Calculate the concentration] of Ag+ required to...Ch. 15 - What [Ag+] is required to reduce [CO32-] to...Ch. 15 - What [F-] is required to reduce [Ca2+] to 1.0104M...Ch. 15 - A volume of 0.800 L of a 2104 -M Ba(NO3)2 solution...Ch. 15 - Perform these calculations for nickel(II)...Ch. 15 - Iron concentrations greater than 5.4106 M in water...Ch. 15 - A solution is 0.010 M in both Cu2+ and Cd2+. What...Ch. 15 - A solution is 0.15 M in both Pb2+ and Ag+. If Cl-...Ch. 15 - What reagent might be used to separate the ions in...Ch. 15 - A solution contains 1.0105 mol of KBr and 0.10 mol...Ch. 15 - A solution contains 1.0102 mol of Kl and 0.10 mol...Ch. 15 - The calcium ions in human blood serum are...Ch. 15 - About 50% of urinary calculi (kidney stones)...Ch. 15 - The pH of normal urine is 6.30, and the total...Ch. 15 - Magnesium metal (a component of alloys used in...Ch. 15 - Hydrogen sulfide is bubbled into a solution that...Ch. 15 - Perform the following calculations involving...Ch. 15 - Calculate the molar solubility of AgBr in 0.035 M...Ch. 15 - How many grams of Pb(OH)2 will dissolve in 500 mL...Ch. 15 - Use the simulation...Ch. 15 - How many grams of Milk of Magnesia, Mg(OH)2 (s)...Ch. 15 - Two hypothetical salts, LM2 and LQ, have the same...Ch. 15 - Which of the following carbonates will form first?...Ch. 15 - How many grams of Zn(CN)2(s) (117.44 g/mol) would...Ch. 15 - Under what circumstances, if any, does a sample of...Ch. 15 - Explain why the addition of NH3 or HNO3 to a...Ch. 15 - Calculate the cadmium ion concentration, [Cd2+],...Ch. 15 - Explain why addition of NH3 or HNO3 to a saturated...Ch. 15 - Sometimes equilibria fur complex ions are...Ch. 15 - Using the value of the formation constant for the...Ch. 15 - Using the dissociation constant, Kd=7.81018,...Ch. 15 - Using the dissociation constant, Kd=3.41015,...Ch. 15 - Using the dissociation constant, Kd=2.21034,...Ch. 15 - Using the dissociation constant kd=1*10-44...Ch. 15 - Calculate the mass of potassium cyanide ion that...Ch. 15 - Calculate the minimum concentration of ammonia...Ch. 15 - A roll of 35-mm black and white photographic film...Ch. 15 - We have seen an introductory definition of an...Ch. 15 - Write the Lewis structures of the reactants and...Ch. 15 - Write the Lewis structures of the reactants and...Ch. 15 - Using Lewis structures, write balanced equations...Ch. 15 - Calculate [HgCl42-] in a solution prepared by...Ch. 15 - In a titration of cyanide ion, 28.72 mL of 0.0100...Ch. 15 - What are the concentrations of Ag+, CN-, and...Ch. 15 - In dilute aqueous solution HF acts as a weak acid....Ch. 15 - The simplest amino acid is glycine, H2NCH2CO2H....Ch. 15 - Boric acid, H3303, is not a Bronsted-Lowry acid...Ch. 15 - A saturated solution of a slightly soluble...Ch. 15 - Calculate the equilibrium concentration of Ni2+ in...Ch. 15 - Calculate the equilibrium concentration of Zn2+ in...Ch. 15 - Calculate the equilibrium concentration of Cu2+ in...Ch. 15 - Calculate the equilibrium concentration of Zn2+ in...Ch. 15 - Calculate the Fe3+ equilibrium concentration when...Ch. 15 - Calculate the CO2+ equilibrium concentration when...Ch. 15 - The equilibrium constant for the reaction...Ch. 15 - Calculate the molar solubility of Sn(OH)2 in a...Ch. 15 - Calculate the molar solubility of Al(OH)3 in a...Ch. 15 - What is the molar solubility of CaF2 in a 0.100-M...Ch. 15 - What is the molar solubility of BaSO4 in a 0.250-M...Ch. 15 - What is the molar solubility of Tl(OH)3 in a...Ch. 15 - What is the molar solubility of Pb(OH)2 in a...Ch. 15 - A solution of 0.075 M CoBr2 is saturated with...Ch. 15 - A 0.125-M solution of 0.075 Mn(NO3)2 is saturated...Ch. 15 - Calculate the molar solubility of BaF2 in a buffer...Ch. 15 - Calculate the molar solubility of CdCO3 in a...Ch. 15 - To a 0.10-M solution of Pb(NO3)2 is added enough...Ch. 15 - Calculate the concentration of Cd2+ resulting from...Ch. 15 - Both AgCl and Agl dissolve in NH3.. (a) What mass...Ch. 15 - Calculate the volume of 1.50 M CH3CO2H required to...Ch. 15 - Even though Ca(OH)2 is an inexpensive base, its...Ch. 15 - What mass of NaCN must be added to 1 L of 0.010 M...Ch. 15 - Magnesium hydroxide and magnesium citrate function...Ch. 15 - The following question is taken from a Chemistry...Ch. 15 - Which of the following compounds, when dissolved...Ch. 15 - Which of the following compounds, when dissolved...Ch. 15 - What is the effect on the amount of solid Mg(OH)2...Ch. 15 - What is the effect on the amount of CaHPO4 that...Ch. 15 - Identify all chemical species present in an...Ch. 15 - A volume of 50 mL of 1.8 M NH3 is mixed with an...
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- 13 Consider the "C NMR spectrum below. 140 120 100 80 60 40 20 20 PPM 0 The spectrum belongs to which one of the following constitutional isomers of the compound C,H12? Select the single best answer. Check ✓ G Save For Later 2025 McGraw Hill LLC. All Rights Reserved. Terms of Usearrow_forwardThe structure of compound 1,3,5-trimethylbenzene (mesitylene) is given below. How many signals would you expect to find in the 'H NMR spectrum of 1,3,5-trimethylbenzene (mesitylene)? Check ×arrow_forward1 How many signals do you expect in the 'H NMR spectrum for this molecule? CI CI Cl Write the answer in the table below. Also, in each of the drawing areas below is a copy of the molecule, with H atoms shown. In each copy, one of the H atoms is highlighted red. Highlight in red all other H atoms that would contribute to the same signal as the H already highlighted red. Note for advanced students: Remember, a multiplet is considered one signal in the 'H NMR spectrum. 1 Number of signals in the 'H NMR spectrum. ☐ For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional H atoms to highlight in top molecule For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at…arrow_forward
- wrtie the balanced equation and find the E° when the following half- reactions are combined Zn2+(aq) + 2e---> Zn(s) E°= -0.763V Ag+(aq) + e---> Ag (s) E°=+0.799Varrow_forwardConsider this molecule: How many H atoms are in this molecule? How many different signals could be found in its 'H NMR spectrum? Note: A multiplet is considered one signal. ☐arrow_forwardStudy this 'H NMR spectrum, and then answer the questions about it in the table below. Check 1.0- 0.5- 0.0 10.0 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.0 What unit symbol should be written on the horizontal axis? What is the chemical shift & of the doublet? If there is no doublet, just check the box instead. Give your answer to 2 significant digits. What is the chemical shift of the signal immediately upfield of the doublet? If there is no doublet, or no signal upfield of it, check the box instead. What is the chemical shift & of the least deshielded proton? If you can't tell without more information, check the box instead. 血 8 = ☐ There is no doublet. 8 = ☐ No such signal. 8 = 0 Need more information.arrow_forward
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